Physical Sciences and Mathematics Commons^™

Synthesis And Electrochemical Characterization Of Alkali Metal Borides As Redox Active Anion Frameworks, Michael R. Shabetai

University of New Orleans Theses and Dissertations

Redox activity in intercalation cathodes is commonly attributed to changes in oxidation states of transition metal ions. Recently, a growing body of evidence revealed that the redox activity of oxygen contributes to the capacity of some known cathodes. We focused on designing an oxygen free intercalation cathode with redox-active anions. In order to overcome the entropic driving force for the decomposition of a charged redox active anion cathode, we looked for chemistries with solid (no gases) possible decomposition products. Additionally, the involvement of anions in a network of covalent bonds with shared electrons was considered as a possible way for …

Synthesis, Derivatives, And Applications Of Structured Nanomaterials, Md Shahidul Islam Khan

University of New Orleans Theses and Dissertations

Nanomaterials offer abundant applications not accessible in regular bulk structures. A nanotubular structure (nanoscroll or nanotube) is a 1D architecture with distinct properties varying from that of the parent material. The new structure for example provides more surface area and presents more active sites on the structure exterior, interior, or edges. In this research, different nanotubular materials were targeted including nanopeapods (NPPs), nanoscrolls (NScs), and their various derivatives.

Halloysite nanotubes (HNT) were used as pod materials to grow noble metal NPs in their lumen. The synthesis was done rapidly, within 2 minutes at 55 ^⸰C. This allows the growth …