Physical Sciences and Mathematics Commons^™

Ab Initio Studies Of Proton Transport In Proton Exchange Membranes, Jeffrey Keith Clark

Doctoral Dissertations

A molecular-level understanding of the factors that contribute to transport properties of proton exchange membranes (PEMs) for fuel cell applications is needed to aid in the development of superior membrane materials. Ab initio electronic structure calculations were undertaken on various PEM ionomer fragments to explore the effects of local hydration, side chain connectivity, protogenic group separation, and specific side chain chemistry on proton dissociation and transfer at low hydration. Cooperative interactions between both intra- and inter-molecular acidic groups and hydrogen bond connectivity were found to enhance proton dissociation at very low degrees of hydration. The energetics associated with proton transfer …

Synthesis And Characterization Of Magnetic Nanowires Prepared By Chemical Vapor Deposition, Siwei Tang

Doctoral Dissertations

Various metal silicide and germanide magnetic nanowires were synthesized using a home-built CVD [chemical vapor deposition] system. The morphology, composition, and magnetic properties of the nanowires were studied and correlated with growth parameters such as temperature, pressure, time, and source-substrate distance.

One of the compositions targeted for synthesis was MnSi [manganese silicide]. In bulk, this material orders helimagnetically at T_c [curie temperature] = 30K, with a helical pitch of about 20 nm. After extensive study, we learned that the thickness of the silicon dioxide layer on the substrate is a critical parameter for the growth of MnSi nanowires. An …

Structural Analysis Of The Tablerock Thrust Sheet, Grandfather Mountain Window, Northwestern North Carolina: Emplacement Kinematics Of A Large Horse In A Major Thrust System, Ann Elizabeth Walker

Masters Theses

The Tablerock thrust sheet is exposed along the southwestern margin of Grandfather Mountain window in northwestern North Carolina, where it separates basement and cover rocks inside the window from basement thrust sheets of the overriding Blue Ridge-Piedmont megathrust sheet. It is a complex of footwall-derived horses of rifted-margin metasedimentary rocks, including Neoproterozoic to Early Cambrian Chilhowee Group quartzite and phyllite, and Shady Dolomite. Penetrative deformation throughout the Tablerock thrust sheet is defined by an extensively transposed foliation, and strong colinearity between well developed transport lineations and SE/NW-trending tight, isoclinal, and sheath folds. Centimeter- to meter-scale sheath folds are common throughout …