Physical Sciences and Mathematics Commons^™

Investigation Of Carbon Dioxide Oxidation Reaction Pathways On Rh(111) Via Reflection Absorption Infrared Spectroscopy (Rairs), Elizabeth A. Jamka

Dissertations

CO oxidation, RAIRS, Rh(111), Surface Science, UHV

Structural And Chemical Consequences Of High Oxygen Coverages On Rh(111), Rachael Gabrielle Farber

Dissertations

Partial oxidations of small molecules over metal surfaces are central to many heterogeneously catalyzed reactions. However, the identity of the actual surface species that promote or hinder these reactions has remained elusive for a variety of reasons. Recently, the understanding of the role of surface oxides in catalytic activity has changed. Instead of being thought of as poisons, they are now believed to be effective promoters of selective catalysis.

Rhodium (Rh) effectively promotes oxidation reactions and is a benchmark system for models of heterogeneously catalyzed chemistry. For this reason, Rh(111) was chosen as the model system for this dissertation work. …

Understanding The Surface Induced Phosphorylation Of Prebiotic Molecules By Schreibersite, Danna Qasim

Master of Science in Chemical Sciences Theses

The study of the surface of a meteoritic mineral, schreibersite (Fe,Ni)₃P, was investigated to provide insight into the role of the mineral’s surface in aqueous-phase phosphorylation reactions. The optimization of a custom-designed ultrahigh vacuum (UHV) apparatus and Fe₂NiP (schreibersite) surface was performed to permit surface science analysis. The bare surface was characterized by scanning electron microscopy (SEM) coupled with energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS), which showed some oxidation and segregation of phosphorous within the near-surface region. The interaction and/or reaction of water (H₂O), methanol (CH₃OH), formic acid …