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Mathematics

Mathematics and Statistics Faculty Publications and Presentations

Optical coatings -- Design and construction

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Full-Text Articles in Physical Sciences and Mathematics

Broadband Moth-Eye Antireflection Coatings On Silicon, Chih-Hung Sun, Peng Jiang, Bin Jiang Feb 2008

Broadband Moth-Eye Antireflection Coatings On Silicon, Chih-Hung Sun, Peng Jiang, Bin Jiang

Mathematics and Statistics Faculty Publications and Presentations

We report a bioinspired templating technique for fabricating broadband antireflection coatings that mimic antireflective moth eyes. Wafer-scale, subwavelength-structured nipple arrays are directly patterned on silicon using spin-coated silica colloidal monolayers as etching masks. The templated gratings exhibit excellent broadband antireflection properties and the normal-incidence specular reflection matches with the theoretical prediction using a rigorous coupled-wave analysis (RCWA) model. We further demonstrate that two common simulation methods, RCWA and thin-film multilayer models, generate almost identical prediction for the templated nipple arrays. This simple bottom-up technique is compatible with standard microfabrication, promising for reducing the manufacturing cost of crystalline silicon solar cells.


Templated Biomimetic Multifunctional Coatings, Chih-Hung Sun, Adriel Gonzalez, Nicholas C. Linn, Peng Jiang, Bin Jiang Feb 2008

Templated Biomimetic Multifunctional Coatings, Chih-Hung Sun, Adriel Gonzalez, Nicholas C. Linn, Peng Jiang, Bin Jiang

Mathematics and Statistics Faculty Publications and Presentations

We report a bioinspired templating technique for fabricating multifunctional optical coatings that mimic both unique functionalities of antireflective moth eyes and superhydrophobic cicada wings. Subwavelength-structured fluoropolymer nipple arrays are created by a soft-lithography-like process. The utilization of fluoropolymers simultaneously enhances the antireflective performance and the hydrophobicity of the replicated films. The specular reflectivity matches the optical simulation using a thin-film multilayer model. The dependence of the size and the crystalline ordering of the replicated nipples on the resulting antireflective properties have also been investigated by experiment and modeling. These biomimetic materials may find important technological application in self-cleaning antireflection coatings.


Templated Fabrication Of Large Area Subwavelength Antireflection Gratings On Silicon, Chih-Hung Sun, Wei-Lun Min, Nicholas C. Linn, Peng Jiang, Bin Jiang Dec 2007

Templated Fabrication Of Large Area Subwavelength Antireflection Gratings On Silicon, Chih-Hung Sun, Wei-Lun Min, Nicholas C. Linn, Peng Jiang, Bin Jiang

Mathematics and Statistics Faculty Publications and Presentations

We report a cheap and scalable bottom-up technique for fabricating wafer-scale, subwavelength-structured antireflection coatings on single-crystalline silicon substrates. Spin-coated monolayer colloidal crystals are utilized as shadow masks to generate metallic nanohole arrays. Inverted pyramid arrays in silicon can then be templated against nanoholes by anisotropic wet etching. The resulting subwavelength gratings greatly suppress specular reflection at normal incidence. The reflection spectra for flat silicon and the templated gratings at long wavelengths agree well with the simulated results using a rigorous coupled wave analysis model. These subwavelength gratings are of great technological importance in crystalline silicon solar cells.


Self-Assembled Biomimetic Antireflection Coatings, Nicholas C. Linn, Chih-Hung Sun, Peng Jiang, Bin Jiang Sep 2007

Self-Assembled Biomimetic Antireflection Coatings, Nicholas C. Linn, Chih-Hung Sun, Peng Jiang, Bin Jiang

Mathematics and Statistics Faculty Publications and Presentations

The authors report a simple self-assembly technique for fabricating antireflection coatings that mimic antireflective moth eyes. Wafer-scale, nonclose-packed colloidal crystals with remarkable large hexagonal domains are created by a spin-coating technology. The resulting polymer-embedded colloidal crystals exhibit highly ordered surface modulation and can be used directly as templates to cast poly(dimethylsiloxane) (PDMS) molds. Moth-eye antireflection coatings with adjustable reflectivity can then be molded against the PDMS master. The specular reflection of replicated nipple arrays matches the theoretical prediction using a thin-film multilayer model. These biomimetic films may find important technological application in optical coatings and solar cells.