Physical Sciences and Mathematics Commons^™

Copper Complexation And Speciation In The Western South And Equatorial Atlantic Ocean, John A. Consolvo

Chemistry & Biochemistry Theses & Dissertations

Presented here are the first data on copper complexation and speciation in the South Atlantic Ocean. Samples were collected at six vertical profile stations and along the surface (1m) transect during the 1996 IOC Baseline Contaminant Survey. Copper complexation measurements were made for the surface transect (1m) samples and three of the six vertical profile stations (1m - ~500m) using differential pulse anodic stripping voltammetry (DPASV) with a thin mercury film, rotating glassy carbon disk electrode (TMFRGCDE).

A strong organic copper complexing ligand (L₁; log K' _cuL1/cu2+ > 11. 8 ± 0 .4) was detected in 57% of all …

Advanced Atmospheric Water Vapor Dial Detection System, Tamer Refaat

Electrical & Computer Engineering Theses & Dissertations

Measurement of atmospheric water vapor is very important for understanding the Earth's climate and water cycle. The remote sensing Differential Absorption Lidar (DIAL) technique is a powerful method to perform such measurement from aircraft and space. This thesis describes a new advanced detection system, which incorporates major improvements regarding sensitivity and size. These improvements include a low noise advanced avalanche photodiode detector, a custom analog circuit, a 14-bit digitizer, a microcontroller for on board averaging and finally a fast computer interface.

This thesis describes the design and validation of this new water vapor DIAL detection system which was integrated onto …

A Taxonomic Evaluation Of The Comatulid Genus Stephanometra (Echinodermata:Crinoidea), Dana Lin Rankin

HCNSO Student Theses and Dissertations

Several genera in the comatulid family Mariametridae are currently ambiguously distinguished on the basis of variations in length and robustness of oral pinnules. Previous descriptions have suggested that at least the genera Stephanometra and Lamprometra are imperfectly distinguishable. A detailed re-examination of morphology coupled with principal component analyses of morphometric data and cladistic analyses provide support for a monophyletic Stephanometra distinct from Lamprometra. A preliminary morphological analysis suggests that Dichrometra and Liparometra should be synonymized with Lamprometra. The six currently recognized species of Stephanometra uniquely share at least one pair of oral pinnules characterized by enlarged size, reduced ambulacral groove …

An Examination Of Gasoline Pollutants From Two-Cycle Marine Engines Within Lake Mead National Recreation Area, Brian Carter

UNLV Theses, Dissertations, Professional Papers, and Capstones

Jet skis are a very popular "toy" to have in the United States. They account for almost a third of all boat sales, and their numbers are growing rapidly. Unfortunately jet skis use two-cycle engines that pollute at unacceptable levels. Jet ski motors can emit up to 25% of its fuel right back into the water. This alarmed me and I wanted to take a deeper look into how bad jet skis pollute Las Vegas' primary water source. Lake Mead. I looked into how a two-cycle engine differs from a regular engine and I looked at the actual pollutants a …

A Longitudinal Assessment Of Temperament In Octopus Bimaculoides, David Loyd Sinn

Dissertations and Theses

Cephalopods, including Octopus spp., are highly intelligent molluscs that play major roles in many marine food webs, both as top-level feeders (Ambrose, 1984) as well as by constituting a major source of protein for the animals above them (Lang, Hochberg, Ambrose, & Engle, 1997). They also are fascinating organisms for behavioral studies, with elaborate repertoires of behavior based on plasticity and learning (Wells, 1962a; 1962b; 1978) which in complexity rivals that of the vertebrates. The study of individual differences in behavior is a facet of behavioral research that has recently gained attention in the literature (Gosling & John, 1999). Traditionally, …

Validation Of The Ionospheric Forecast Model (Ifm) Version 3, Michael D. Scott

Theses and Dissertations

The purpose of this research was to validate the Ionospheric Forecast Model (IFM) Version 3 to assess its suitability and usefulness as an operational tool. The Ionospheric forecast model is a first principles computer model designed to forecast the state of the global ionosphere to 24 hours. The scope was limited to a comparison of the F2 layer critical frequency (foF2) and peak electron density (hmF2) against observed ionosonde data. The model was run with global solar and geomagnetic indices and Information from Digitial Ionospheric Sounding System (DISS) observations as inputs. The DISS observations were input through the Parameterized Real-Time …

An Evaluation Of Microburst Prediction Indices For The Kennedy Space Center And Cape Canaveral Air Station (Ksc/Ccas), Steven N. Dickerson

Theses and Dissertations

A wet-microburst event on 16 August 1994 at the Kennedy Space Center's Shuttle Landing Facility alerted forecasters from the 45th Weather Squadron (45WS), the provider of weather support to the Kennedy Space Center (KSC) and Cape Canaveral Air Station (CCAS), to the challenges of wet-microburst prediction. Although there was no operational impact, this event caused the 45WS to revise their severe thunderstorm forecasting procedures to specifically address microbursts, resulting in the locally developed Microburst-Day Potential Index (MDPI). MDPI provides a several-hour outlook of microburst potential based on the results of the Microburst and Severe Thunderstorm (MIST) project. The 45WS also …

Sensitivity Studies On A Limited Area Mesoscale Model: An Examination Of Lateral Boundary Placement, Grid Resolution And Nesting Type, Robert A. Stenger

Theses and Dissertations

With the advances of computer technology in recent years, limited area mesoscale models are being used to produce operational forecasts on a broader scale worldwide than ever before. The past limitations of computational resources have caused previous research efforts to focus more on model physics, thus creating a gap in the number of sensitivity studies conducted on these models. This research is intended to bridge a gap in the apparent paucity of sensitivity studies on the limited area model (LAM). The Pennsylvania State University/National Center for Atmospheric Research Mesoscale Model 5 was utilized to conduct sensitivity studies on lateral boundary …

A 3d Display System For Lightning Detection And Ranging (Ldar) Data, Michael W. Darwin

Theses and Dissertations

Lightning detection is an essential part of safety and resource protection at Cape Canaveral. In order to meet the unique needs of launching space vehicles in the thunderstorm prone Florida environment, Cape Canaveral has the only operational three- dimensional (3D) lightning detection network in the world, the Lightning Detection and Ranging (LDAR) system. Although lightning activity is detected in three dimensions, the current LDAR display, developed 20 years ago, is two-dimensional. This thesis uses modern three-dimensional graphics, object-oriented software design, and innovative visualization techniques to develop a 3D visualization application for LDAR data.

A Neural Network Solution To Predicting Wind Speed At Cape Canaveral’S Atlas Launch Pad, Kenneth P. Cloys

Theses and Dissertations

This thesis demonstrates the potential for using time-delay neural networks to provide Launch Weather Officers (LWOs) at 45th Weather Squadron (45 WS) with advance warning of wintertime (November-March) peak wind speeds at the Atlas launch pad. The 45 WS provides weather support to the United States space program at Cape Canaveral Air Station, NASA's Kennedy Space Center, and Patrick Air Force Base. Due to the complex wintertime environment produced by the effects of friction and instability, 45 WS LWOs consider wintertime launch pad winds their toughest forecast challenge. Neural networks were developed, trained, and tested using observations of wintertime peak …

Data Warehouse Techniques To Support Global On-Demand Weather Forecast Metrics, Meriellen C. Joga

Theses and Dissertations

Air Force pilots and other operators make crucial mission planning decisions based on weather forecasts; therefore, the ability to forecast the weather accurately is a critical issue to Air Force Weather (AFW) and its customers. The goal of this research is to provide Air Force Weather with a methodology to automate statistical data analysis for the purpose of providing on-demand metrics. A data warehousing methodology is developed and applied to the weather metrics problem in order to present an option that will facilitate on-demand metrics. On-line analytical processing (OLAP) and data mining solutions are also discussed.

Mixed Layer Height Estimates – A Statistical Analysis Of Algorithm Performance, Lisa C. Shoemaker

Theses and Dissertations

The Air Force Technical Applications Center (AFTAC) conducts dispersion transport modeling as part of their mission support for the United States Atomic Energy Detection System. Part of that modeling effort requires knowledge of the height of the mixed layer in the lower atmosphere to determine the vertical extent through which particulates can be distributed. The mixed layer can be estimated by analyzing atmospheric profiles of parameters obtained from observations (e.g., upper air soundings) or atmospheric models. Six mixed layer algorithms were evaluated: Gradient Richardson Number (RICH), Potential Temperature (POTEMP), Potential Instability Mixing Depth (PIMIX), and three variations of the PIMIX …

Extensible Markup Language As A Weather Tool, Michael J. Calidonna

Theses and Dissertations

This thesis is a proof of concept work that will extend the Core Mapping Application Program Interface (CMAPI) components to include weather data. The CMAPI project is headed by Air Force Research Lab (AFRL)/Information Directorate Information Handling Branch (IFEB) at Rome labs in Rome, New York. This work extends the CMAPI project in two distinct areas. The first goal is to figure out how to overlay and display weather data on a dynamically linked Internet platform. This was accomplished by incorporating existing data from the Air Force Weather Agency (AFWA) into the CMAPI program in a static environment. The other …

Use Of Climatology To Predict Maximum Wind Speeds At The Kennedy Space Center And Cape Canaveral Air Station, Lisa K. Coleman

Theses and Dissertations

This thesis uses statistical analysis to forecast the probability of meeting or exceeding the maximum allowable wind speeds for each of the launch pads at the Kennedy Space Center (KSC) and Cape Canaveral Air Station (CCAS). Wind data were collected from the Weather Information Network Display System (WINDS), a collection of 47 meteorological towers located throughout KSC and CCAS, over a period of five winters. A Fortran program was written to calculate conditional probabilities of meeting or exceeding a given threshold speed during eight consecutive one-hour periods, using the current wind direction and peak wind speed as inputs. Forecast probabilities …

Quantifying The Protonospheric Effect On Prism, Kelly B. Doser

Theses and Dissertations

The total electron content (TEC) contribution to a Parameterized Real-time Ionospheric Specification Model (PRISM) calculation has been studied using protonospheric TEC measurements made by Global Positioning Satellites (GPS). Including the protonosphere proved challenging to both the calibration of GPS measurements and execution of PRISM. Though 46 days of GPS measurements were acquired, only 40 were successfully calibrated, and only 35 of those were used in the study. Data issues such as availability and completeness as well as measurement quality affected 6 of the days used. Calibration was done at Pittsburgh by excluding all measurements below 40.750 N. latitude cutoff. This …

Tunable Mid-Ir Optical Parametric Oscillator Using Periodically Poled Rubidum Titanyl Arsenate, Frank J. Glavic

Theses and Dissertations

Tunable sources of coherent radiation are needed for a variety of military and commercial applications, including infrared countermeasures and atmospheric remote sensing. This research investigates a tunable mid-infrared coherent source using periodically-poled rubidium titanyl arsenate (PPRTA) as a quasi-phase matched (QPM) optical parametric oscillator (OPO). The advantages of PPRTA over periodically poled lithium niobate (PPLN) are presented. Quasi-phase matching and periodic poling theory are discussed, along with some important historical results and current developments. Experimental setups for determining threshold, conversion efficiency, pump depletion, and beam quality are presented along with experimental results. The research effort is focused on characterizing PPRTA …

Atmospheric Temperature Profiles By Ground-Based Infrared Spectrometer Measurements, Jon M. Saul

Theses and Dissertations

A method to recover atmospheric temperature profiles using a ground-based Fourier Transform Infrared spectrometer was investigated. The method used a difference form of the radiative transfer equation, a Bomem MR series Fourier Transform Infrared Spectrometer to collect atmospheric radiance values, and the Phillips Laboratory Expert- assisted User Software (PLEXUS) atmospheric radiance model, to recover an atmospheric temperature profile. The method researched uses radiance values from both the spectrometer measurements and the atmospheric model, along with kernel functions calculated by the atmospheric model as input to a difference form of the radiation transfer equation. From this the change in brightness temperatures …

An Intelligent User Interface To Support Air Force Weather Product Generation And Automated Metrics, Darryl N. Leon

Theses and Dissertations

Air Force pilots require dependable weather reports so they may avoid unsafe flying conditions. In order to better gauge the accuracy of its weather products, Air Force Weather has established the requirement for an Air Force-wide automated weather metrics program. Under the guidelines for this program, forecasts will automatically be compared to observed weather to determine their accuracy. Statistics will be collected in the hopes of determining forecast error trends that can be corrected through education and training. In order for the statistical data produced by such a program to draw reliable conclusions about forecast accuracy, however, the correct format …

An Analysis In Cloud-To-Ground Lightning Over Land Versus Water, Elizabeth A. Boll

Theses and Dissertations

Understanding lightning characteristics over land and water is vital to achieving optimal safety and success in Air Force missions. Lightning safety rules are often based on experience rather than a scientific understanding of lightning. Examining lightning characteristics over water and land will assist in a better understanding of lightning and provide answers that can protect human lives and property. Water and land have different compositions and surface conductivity values. A lightning stroke is detected through a change in the electro-magnetic field at the surface. The change in surface conductivity values from land to water can affect the detection of a …

Descriptive And Conditional Climatology For Specific Launch Commit Criteria For Cape Canaveral, Florida, Edward C. Goetz

Theses and Dissertations

In 1987, an unmanned Atlas-Centaur-67 launched from the Cape triggered a lightning discharge that disabled the on-board guidance system and Range Control destroyed the platform. This incident spurred the review and revision of the natural and triggered lightning launch commit criteria (LCC). The LCC are a set of eleven complex rules that are constantly evaluated by the Launch Weather Team (LWT) of 45th Weather Squadron (45WS). Unfortunately, the 45WS LWT does not have either a descriptive or conditional climatology for many of the LCC. This thesis addresses the lightning and the cumulus LCC. A descriptive climatology for both the lightning …

Techniques For Forecasting The Cessation Of Lightning At Cape Canaveral Air Station And The Kennedy Space Center, Michael W. Holmes

Theses and Dissertations

The focus of this research effort is directed toward identifying new methods of forecasting the cessation of lightning along the Central Atlantic Coast of Florida. Cloud-to-ground lightning flashes place Air Force (AF) personnel and assets at risk almost daily at this location. Providing a more accurate method of forecasting the cessation of lightning would allow for safer and more efficient execution of AF operations. A data set consisting of 40 thunderstorm cases was identified within a 90 nautical miles (nmi) region surrounding the Melbourne, Florida WSR-88D (KMLB) site. Each case falls between the months of May and September and the …

Determining The Horizontal Distance Distribution Of Cloud-To-Ground Lightning, Tamara L. Parsons

Theses and Dissertations

This research effort attempted to quantify what constitutes a safe distance when lightning is present. The method used in this research project groups lightning flashes into clusters using spatial and temporal constraints. However, not all flashes meet the time and distance criteria for clustering and remained outside of tile grouped flashes and as such are identified as isolated flashes. These isolated flashes are outliers in the data set, but are precisely the flashes that prove most dangerous. For this reason not only were the distances between each flash and cluster center studied, but also the distances between each isolated flash …

Timing Of Thunderstorm Occurrence For Cape Canaveral, Florida, Thomas G. Renwick

Theses and Dissertations

This research is concerned with improving an existing algorithm to accurately forecast thunderstorm starting times for Cape Canaveral, Florida. This was accomplished by investigating different linear regression techniques than those used in the existing algorithm. The result is three new thunderstorm start time algorithms. The forecast start times of these new algorithms were then compared to actual thunderstorm start times to determine which method produced the most accurate results. The average thunderstorm starting time was also calculated from the data. This time was also compared to actual thunderstorm starting time. Upon examination of the various start times produced, it was …

A Study Of Morning Radiation Fog Formation, Jimmie L. Trigg Jr.

Theses and Dissertations

This research focuses on developing a linear regression formula that forecasters in the Midwest can use to accurately anticipate the formation of radiation fog. This was accomplished in three stages. First a study of the surface and upper air parameters and processes required to develop radiation fog were identified and explored. Next, a linear regression technique was applied to the 23 parameters identified. The top four indicators were then reprocessed and a new linear regression equation was developed. Finally, the new regression equation was compared to an existing fog forecasting technique. The existing forecast technique selected was the 2nd Weather …

Oxygen Isotopes And Metolachlor Residues In Water Samples From A Portion Of The Canajoharie Creek Watershed, Central New York, John M. Nadeau

Geology Theses and Dissertations

Increased ground and surface water contamination has fueled the need for a better understanding of factors affecting hydrogeological settings. Seasonal variability in the recharge of an aquifer can affect the rate and amount of contamination that can occur. Stable isotopes have been previously investigated as tracers to determine flow paths of the water and contaminants. In this study, oxygen isotopes were used to determine the factors that influence seasonal variations in ground and surface water, such as well location, aquifer type, surface water sites, and soil type. Samples were collected from different locations around the Canajoharie Field Site, including wells …

Maturation And Repeat Spawning By American Shad In The York River, Virginia, Kristin L. Maki

Dissertations, Theses, and Masters Projects

No abstract provided.

Field Measurement Of Mixed Grain Size Suspension In The Nearshore Under Waves, Grace M. Battisto

Dissertations, Theses, and Masters Projects

The Sensor Insertion System (SIS) located at the US Army Corps Field Research Facility (FRF) in Duck, NC, allows closely spaced measurements of along-shore velocity and suspended sediment concentration to be collected across the entire surf zone during storms. The SIS infers suspended sand concentration from backscatter off of suspended material using optical backscatter (OBS) sensors. Unfortunately, OBS response is highly sensitive to grain size, including both differences between sand and mud and variations in size within the sand range. As part of this study, ground-truthing measurements were added to the SIS during a storm in October 1997, including measurements …

Effects Of Polychlorinated Biphenyl Exposure On Development And Sexual Differentiation In Ranid Tadpoles, Mary J. Rybitski

Dissertations, Theses, and Masters Projects

The effects of AroclorRTM1242 exposure on developing amphibians were examined by exposing southern leopard frogs, Rana sphenocephala, to a contaminated diet throughout the larval period. Treatment groups consisted of an untreated control, a solvent control, 17beta-estradiol, and three PCB doses (10, 100, and 1000 mug/g). PCB accumulation and biotransformation were examined. Effects of PCB exposure on metamorphosis and sexual differentiation were assessed. PCB accumulation was not statistically different between the egg masses. Levels of PCBs in the tissues differed in a dose related manner. Within treatments, body weight appeared to be the major factor correlated with PCB concentration. Congener patterns …

The Human Factor In Size Selectivity In The Sea Scallop, Placopecten Magellanicus Fishery, Arman O. Kaltayev

Dissertations, Theses, and Masters Projects

No abstract provided.

Synoptic Scale Climatic Forcing Of Multispecies Fish Recruitment Patterns In Chesapeake Bay, Robert J. Wood

Dissertations, Theses, and Masters Projects

Five fishery independent data sets were used to investigate multispecies fish recruitment patterns in Chesapeake Bay (1966--1997). Despite differences in sampling gear, sampled habitat, collection methods, and sampling sites, the strongest multispecies recruitment patterns within each data set (revealed by separate principal components analyses) depict a negative relationship between recruitment of spring spawning anadromous fishes and fall-winter continental shelf spawning species. This pattern dominates both low and high frequency components of the multispecies data. Because these two species groups utilize freshwater and oligohaline reaches of the Bay and its tributaries as springtime nursery areas, this Chesapeake Bay Anadromous-Shelf Spawner (CBASS) …