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Materials Chemistry

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Full-Text Articles in Physical Sciences and Mathematics

A Sodium Salt Of The Dimer Of Boronoterephthalic Acid Anhydride, Scott Simmons, Albert Fratini, Vladimir Benin Mar 2016

A Sodium Salt Of The Dimer Of Boronoterephthalic Acid Anhydride, Scott Simmons, Albert Fratini, Vladimir Benin

Albert Fratini

The title compound, sodium bis­(6-carb­oxy-1-hy­droxy-3-oxo-1,3-dihydro-2,1-benzoxaborol-1-yl)oxidanium, Na+·C16H15B2O13-, was prepared in two steps from 2-bromo-p-xylene. Its crystal structure was determined at 140 K and has triclinic (P) symmetry. The compound presents a unique structural motif, including two units of the cyclic anhydride of boronoterephthalic acid, joined by a protonated, and thereby trivalent, oxonium center. Association in the crystal is realized by complementary hydrogen bonding of the carboxyl groups, as well as by coordination of the sodium cations to the oxygen centers on the five-membered rings.


A Warning For The Wagner Polarization Cell, Michael Setter, J. Akridge, M. Balkanski Dec 1989

A Warning For The Wagner Polarization Cell, Michael Setter, J. Akridge, M. Balkanski

Michael P. Setter

No abstract provided.


A Refined Model For The Space-Charge Layer In Composite Electrolyte Systems, Michael Setter Jul 1986

A Refined Model For The Space-Charge Layer In Composite Electrolyte Systems, Michael Setter

Michael P. Setter

No abstract provided.