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Physical Sciences and Mathematics Commons

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Materials Chemistry

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Journal

1995

Cyclic voltammetry

Articles 1 - 2 of 2

Full-Text Articles in Physical Sciences and Mathematics

The Electrochemical Reduction Of 2-Ethylanthraquinone(2eaq), Yaobin Zhu May 1995

The Electrochemical Reduction Of 2-Ethylanthraquinone(2eaq), Yaobin Zhu

Journal of Electrochemistry

The process of electrochemical reduction of 2EAQ in DMSO is studied using CVand ESR methods in this work, Pt, Pd and some implanted materials are used as electrodes. Thequasi-rever+sible property of two electron transfer steps and their following homogeneous chemicalreactions are illustrated,The mechanism of the electrochemical red uction of 2 EAQ and the kineticparameters of the related steps are obtained. Having measured the influence of water content in thesystem, the effect of the proton donor is discussed. After comparising the experimental results witheach other these experiments gives us the idea that the replacement of metal Pd or some Pd-catalystswith pd-implanted …


The Electrode Process Of Y(Ⅲ)On Copper Electrode And Its Surface Metallizing, Chungen Zhou, Shuzhen Duan Feb 1995

The Electrode Process Of Y(Ⅲ)On Copper Electrode And Its Surface Metallizing, Chungen Zhou, Shuzhen Duan

Journal of Electrochemistry

The reduction of yttrium ion on copper electrode in NaCl-KCl-YCl_3 molten saltshas been investigated.The results indicate that the formation of intermetallic compounds is occuredbefore the metallic yttrium to be formed.The formation of intermetallic compounds is controlled bythe process of which yttrium atoms are diffusing into copper electrode.The kinetic characters todiffusion of yttrium atoms were also discussed.