Physical Sciences and Mathematics Commons^™

Dual Crosslinked Poly(Acrylamide-Co-N-Vinylpyrrolidone) Microspheres With Re-Crosslinking Ability For Fossil Energy Recovery, Jingyang Pu, Baojun Bai, Jiaming Geng, Na Zhang, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Microspheres have been proposed to be applied in controlling wastewater production for mature oilfields and migrating leakage for gas and nuclear waste storage. However, it remains challenging for stacked microspheres to maintain strong blocking ability in micron-sized small pores or fractures. In this study, a novel microsphere was developed with comprehensive properties including high deformability and long re-crosslinking time upon tunable swelling ratio for the applications. A dual covalent and physical crosslinking strategy was used to develop novel microspheres reinforced by a hydrogen bond (H-bond, between pyrrole ring and amide group) and coordination bond (between chromium acetate (CrAc) and carboxyl …

Seismic Azimuthal Anisotropy Beneath A Fast Moving Ancient Continent: Constraints From Shear Wave Splitting Analysis In Australia, Kailun Ba, Stephen S. Gao, Jianguo Song, Kelly H. Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Seismic Azimuthal Anisotropy Beneath Australia is Investigated using Splitting of the Teleseismic PKS, SKKS, and SKS Phases to Delineate Asthenospheric Flow and Lithospheric Deformation Beneath One of the Oldest and Fast-Moving Continents on Earth. in Total 511 Pairs of High-Quality Splitting Parameters Were Observed at 116 Seismic Stations. Unlike Other Stable Continental Areas in Africa, East Asia, and North America, Where Spatially Consistent Splitting Parameters Dominate, the Fast Orientations and Splitting Times Observed in Australia Show a Complex Pattern, with a Slightly Smaller Than Normal Average Splitting Time of 0.85 ± 0.33 S. on the North Australian Craton, the Fast …

Coreflooding Evaluation Of Fiber-Assisted Recrosslinkable Preformed Particle Gel Using An Open Fracture Model, Shuda Zhao, Ali Al Brahim, Junchen Liu, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Recrosslinkable Preformed Particle Gels (RPPGs) Have Been Used to Treat the Problem of Void Space Conduits (VSC) and repair the "Short-Circuited" Waterflood in Alaska's West Sak Field. Field Results Showed a 23% Increase in Success Rates over Typical Preformed Particle Gel (PPG) Treatments. in This Paper, We Evaluated Whether Adding Fiber into RPPGs Can Increase the RPPG Plugging Efficiency and Thus Further Improve the Success Rate. We Designed Open Fracture Models to Represent vs.C and Investigated the Effect of Swelling Ratio (SR), Fracture Size, and Fiber Concentration on Gel Injection Pressure, Water Breakthrough Pressure, and Permeability Reduction. Results Show that …

Lysine Crosslinked Polyacrylamide─A Novel Green Polymer Gel For Preferential Flow Control, Tao Song, Baojun Bai, Yugandhara Eriyagama, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Acrylamide-based polymer gels have been applied to control the preferential flow in the subsurface for decades. However, some commonly used crosslinkers, such as Cr (III) and phenol-formaldehyde, are highly toxic and are being phased out because of stringent environmental regulations. This work uses l-lysine as the green crosslinker to produce acrylamide-based polymer gels. This article systematically studied the effect of lysine and polymer concentration, salinity, pH, and temperature on gelation behavior and thermal stability. Besides, the gelation mechanism and crosslinking density were elucidated in this work. A high-permeability sandstone core was used to test the plugging efficiency of this novel …

Transport And Plugging Performance Evaluation Of A Novel Re-Crosslinkable Microgel Used For Conformance Control In Mature Oilfields With Super-Permeable Channels, Adel Alotibi, T. Song, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Preformed particle gels (PPG) have been widely applied in oilfields to control excessive water production. However, PPG has limited success in treating opening features because the particles can be flushed readily during post-water flooding. We have developed a novel micro-sized Re-crosslinkable PPG (micro-RPPG) to solve the problem. The microgel can re-crosslink to form a bulk gel, avoiding being washed out easily. This paper evaluates the novel microgels' transport and plugging performance through super-permeable channels. Micro-RPPG was synthesized and evaluated for this study. Its storage moduli after fully swelling are approximately 82 Pa. The microgel characterization, self-healing process, transportation behavior, and …

Comprehensive Evaluation Of A Novel Re-Crosslinkable Preformed Particle Gel For The Water Management Of Reservoir With Concentrated Divalent Ions, Tao Song, Mohamed Ahdaya, Zhanmiao Zhai, Thomas P. Schuman, Baojun Bai

Chemistry Faculty Research & Creative Works

As one of the most widely used technology to ameliorate the reservoir's heterogeneity, polymer gels have been applied for more than 60 years. However, how to plug fractured reservoirs with significant abnormal features, high temperature and high salinity, especially the divalent cations, is still a challenging target. This work systematically evaluated a novel salt-resistant re-crosslinkable preformed particle gel (SR-RPPG) designed for fractured reservoirs with excellent salt resistance (up to 5 % CaCl₂). We evaluated the swelling kinetics, thermal stability and plugging efficiency of this SR-RPPG. We assessed the swelling kinetic and re-crosslinking behavior of the SR-RPPG through the …

Laboratory Evaluation Of A Novel Self-Healable Polymer Gel For Co2 Leakage Remediation During Co2 Storage And Co2 Flooding, Tao Song, Zhanmiao Zhai, Junchen Liu, Yugandhara Eriyagama, Mohamed Ahdaya, Adel Alotibi, Ze Wang, Thomas P. Schuman, Baojun Bai

Chemistry Faculty Research & Creative Works

For CO₂ storage in subsurface reservoirs, one of the most crucial requirements is the ability to remediate the leakage caused by the natural fractures or newly generated fractures due to the increasing pore pressure associated with CO₂ injection. For CO₂ Enhanced Oil Recovery (EOR), high conductivity features such as fractures and void space conduits can severely restrict the CO₂ sweep efficiency. Polymer gels have been developed to plug the leakage and improve the sweep efficiency. This work evaluated a CO₂ resistant branched self-healable preformed particle gel (CO₂-BRPPG) for CO₂ plugging purpose. This …

Fabrications And Applications Of Micro/Nanofluidics In Oil And Gas Recovery: A Comprehensive Review, Junchen Liu, Yandong Zhang, Mingzhen Wei, Xiaoming He, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Understanding fluid flow characteristics in porous medium, which determines the development of oil and gas oilfields, has been a significant research subject for decades. Although using core samples is still essential, micro/nanofluidics have been attracting increasing attention in oil recovery fields since it offers direct visualization and quantification of fluid flow at the pore level. This work provides the latest techniques and development history of micro/nanofluidics in oil and gas recovery by summarizing and discussing the fabrication methods, materials and corresponding applications. Compared with other reviews of micro/nanofluidics, this comprehensive review is in the perspective of solving specific issues in …

Comprehensive Review Of Polymer And Polymer Gel Treatments For Natural Gas-Related Conformance Control, Ali Al Brahim, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Conformance problems often exist in natural gas-related activities, resulting in excessive water production from natural gas production wells and/or excessive natural gas production from oil production wells. Several mechanical and chemical solutions were reported in the literature to mitigate the conformance problems. Among the chemical solutions, two classes of materials, namely polymer gels and water-soluble polymers, have been mostly reported. These systems have been mainly reviewed in several studies for their applications as water shutoff treatments for oil production wells. Natural gas production wells exhibit different characteristics and have different properties which could impact the performance of the chemical solutions. …

Systematic Evaluation Of A Novel Self-Healing Poly(Acrylamide-Co-Vinyl Acetate)/Alginate Polymer Gel For Fluid Flow Control In High Temperature And High Salinity Reservoirs, Jingyang Pu, Baojun Bai, Thomas P. Schuman

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Preferential fluid flow often occurs when water and CO₂ is injected into mature oilfields, sig-nificantly reducing their injection efficiency. Particle gels have been evaluated and applied to control the short circulation problems. This study systematically investigated a novel poly(acrylamide-co-vinyl acetate)/alginate-based interpenetrated gel system (Alg-IPNG) which is designed to control the preferential fluid flow problems in high-temperature reservoirs. Chromium acetate was incorporated into the gel system to provide the delayed crosslinking feature of the particle gels. The alginate polymer system can also take advantage of the Ca²⁺ ions in the formation water, which exist in most reservoirs, to reinforce …

Experimental Data On Water Soluble Polymers Thermal And Hydrolytic Stability, Reactivity Ratios Of Monomers And Frr Calculation For Thermally Stable Preformed Particle Gels Therefrom, Buddhabhushan Salunkhe, Thomas P. Schuman, Ali Al Brahim, Baojun Bai

Chemistry Faculty Research & Creative Works

Experimental data on water soluble polymer thermal and hydrolytic stability in acidic, neutral and basic pH conditions in aqueous solution is presented. Thermal and hydrolytic stability of polymer aqueous solutions were monitored in variable pH medium by aging at 130 °C temperature for different aging time. Polymer viscosity measurements were performed periodically for 3 months. Furthermore, this data can serve as a basis of monomer selection for thermally stable hydrogels for applications like oil recovery, hydrogel coatings for steam sterilized medical devices and other applications. Reactivity ratios were determined for monomers associated to the most stable polymers using ¹H …

Characterization And Oil Recovery Enhancement By A Polymeric Nanogel Combined With Surfactant For Sandstone Reservoirs, Mustafa Mohammed Almahfood, Baojun Bai

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The characterization and enhanced oil recovery mechanisms of a nanosized polymeric cross-linked gel are presented herein. A negatively charged nanogel was synthesized using a typical free radical suspension polymerization process by employing 2-acrylamido 2-methyl propane sulfonic acid monomer. The synthesized nanogel showed a narrow size distribution with one peak pointing to a predominant homogeneous droplet size. The charged nanogels were also able to adsorb at the oil-water interfaces to reduce interfacial tension and stabilize oil-in-water emulsions, which ultimately improved the recovered oil from hydrocarbon reservoirs. In addition, a fixed concentration of negatively charged surfactant (sodium dodecyl sulfate or SDS) was …

Extraction And Visualization Of Orientation Data From Virtual Geologic Surfaces With Matlab®, Avery J. Welker, John Patrick Hogan, Andreas Eckert

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

High-resolution visualization of surfaces of geologic interest, at a multitude of scales, using 3D point cloud technologies provides an opportunity to analyze spatial relationships of surfaces using orientation data. We present a MATLAB® script that produces planar geologic attitude data (e.g., strike, dip, and dip-direction data) from 3D datasets (e.g., point clouds, 3D scanning). The method utilizes Cartesian coordinates of triangular planar surfaces and converts them into matrices of conventional geologic attitude data. Spatial relationships among data points can be investigated, using polar tangent diagrams, stereographic analysis, or geologic curvature analysis. We utilize this script to create "synthetic" graphical plots …

Experimental Investigation Of Fracture Width Limitations Of Granular Lost Circulation Treatments, Mortadha Al-Saba, Runar Nygaard, Arild Saasen, Olav Magnar Nes

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Drilling fluid losses into fractured shales is a major challenge. Lost circulation treatments are widely applied to mitigate the losses; however, the effectiveness of these treatments is affected by different physical properties of the used lost circulation materials (LCM). This paper presents an experimental investigation to study the effect of LCM type, concentration, particle size distribution, temperature, and LCM shape on the formed seal integrity, with respect to differential pressure, at different fracture widths. The overall objective of this study is to address the effectiveness of LCM treatments in sealing fractured shales, with specific application to the over consolidated Barents …

Modeling Of Gas Production From Shale Reservoirs Considering Multiple Transport Mechanisms, Chaohua Guo, Mingzhen Wei, Hong Liu

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Gas transport in unconventional shale strata is a multi-mechanism-coupling process that is different from the process observed in conventional reservoirs. In micro fractures which are inborn or induced by hydraulic stimulation, viscous flow dominates. And gas surface diffusion and gas desorption should be further considered in organic nano pores. Also, the Klinkenberg effect should be considered when dealing with the gas transport problem. In addition, following two factors can play significant roles under certain circumstances but have not received enough attention in previous models. During pressure depletion, gas viscosity will change with Knudsen number; and pore radius will increase when …

Decoupling The Stationary Navier-Stokes-Darcy System With The Beavers-Joseph-Saffman Interface Condition, Yong Cao, Yuchuan Chu, Xiaoming He, Mingzhen Wei

Mathematics and Statistics Faculty Research & Creative Works

This paper proposes a domain decomposition method for the coupled stationary Navier-Stokes and Darcy equations with the Beavers-Joseph-Saffman interface condition in order to improve the efficiency of the finite element method. The physical interface conditions are directly utilized to construct the boundary conditions on the interface and then decouple the Navier-Stokes and Darcy equations. Newton iteration will be used to deal with the nonlinear systems. Numerical results are presented to illustrate the features of the proposed method.

Design Of A Conditioner For Smoothing Wind Turbine Output Power, Murali Bottu, Mariesa Crow, A. Curt Elmore

Electrical and Computer Engineering Faculty Research & Creative Works

As a result of wind speed intermittency, highly variable wind power output can adversely impact local loads. We propose a conditioner to smooth the variable wind power by utilizing the energy of an ultracapacitor. The conditioner is based on a single phase voltage source inverter (VSI) connected between the grid interconnection point and the ultracapacitor. The shunt VSI injects or absorbs active power from the line to smooth the wind power by utilizing the short term storage capabilities of the ultracapacitor. The ultracapacitor is connected to the DC link through a DC-DC converter, which maintains the voltage of the DC …

Characteristics Of Co₂ Sequestration In Saline Aquifers, Fang Yang, Baojun Bai, Dazhen Tang, Shari Dunn-Norman, David J. Wronkiewicz

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Storage of CO₂ in saline aquifers is a viable option for reducing the amount of CO₂ released to the atmosphere. This paper provides an overall review of CO₂ sequestration in saline aquifers. First, the principles of CO₂ sequestration are presented, including CO₂ phase behavior, CO₂-water-rock interaction, and CO₂ trapping mechanisms. Then storage capacity and CO₂ injectivity are discussed as the main determinants of the storage potential of saline aquifers. Next, a site section process is addressed considering basin characteristics, reservoir characteristics, and economic and social concerns. Three main procedures are then …

Fault Growth And Propagation During Incipient Continental Rifting: Insights From A Combined Aeromagnetic And Shuttle Radar Topography Mission Digital Elevation Model Investigation Of The Okavango Rift Zone, Northwest Botswana, Baraka D. Kinabo, John Patrick Hogan, Eliot A. Atekwana, Mohamed G. Abdel Salam, Motsoptse P. Modisi

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Digital Elevation Models (DEM) extracted from the Shuttle Radar Topography Mission (SRTM) data and high-resolution aeromagnetic data are used to characterize the growth and propagation of faults associated with the early stages of continental extension in the Okavango Rift Zone (ORZ), northwest Botswana. Significant differences in the height of fault scarps and the throws across the faults in the basement indicate extended fault histories accompanied by sediment accumulation within the rift graben. Faults in the center of the rift either lack topographic expressions or are interpreted to have become inactive, or have large throws and small scarp heights indicating waning …

Natrolitite, An Unusual Rock -- Occurrence And Petrographic And Geochemical Characteristics (Eastern Turkey), Emin Ciftci, John Patrick Hogan, Hasan Kolayli, Emin Cadirli

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Very unusual rocks consisting of natrolite (>95 vol.%) ± pargasite (<5 vol.%) and rare albite (<1 vol. %) have been discovered in the Kop mountain range, eastern Turkey. We propose to call these rocks 'natrolitite' and 'pargasite natrolitite'. They were produced by Na Si metasomatism of dikes and stocks of diorite through replacement of the intermediate primary igneous plagioclase to produce natrolite. The metasomatic alteration produced concentric elliptical zones characterized by distinct mineral assemblages centered on intrusions of diorite. The Central Zone 1 consists of variably albitized diorite with preserved magmatic textures (albite ± andesine ± pargasite ± quartz). Transition Zone 2 comprises natrolite-bearing diorite (natrolite ± albite ± andesine ± pargasite ± calcite ± quartz). Marginal Zone 3 is a rock made up almost entirely of natrolite (natrolite ± pargasite ± albite ± calcite ± chlorite). Outer Zone 4 occurs along the boundary between the natrolitite and the surrounding serpentinite and consists of listvenite, a rock which comprises magnesite, quartz, calcite, mica, talc, and hematite, indicating a role for CO₂ in the metasomatic reactions, consistent with the presence of calcite in the alteration zones. Zone 5 consists essentially of brecciated serpentinite with numerous hydrothermal quartz veins and calcite veins. Whole-rock compositions document an increase in Na₂O, Al₂O₃, and H₂O from the core (central zone) to the margin while CaO, MgO, and SiO₂ decrease. Plagioclase abundance and composition also varies outwards from the central core rocks where it occurs as a primary magmatic phase (~95 vol.% An_41-38) …

Hydrological Monitoring With Hybrid Sensor Networks, Thomas V. Freiberger, Sahra Sedigh, Estella A. Atekwana

Electrical and Computer Engineering Faculty Research & Creative Works

Existing hydrological monitoring systems suffer from short- comings in accuracy, resolution, and scalability. Their fragility, high power consumption, and lack of autonomy necessitate frequent site visits. Cabling requirements and large size limit their scalability and make them prohibitively expensive. The research described in this paper proposes to alleviate these problems by pairing high-resolution in situ measure- ment with remote data collection and software maintenance. A hybrid sensor network composed of wired and wireless connections autonomously measures various attributes of the soil, including moisture, temperature, and resistivity. The mea- surements are communicated to a processing server over the existing GSM cellular …

Improving Database Quality Through Eliminating Duplicate Records, Mingzhen Wei, Andrew H. Sung, Martha E. Cather

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Redundant or duplicate data are the most troublesome problem in database management and applications. Approximate field matching is the key solution to resolve the problem by identifying semantically equivalent string values in syntactically different representations. This paper considers token-based solutions and proposes a general field matching framework to generalize the field matching problem in different domains. By introducing a concept of String Matching Points (SMP) in string comparison, string matching accuracy and efficiency are improved, compared with other commonly-applied field matching algorithms. The paper discusses the development of field matching algorithms from the developed general framework. The framework and corresponding …

Hydrogeophysical Investigation At Luxor, Southern Egypt, Ahmed Ismail, Neil Lennart Anderson, J. David Rogers

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Over the past 35 years, the exposed stone foundations of the ancient Egyptian monuments at Luxor have deteriorated at an alarmingly accelerated rate. Accelerated deterioration is attributable to three principal factors: 1) excavation and exposure of foundation stone; 2) construction of the Aswan High Dam; and 3) changes in the regional groundwater regime. In an effort to better elucidate the hydrostratigraphy in the Luxor study area that extends from the River Nile to the boundaries of the Nile Valley and covers about 70 km², a geophysical/hydrological investigation was conducted. Forty Schlumberger vertical electrical soundings (VES), two approximately 6 …

Calibration Of Optical Digital Fragmentation Measuring Systems, Norbert H. Maerz, Wei Zhou

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Optical granulometry systems like WipFrag are required to measure fragments in situ. That is to say, the fragments are in piles where sorting takes place, where fragments are partially overlapped, and where fines may not be seen because they fall in and behind the coarser fragments, or where the fines are simply too small to be seen. As a result, optical systems tend typically to overestimate the size of the distribution, and underestimate the variability of the distribution. The wider the size distribution being measured, the more severe the problem is. This paper presents the results of a study that …

Magma Traps And Driving Pressure: Consequences For Pluton Shape And Emplacement In An Extensional Regime, John Patrick Hogan, Jonathan D. Price, M. Charles Gilbert

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

The level of emplacement and final form of felsic and mafic igneous rocks of the Wichita Mountains Igneous Province, southwestern Oklahoma, U.S.A. Are discussed in light of magma driving pressure, lithostatic load, and crustal magma traps. Deposition of voluminous A-type rhyolites upon an eroded gabbroic substrate formed a subhorizontal strength anisotropy that acted as a crustal magma trap for subsequent rising felsic and mafic magma. Intruded along this crustal magma trap are the A-type sheet granites (length/thickness 100:1) of the Wichita Granite Group, of which the Mount Scott Granite sheet is typical, and smaller plutons of biotite bearing Roosevelt Gabbro. …

Optical Digital Fragmentation Measuring Systems -- Inherent Sources Of Error, Norbert H. Maerz, Wei Zhou

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Automated optical imaging systems of measuring fragmentation are increasingly being used in the mining, comminution, and materials handling industries. These methods have been well received in many of the industries involved. Considering that in many of these applications there are no alternative ways of sizing material, having even a rudimentary measurement of size distributions allows evaluations of explosive, blast design, detonator performance, crusher and milling performance, and material degradation due to transport.

Optical methods have inherent limitations, which reflect on accuracy, precision, and reproducibility of measurement results. This stems from the fact that there are myriads of variables, which affect …

Sporomorphs And Palynological Interpretations Of Lower Oligocene Strata From The Eastern Gulf Coast, U.S.A., Lisa M. Reeves

Opportunities for Undergraduate Research Experience Program (OURE)

The Vicksburg Group in the eastern Gulf Coast of the United States belongs to one of the most complete and continuous Paleogene strata in the world. Previous studies in this region have neglected the rich palynomorph assemblages of the Lower Oligocene units of the Vicksburg Group. Four samples from Wayne County Mississippi were analyzed for palynological information on the Vicksburg Group. The initial objective of the study was to understand the principles of palynology and the basis for sporomorph identification. A minimum of 300 specimens were counted per slide to determine the distribution of sporomorphs in the sediments. Two hundred …

Statistical Analysis Of A Compound Power-Law Model For Repairable Systems, Max Engelhardt, Lee J. Bain

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Conclusions - A compound (mixed) Poisson distribution is sometimes used as an alternative to the Poisson distribution for count data. Such a compound distribution, which has a negative binomial form, occurs when the population consists of Poisson distributed individuals, but with intensities which have a gamma distribution. A similar situation can occur with a repairable system when failure intensities of each system are different. A more general situation is considered where the system failures are distributed according to nonhomogeneous Poisson processes having Power Law intensity functions with gamma distributed intensity parameter. If the failures of each system in a population …

On The Mean Time Between Failures For Repairable Systems, Max Engelhardt, Lee J. Bain

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Much of the recent work on modeling repairable systems involves Poisson processes with nonconstant intensity functions, viz, nonhomogeneous Poisson processes. Since times between failures are not identically distributed when the process is nonhomogeneous, it is not clear what concept should take the place of the mean time between failures in assessing the reliability of a repairable system. A number of alternate concepts can be found in the literature. We investigate the relationship between two of the most frequently considered alternatives: the reciprocal of the intensity function, and the mean waiting time from t until the next failure. Theorem 1 states …

Approximate Tolerance Limits And Confidence Limits On Reliability For The Gamma Distribution, Lee J. Bain, Max Engelhardt, Wei Kei Shiue

Mathematics and Statistics Faculty Research & Creative Works

No abstract provided.