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Full-Text Articles in Physical Sciences and Mathematics

Atom Trapping And Its Role On The Nucleation & Growth Of Platinum Nanoparticles, Deepak Kunwar Nov 2020

Atom Trapping And Its Role On The Nucleation & Growth Of Platinum Nanoparticles, Deepak Kunwar

Chemistry and Chemical Biology ETDs

Diesel oxidation catalysts deactivate due to Pt sintering, a major problem in automotive industries. To make sure they operate effectively throughout the lifetime of the vehicle, automotive industries are putting an excessive amount of Pt. There is a need to develop a catalyst that serves long term performance with minimal use of Pt. Jones et al.1 demonstrated that ceria traps Pt atoms. His work generated some logical and valid questions such as what is the mechanism for the formation of anomalously large Pt particles? What is the upper limit of Pt metal loading in the form of single atoms …


Methods Of Uncertainty Quantification For Physical Parameters, Kellin Rumsey Jul 2020

Methods Of Uncertainty Quantification For Physical Parameters, Kellin Rumsey

Mathematics & Statistics ETDs

Uncertainty Quantification (UQ) is an umbrella term referring to a broad class of methods which typically involve the combination of computational modeling, experimental data and expert knowledge to study a physical system. A parameter, in the usual statistical sense, is said to be physical if it has a meaningful interpretation with respect to the physical system. Physical parameters can be viewed as inherent properties of a physical process and have a corresponding true value. Statistical inference for physical parameters is a challenging problem in UQ due to the inadequacy of the computer model. In this thesis, we provide a comprehensive …


Mid-Ir Optical Refrigeration And Radiation Balanced Lasers, Saeid Rostami Apr 2020

Mid-Ir Optical Refrigeration And Radiation Balanced Lasers, Saeid Rostami

Optical Science and Engineering ETDs

This dissertation reports recent advances in mid-infrared (mid-IR) optical refrigeration and Radiation Balanced Lasers (RBLs). The first demonstration of optical refrigeration in Ho:YLF and Tm:YLF crystals as promising mid-IR laser cooling candidates is reported. Room temperature laser cooling efficiency of Tm- and Ho-doped crystals at different excitation polarization is measured and their external quantum efficiency and background absorption are extracted. Complete characterization of laser cooling samples is obtained via performing detailed low-temperature spectroscopic analysis, and their minimum achievable temperature as well as conditions to achieve laser cooling efficiency enhancement in mid-IR are investigated. By developing a Thulium-doped fiber amplifier, seeded …