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Full-Text Articles in Physical Sciences and Mathematics
Design And Fabrication Of An Apparatus For Tao High-Resolution Laser Spectroscopy, Timothy Chung
Design And Fabrication Of An Apparatus For Tao High-Resolution Laser Spectroscopy, Timothy Chung
UNLV Theses, Dissertations, Professional Papers, and Capstones
In this study, an apparatus for the high-resolution laser spectroscopy of molecules is designed and constructed. The apparatus is used to identify TaO transitions, but may be used for any other molecular species in the future. It will also later be used for experiments such as quantum logic spectroscopy, which are enabled by attachable chambers that can be supplied with molecules from the apparatus. Several considerations are made to improve the quality and longevity of the apparatus such as regulating the rovibrational states of the produced molecules, optimizing the linewidth of the ionization lasers, reducing noise from sources such as …
Speciation And Spectroscopy Of The Uranyl And Tetravalent Plutonium Nitrate Systems: Fundamental Studies And Applications To Used Fuel Reprocessing, Nicholas A. Smith
Speciation And Spectroscopy Of The Uranyl And Tetravalent Plutonium Nitrate Systems: Fundamental Studies And Applications To Used Fuel Reprocessing, Nicholas A. Smith
UNLV Theses, Dissertations, Professional Papers, and Capstones
This dissertation explores the use of UV-Visible spectroscopy and Time Resolved Laser Induced Fluorescence spectroscopy as near real time process monitors of uranium and plutonium concentrations in aqueous reprocessing trains. The molar absorptivities and linear ranges of these metals were investigated under total nitrate and acid concentrations similar to those found in current reprocessing systems. Concurrent to this, a new multiple wavelength monitor was derived that is capable of determining the total nitrate concentration spectroscopically. This method uses the uranium absorbance spectrum to calculate the nitrate concentration in solution. When used as part of an Advanced Safeguard suite, this technique …