Physical Sciences and Mathematics Commons^™

Large-Scale Assembly Of Periodic Nanostructures With Metastable Square Lattices, Chih-Hung Sun, Wei-Lun Min, Nicholas C. Linn, Peng Jiang, Bin Jiang

Mathematics and Statistics Faculty Publications and Presentations

This article reports a simple and scalable spin-coating technique for assembling non-close-packed colloidal crystals with metastable square lattices over wafer-scale areas. The authors observe the alternate formation of hexagonal and square diffraction patterns when the thickness of the colloidal crystals is gradually reduced during spin coating. No prepatterned templates are needed to induce the formation of the resulting metastable crystals with square arrangement. This bottom-up technology also enables the large-scale production of a variety of squarely ordered nanostructures that are consistent with the industry-standard rectilinear coordinate system for simplified addressing and circuit interconnection. Broadband moth-eye antireflection gratings with square lattices …