Physical Sciences and Mathematics Commons^™

The Mobility Of Long-Lived Radioisotopes And Their Burial In The Marine Environment, Neil Redmond

Dissertations

Marine sediments record chemical signals that reflect past environmental conditions. It is important to establish how these signals are created and whether they may be altered over time so that they can be useful for reconstructing ocean history. Measurements of uranium isotopes are used as a novel proxy for sedimentary diagenetic processes (Chapter 2). Because ²³⁴U can be ejected from mineral lattice during the decay of ²³⁸U, it creates a pool of U in porewater that is potentially mobilized and then deposited elsewhere in the core. We found that alpha-recoiled ²³⁴U is sensitive to differences in sediment …

Past Ice-Ocean Interactions On The Sabrina Coast Shelf, East Antarctica: Deglacial To Recent Paleoenvironmental Insights From Marine Sediments, Kara J. Vadman

USF Tampa Graduate Theses and Dissertations

The East Antarctic Ice Sheet (EAIS) contains ~53 meters of sea level equivalent (SLE) ice, and observations suggest it is sensitive to ongoing and past climate change. The EAIS has traditionally been considered insensitive to climate perturbations because it is largely grounded above sea level. However, aerogeophysical surveys, oceanographic observations, and models indicate that large areas of the EAIS are grounded below sea level and contain 19.2 m SLE. Marine-based parts of the EAIS are thought to be located on inland-sloping beds that drain through marine terminating outlet glaciers, indicating large areas of the EAIS may be more sensitive to …

Plio-Pleistocene Antarctic Ice-Ocean Interactions In The Ross Sea, Catherine Prunella

USF Tampa Graduate Theses and Dissertations

Warm, intermediate-depth Southern Ocean waters are implicated in recent Antarctic ice mass loss. Direct observations of Antarctic Ice Sheet (AIS) retreat are temporally limited, necessitating paleoceanographic records of ocean-ice interactions during past warm climate intervals. Deepsea and ice-proximal sediments record orbitally-paced glacial-interglacial fluctuations in AIS volume during the Plio-Pleistocene (last 5 million years; Ma), but the total contribution of the AIS and the role of ocean heat in these fluctuations remain unresolved. To address the response of Antarctica’s ice sheets to changing ocean temperatures during the Plio-Pleistocene, International Ocean Discovery Program (IODP) Expedition 374 recovered sediments from the Ross Sea …

Lithological And Geochemical Responses To Abrupt Global And Regional Paleoenvironmental Changes During The Aptian In A Hemipelagic Setting Of The Eastern Iberian Peninsula: A Multi-Proxy Approach, Jander Socorro

FIU Electronic Theses and Dissertations

Intense episodes of environmental perturbations and regionally to globally distributed, oxygen-deprived marine facies characterize the Cretaceous sedimentary record. The Organyà Basin in the Spanish Pyrenees chronicles this period in expanded stratigraphic sequences that enabled high-resolution sampling and detailed analysis of disturbances poorly recorded in more lithologically condensed sections. Here, I present an integrated multi-proxy study aimed at understanding the Basin’s response to changing paleoenvironmental conditions during the early Aptian stage of the Cretaceous.

Results from the El Pui section indicate that large-scale (> 1‰), negative carbon isotope excursions (CIEs) that show no corresponding shifts in local sources of organic matter …

Characterizing The Waters Of 6 Rivers In Upstate New York With A Focus On Physical Hydrology And Controls On Water Quality, Connor Horan

Honors Theses

Rivers are key passageways connecting inland waters to the world’s oceans. They are responsible for the mobilization and transport of nutrients, sediments, and weathered materials. Rivers have been influential in the development of human civilization and are hubs for people and businesses to populate. As our population puts a heavier burden on these waterways, there is a need to better understand the controls on their water quality.

The overarching goal of this research is to improve our understanding of the hydrology and water resources of the Upper Hudson and Mohawk watersheds. This is critical to our understanding of the ecological …

Controls On Deuterium Excess Across Asia, John Bershaw

Geology Faculty Publications and Presentations

Deuterium excess (d-excess) is a second-order stable isotope parameter measured in meteoric water to understand both the source of precipitation and the evolution of moisture during transport. However, the interpretation of d-excess patterns in precipitation is often ambiguous, as changes in moisture source and processes during vapor transport both affect d-excess in non-unique ways. This is particularly true in Asia where continental moisture travels a long distance across diverse environments from unique moisture sources before falling as precipitation. Here, I analyzed published d-excess records from meteoric water throughout Asia to better characterize what influences d-excess values. I conclude that, (1) …

Chemical And Statistical Analysis Of Karst Groundwater Basin Signatures - Springfield, Mo, Benjamin E. Lockwood

MSU Graduate Theses

Springfield, MO is located on the Springfield Plateau physiographic province. The Springfield plateau contains a number of Mississippian aged units and is mainly capped by the Burlington-Keokuk Formation. The Burlington-Keokuk is a highly fossiliferous limestone with nodular and interbedded chert. Beneath the Burlington-Keokuk lies the Elsey, Reeds Spring, and Pierson Formations respectively which comprise the Springfield Plateau aquifer hydrostratigraphic unit. Within the Springfield Plateau aquifer, a well-developed karst system includes springs, sinkholes, and caves. The Springfield Plateau aquifer is the predominant source for springs and seeps in the Springfield area. The purpose of this study was to understand the differences …

Source, Transport, And Age Of Sediment From Cascade Volcano Watersheds To The Nearshore: Insights For Contaminant And Ecological Studies, Renee Takesue, Kathy Conn, Margaret Dutch

Salish Sea Ecosystem Conference

Inputs of sediment and sediment-bound contaminants from urbanized watersheds to the nearshore region are a growing concern as coastal populations increase around the Salish Sea and worldwide. Geochemical sourcing and aging of nearshore sediment is one potential way to: a) distinguish land-derived sediment in nearshore environments, b) gain insights about how sediment and contaminants are redistributed, and c) determine how recently they were deposited. Sediments from Cascade volcanoes have distinct geochemical compositions that allow discrimination between land-derived (volcanic) and marine (lowland) sediment. As sediment is transported by rivers to the nearshore, it adsorbs particle-reactive contaminants and short-lived radionuclides, and the …

Carbon Flux And Weathering Processes In Icelandic Glacial-Fed Rivers, Allison Quiroga

Masters Theses & Specialist Projects

An investigation into the carbon dynamics and weathering processes occurring in Icelandic glacial-fed streams was conducted during the spring to summer seasonal transition in June of 2017. Four major outlet rives were sampled from the glaciers of Gígjökull, Steinsholtsjökull, Sólheimajökull, and Falljökull. Markarfljót, the major river that Gígjökull, Steinsholtsjökull, and many other glaciers drain into, was also sampled. Longitudinal sampling occurred at all sites to capture downstream trends in the hydrogeochemistry and carbon dynamics. Distinct differences in geochemistry between glacier surface meltwater, sub-glacial waters, pro-glacial lake water, and post-mixed downstream samples were evident in the data. Glacier surface streams were …

Geochemistry And Mineralogy Of Late Quaternary Loess In The Upper Mississippi River Valley, Usa: Provenance And Correlation With Laurentide Ice Sheet History, Daniel R. Muhs, E. Arthur Bettis Iii, Gary L. Skipp

United States Geological Survey: Staff Publications

The midcontinent of North America contains some of the thickest and most extensive last-glacial loess deposits in the world, known as Peoria Loess. Peoria Loess of the upper Mississippi River valley region is thought to have had temporally varying glaciogenic sources resulting from inputs of sediment to the Mississippi River from different lobes of the Laurentide Ice Sheet. Here, we explore a new method of determining loess provenance using K/Rb and K/Ba values (in K-feldspars and micas) in loess from a number of different regions in North America. Results indicate that K/Rb and K/Ba values can distinguish loess originating from …

The Geochemistry Of Loess: Asian And North American Deposits Compared, Daniel R. Muhs

United States Geological Survey: Staff Publications

Loess is widely distributed over Asia and North America and constitutes one of the most important surficial deposits that serve as terrestrial records of the Quaternary. The oldest Pleistocene loess in China is likely ∼2.6 Ma, thus spanning much or all of the Pleistocene. In North America, most loess is no older than the penultimate glacial period, with the exception of Alaska, where the record may go back to ∼3.0 Ma. On both continents, loess deposits date primarily to glacial periods, and interglacial or interstadial periods are represented by paleosols. Both glacial and non-glacial sources of silts that comprise the …

A Complex Origin For The Kelso Dunes, Mojave National Preserve, California, Usa: A Case Study Using A Simple Geochemical Method With Global Applications, Daniel R. Muhs, Nicholas Lancaster, Gary L. Skipp

United States Geological Survey: Staff Publications

The Kelso Dune field in southern California is intriguing because although it is of limited areal extent (~100 km2), it has a wide variety of dune forms and contains many active dunes (~40 km2), which is unusual in the Mojave Desert. Studies over the past eight decades have concluded that the dunes are derived primarily from a single source, Mojave River alluvium, under a dominant, westerly-to-northwesterly wind regime. The majority of these studies did not, however, present data to support the Mojave River as the only source.We conducted mineralogical and geochemical studies ofmost of the 14 geomorphically defined dune groups …

Geochemical Evidence For Seasonal Controls On The Transportation Of Holocene Loess, Matanuska Valley, Southern Alaska, Usa, Daniel R. Muhs, James R. Budahn, Gary Skipp, John P. Mcgeehin

United States Geological Survey: Staff Publications

Loess is a widespread Quaternary deposit in Alaska and loess accretion occurs today in some regions, such as the Matanuska Valley. The source of loess in the Matanuska Valley has been debated for more than seven decades, with the Knik River and the Matanuska River, both to the east, being the leading candidates and the Susitna River, to the west, as a less favorable source. We report here new stratigraphic, mineralogic, and geochemical data that test the competing hypotheses of these river sources. Loess thickness data are consistent with previous studies that show that a source or sources lay to …

8000 Years Of Environmental Evolution Of Barrier–Lagoon Systems Emplaced In Coastal Embayments (Nw Iberia), Rita González-Villanueva, Marta Pérez-Arlucea, Susana Costas, Roberto Bao, Xose L. Otero, Ronald J. Goble

Department of Earth and Atmospheric Sciences: Faculty Publications

The rocky and indented coast of NW Iberia is characterized by the presence of highly valuable and vulnerable, small and shallow barrier– lagoon systems structurally controlled. The case study was selected to analyse barrier–lagoon evolution based on detailed sedimentary architecture, chronology, geochemical and biological proxies. The main objective is to test the hypothesis of structural control and the significance at regional scale of any highenergy event recorded. This work is also aimed at identifying general patterns and conceptualizing the formation and evolution of this type of coastal systems. The results allowed us to establish a conceptual model of Holocene evolution …

Nwa 8614: The Least Heated Winonaite, Karla Farley, Alexander M. Ruzicka, Katherine Armstrong

Student Research Symposium

Northwest Africa 8614 is classified as a winonaite on the basis of oxygen isotope ratios, mineralogy, and highly reduced chemistry. Unlike other winonaites, it contains numerous and readily apparent chondrules. Here we discuss various features of NWA 8614 and the possible significance of the meteorite.

Petrological and chemical analyses were performed using optical microscopy with a DM2500 Leica petrographic microscope and a Zeiss Sigma VP-FEG scanning electron microscope (SEM) with a high-efficiency energy dispersive spectrometer (EDS). Oxygen isotopes were analyzed by Karen Ziegler at the University of New Mexico on acid-washed samples to remove terrestrial weathering products.

Owing to the …

Hydroclimatic Shifts In Northeast Thailand During The Last Two Millennia — The Record Of Lake Pa Kho, Sakonvan Chawchai, Akkaneewut Chabangborn, Sherilyn C. Fritz, Minna Väliranta, Carl-Magnus Mörth, Maarten Blaauw, Paul J. Reimer, Paul J. Kusic, Ludvig Löwemark, Barbara Wohlfarth

Department of Earth and Atmospheric Sciences: Faculty Publications

The Southeast Asian mainland is located in the central path of the Asian summer monsoon, a region where paleoclimatic data are still sparse. Here we present a multi-proxy (TOC, C/N, δ13C, biogenic silica, and XRF elemental data) study of a 1.5 m sediment/peat sequence from Lake Pa Kho, northeast Thailand, which is supported by 20 AMS 14C ages. Hydroclimatic reconstructions for Pa Kho suggest a strengthened summer monsoon between BC 170–AD 370, AD 800–960, and after AD 1450; and a weakening of the summer monsoon between AD 370–800, and AD 1300–1450. Increased run-off and a higher nutrient supply after AD …

The Champlain Sea/Lake Champlain Transition Recorded In The Northeast Arm Of Lake Champlain, Usa-Canada, Ashliegh Theresa Belrose

Graduate College Dissertations and Theses

Sediment accumulated on a lakebed archives information about past climate and changes in the regional environment. Previous studies (Burgess, 2007; Koff, 2011; Palmer, 2012) in the Northeast Arm of Lake Champlain, specifically Missisquoi Bay and Saint Albans Bay, showed a period (~9,400 - 8,600 yBP) of elevated organic matter deposition in both bays, indicating a productive event that pre-dated any possible anthropogenic influence. However, the record was abruptly cut off and any documentation representing the span of time leading up to this event was not found. The elevated organic matter levels were explained as being the result of a warm, …

Holocene Paleo-Environmental Variability Reconstructed From A Lake Sediment Record From Southeast Greenland, Gregory A. De Wet

Masters Theses 1911 - February 2014

Arctic climate variability over the Holocene has been both extensive and, at times, abrupt. Current understanding of these changes is still quite limited with few high-resolution paleoclimate records available for this period. In order to place observed and predicted 21^st century climate change in perspective, reliable and highly resolved paleo-reconstructions of Arctic climate are essential. Using an 8.5 m sediment core from Nanerersarpik Lake, this project will characterize climate changes during the Holocene, including the deglacial transition, the rapid changes that are known to have occurred around 8,200 years ago, the transition from Holocene thermal maximum (HTM) to the …

Slides: Impacts Of Oil Shale On Carbon Emissions, Jeremy Boak

The Promise and Peril of Oil Shale Development (February 5)

Presenter: Dr. Jeremy Boak, Center for Oil Shale Technology & Research, Colorado School of Mines

43 slides

State Of The Antarctic And Southern Ocean Climate System, Paul Andrew Mayewski, M. P. Meredith, C. P. Summerhayes, J. Turner, A. Worby, P. J. Barrett, G. Casassa, Nancy Bertler, T. Bracegirdle, A. C. Naveira Garabato, D. Bromwich, H. Campbell, Gordon S. Hamilton, W. B. Lyons, Kirk A. Maasch, S. Aoki, C. Xiao, Tas Van Ommen

Earth Science Faculty Scholarship

This paper reviews developments in our understanding of the state of the Antarctic and Southern Ocean climate and its relation to the global climate system over the last few millennia. Climate over this and earlier periods has not been stable, as evidenced by the occurrence of abrupt changes in atmospheric circulation and temperature recorded in Antarctic ice core proxies for past climate. Two of the most prominent abrupt climate change events are characterized by intensification of the circumpolar westerlies (also known as the Southern Annular Mode) between ∼6000 and 5000 years ago and since 1200–1000 years ago. Following the last …

Ice Core Record Of Rising Lead Pollution In The North Pacific Atmosphere, E. Osterberg, Paul Andrew Mayewski, Karl J. Kreutz, D. Fisher, Michael Handley, Sharon Sneed, C. Zdanowicz, J. Zheng, M. Demuth, M. Waskiewicz, J. Bourgeois

Earth Science Faculty Scholarship

A high-resolution, 8000 year-long ice core record from the Mt. Logan summit plateau (5300 m asl) reveals the initiation of trans-Pacific lead (Pb) pollution by ca. 1730, and a >10-fold increase in Pb concentration (1981–1998 mean = 68.9 ng/l) above natural background (5.6 ng/l) attributed to rising anthropogenic Pb emissions from Asia. The largest rise in North Pacific Pb pollution from 1970–1998 (end of record) is contemporaneous with a decrease in Eurasian and North American Pb pollution as documented in ice core records from Greenland, Devon Island, and the European Alps. The distinct Pb pollution history in the North Pacific …

Application Of Paleoclimatology To Coral Reef Monitoring And Management, C. Mark Eakin, Peter K. Swart, Terrence M. Quinn, Kevin P. Helmle, Jennifer M. Smith, Richard E. Dodge

Marine & Environmental Sciences Faculty Proceedings, Presentations, Speeches, Lectures

The skeletons of reef-building corals are valuable archives of climatic and environmental information. Paleoclimatic data chiefly have been generated in areas most sensitive to global or regional climatic variability. However, these records also provide valuable information on anthropogenic influences – guidance of value to resource managers. NOAA’s Coral Reef Watch targets observations of current and past coral reef health in or near marine protected areas through satellites, in situ sensor platforms, and paleoclimatic analyses. Paleoclimatic data provide retrospective monitoring through multi-century environmental reconstructions that improve our understanding of past stress to coral reefs. Two sites in the Florida Keys National …

Snow Chemistry Across Antarctica, Nancy Bertler, Paul Andrew Mayewski, Alberto Aristarain, P. Barrett, S. Becagli, Ronaldo Torma Bernardo, Xiao Cunde, M. Curran, Qin Dahe, Daniel Dixon, Francisco Adolfo Ferron, H. Fischer, Markus Frey, M. Frezzotti, F. Fundel, Christophe Genthon, R. Gragani, Gordon Hamilton, M. Handley, Sungmin Hong, E. Isaksson, Ren Jiawen, Kokichi Kamiyama, Satoru Kanamori, Eija Karkas, L. Karlöf, S. Kaspari, K. Kreutz, A. Kurbatov, E. Meyerson, Hideaki Motoyama, R. Mulvaney, Zhang Mingjun, H. Oerter, E. Osterberg, M. Proposito, A. Pyne, U. Ruth, Jefferson Cardia Simoes, B. Smith, S. Sneed, Kimmo Teinila, F. Traufetter, R. Udisti, Aki Virkkula, Okitsugu Watanabe, B. Williamson, E. Wolff, Li Zhongqin

Earth Science Faculty Scholarship

An updated compilation of published and new data of major-ion (Ca, Cl, K, Mg, Na, NO₃, SO₄) and methylsulfonate (MS) concentrations in snow from 520 Antarctic sites is provided by the national ITASE (International Trans-Antarctic Scientific Expedition) programmes of Australia, Brazil, China, Germany, Italy, Japan, Korea, New Zealand, Norway, the United Kingdom, the United States and the national Antarctic programme of Finland. The comparison shows that snow chemistry concentrations vary by up to four orders of magnitude across Antarctica and exhibit distinct geographical patterns. The Antarctic-wide comparison of glaciochemical records provides a unique opportunity to improve …

The International Trans-Arctic Scientific Expedition (Itase): An Overview, Paul Andrew Mayewski, Massimo Frezzotti, Nancy Bertler, Tas Van Ommen, Gordon S. Hamilton, Tim H. Jacka, Brian Welch, Markus Frey, Dahe Qin, Jiawen Ren, Jefferson Simões, Michel Fily, Hans Oerter, Fumihiko Nishio, Elisabeth Isaksson, Robert Mulvaney, Per Holmund, Volodya Lipenkov, Ian Goodwin

Earth Science Faculty Scholarship

From its original formulation in 1990 the International Trans-Antarctic Scientific Expedition (ITASE) has had as its primary aim the collection and interpretation of a continent-wide array of environmental parameters assembled through the coordinated efforts of scientists from several nations. ITASE offers the ground-based opportunities of traditional-style traverse travel coupled with the modern technology of GPS, crevasse detecting radar, satellite communications and multidisciplinary research. By operating predominantly in the mode of an oversnow traverse, ITASE offers scientists the opportunity to experience the dynamic range of the Antarctic environment. ITASE also offers an important interactive venue for research similar to that afforded …

Variability In Accumulation Rates From Gpr Profiling On The West Antarctic Plateau, Vandy B. Spikes, Gordon S. Hamilton, Steven A. Arcone, Susan Kaspari, Paul Andrew Mayewski

Earth Science Faculty Scholarship

Isochronal layers in firn detected with ground-penetrating radar (GPR) and dated using results from ice-core analyses are used to calculate accumulation rates along a 100 km across-flow profile in West Antarctica. Accumulation rates are shown to be highly variable over short distances. Elevation measurements from global positioning system surveys show that accumulation rates derived from shallow horizons correlate well with surface undulations, which implies that wind redistribution of snow is the leading cause of this variability. Temporal changes in accumulation rate over 25-185 year intervals are smoothed to along-track length scales comparable to surface undulations in order to identify trends …

Antarctic Oversnow Traverse-Based Southern Hemisphere Climate Reconstruction, Paul Andrew Mayewski

Earth Science Faculty Scholarship

On 2 January 2003, the U.S. component of the International Trans Antarctic Scientific Expedition (U.S. ITASE) (Figure 1) arrived at the South Pole after completing more than 5000 km of oversnow traverses that included much of west Antarctica and a portion of east Antarctica (Figure 2). During the traverses, which were performed from 1999 through 2003, U.S. ITASE focused on collecting data that will allow the reconstruction of sub-annual scale climate variability and changes in the chemistry of the atmosphere over the last 200+ years.

ITASE is a multi-disciplinary research program supported by 19 nations and endorsed by the Scientific …

Chemical Composition Of Fresh Snow On Xixabangma Peak, Central Himalaya, During The Summer Monsoon Season, Shichang Kang, Dahe Qin, Paul Andrew Mayewski, Sharon B. Sneed

Earth Science Faculty Scholarship

The physical and chemical analysis of ice cores recovered from glaciers in the Himalaya provide some of the best records of past climate change in the region (e.g. Qin and others, 2000; Thompson and others, 2000; Kang and others, 2001, 2002). In order to better understand the climatic and environmental records preserved in snow and ice, studies have investigated the precipitation chemistry in the high Himalaya, notably that the northern slopes of the central Himalaya (Mayewski and others, 1986; Jenkins and others 1987) and the southern slopes of the central Himalaya (Shrestha and others, 1997; Marinoni and others, 2001).

High-Precision Dating Of Volcanic Events (A.D. 1301–1995) Using Ice Cores From Law Dome, Antarctica, Anne S. Palmer, Tas D. Van Ommen, Mark A. J. Curran, Vin Morgan, Joe M. Souney, Paul Andrew Mayewski

Earth Science Faculty Scholarship

A record of volcanic activity over the period A.D. 1301–1995 has been extracted from three Law Dome ice cores (East Antarctica). The record dating is unambiguous at the annual level from A.D. 1807 to 1995 and has an uncertainty of ±1 year at A.D. 1301. Signals from 20 eruptions are preserved in the record, including those of two unknown eruptions with acid deposition beginning in A.D. 1810.8 and A.D. 1685.8. The beginning of the ice core signal from the A.D. 1815 Tambora eruption is observed in the austral summer of A.D. 1816/1817. The mean observed stratospheric transport and deposition time …

The Effect Of Spatial And Temporal Accumulation Rate Variability In West Antarctica On Soluble Ion Deposition, K. J. Kreutz, Paul Andrew Mayewski, L. D. Meeker, M. S. Twickler, S. I. Whitlow

Earth Science Faculty Scholarship

Annually‐dated snowpit and ice core records from two areas of West Antarctica are used to investigate spatial accumulation patterns and to evaluate temporal accumulation rate/glaciochemical concentration and flux relationships. Mean accumulation rate gradients in Marie Byrd Land (11–23 gcm⁻²yr⁻¹ over 150 km, decreasing to the south) and Siple Dome (10–18 gcm⁻²yr⁻¹ over 60 km, decreasing to the south) are consistent for at least the last several decades, and demonstrate the influence of the offshore quasi‐permanent Amundsen Sea low pressure system on moisture flux into the region. Local and regional‐scale topography in both regions appears …

Sea Level Pressure Variability In The Amundsen Sea Region Inferred From A West Antarctic Glaciochemical Record, K. J. Kreutz, Paul Andrew Mayewski, I. I. Pittalwala, L. D. Meeker, M. S. Twickler, S. I. Whitlow

Earth Science Faculty Scholarship

Using European Center for Medium-Range Weather Forecasts (ECMWF) numerical operational analyses, sea ice extent records, and station pressure data, we investigate the influence of sea level pressure variability in the Amundsen Sea region on a West Antarctic (Siple Dome) glaciochemical record. Empirical orthogonal function analysis of the high-resolution Siple Dome multivariate ice core chemical time series record (SDEOF1) documents lower tropospheric transport of sea-salt aerosols to the site. During 1985–1994 the SDEOF1 record of high (low) aerosol transport corresponds to anomalously low (high) sea level pressure (SLP) in the Amundsen Sea region. Spatial correlation patterns between ECMWF monthly SLP fields …