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Photoluminescence Spectroscopy Of Zinc Germanium Diphosphide (Zngep2), Jack E. Mccrae

Theses and Dissertations

Zinc germanium diphosphide (ZnGeP₂) is a chalcopyrite semiconductor with strong nonlinear optical properties and potential application to Air Force interests. The characteristics of this material have been studied using photoluminescence (PL) spectroscopy. The PL spectrum is dominated by transitions from the conduction band to a deep acceptor level, and features in the spectrum suggest that more than one transition is being observed. The PL is partially polarized, and the degree of polarization appears to differ for each feature in the spectrum. The relative PL intensity of these features are seen to depend upon the wavelength of the excitation …