Physical Sciences and Mathematics Commons^™

Visible Light Generation And Mechanistic Investigation Of High-Valent Metal-Oxo Species Supported By Different Ligands, Seth Ellis Klaine

Masters Theses & Specialist Projects

Numerous transition metal catalysts have been designed as biomimetic model compounds for the active site of metalloenzymes found throughout Nature, most notably cytochrome P450 monooxygenases that carry out the oxidative transformations of organic substrates with near-perfect chemo-, regio-, and stereo-selectivity. The primary active oxidants in catalytic and enzymatic cycles are fleeting high-valent metal-oxo intermediates where the oxo ligand can transfer to an organic substrate in a process known as oxygen atom transfer (OAT).

In the present work, porphyrin-manganese(III), salen-chromium(III), and salenmanganese( III) derivatives were successfully synthesized and spectroscopically characterized using 1H NMR and UV-Vis spectroscopies. A facile photochemical approach was …

Alfred Russel Wallace Notes 15. Wallace's Many "Hats": What Should We Call Him?, Charles H. Smith

Faculty/Staff Personal Papers

Alfred Russel Wallace (1823−1913) has been referred to by name through the aid of a variety of labels – some thirty or more, in fact – that link him to his emphases of attention. How many of these labels are/were justifiable? The assessment here is that he is probably best remembered as a ‘naturalist,’ ‘geographer,’ ‘evolutionist,’ and ‘social critic.’

A Review And Comparison Of U.S. State Wildlife Action Plans For Stonefly (Insecta, Plecoptera) Species Of Greatest Conservation Need, Kathryn Greene

Mahurin Honors College Capstone Experience/Thesis Projects

State Wildlife Action Plans (SWAPs) were created in order to identify Species of Greatest Conservation Need (SGCN) and develop plans to prevent their populations from further decline and the possibility of being listed as threatened or endangered. Which SGCNs are included are decided based on characteristics that determine their vulnerability. As of early 2021, approximately 720stoneflies (Insecta, Plecoptera) species are found in the U.S., but only 143 are listed as SGCN. Only 29 states have stoneflies included on their SGCN lists, but 37 states use EPT (Ephemeroptera + Plecoptera + Trichoptera) metrics when assessing water quality issues in running water …

Antibiotic Resistant Gene Concentrations In Bacteria In Groundwater From Agricultural Waste, Koji Barnaby

Mahurin Honors College Capstone Experience/Thesis Projects

The overuse of antibiotics has led to an increase in antibiotic resistant bacteria since some antibiotics are sent into the wastewater system by waste produced by both humans and agriculture, making exposure to these bacteria more likely. The evolution of these bacteria in groundwater is of particular concern, as groundwater is used as a source of drinking water, and infections by these bacteria would be more difficult to treat. There are no policies in place to monitor or regulate antibiotic resistance bacteria in groundwater, leaving the threat to public health unknown. The study area of Crumps Cave in Smiths Grove, …

Drought In The Breadbasket Of America And The Influence Of Oceanic Teleconnections, Grace Campbell

Mahurin Honors College Capstone Experience/Thesis Projects

From 1980 to 2020, drought events accounted for 11.4% of the billion-dollar disasters in the United States (U.S.) yet caused the second highest total amount in damages at $236.6 billion. With the average cost of a drought being upwards of $9.5 billion, these natural disasters can create serious problems in agriculture. Drought is defined as a period of below average precipitation that causes damage to agriculture and water supply. Previous research has linked drought events in the U.S. Great Plains to oceanic teleconnections in the Pacific and Atlantic basins, indicating the influence of the El Niño – Southern Oscillation (ENSO), …

Acoustic Communication In The Atlantic Mudskipper, Periopthalmus Barbarus, Seth Hoffman

Mahurin Honors College Capstone Experience/Thesis Projects

Mudskippers are intertidal fishes that can survive both in and out of the water. They are territorial and exhibit behaviors to attract mates and defend against competitors. Recently, it has been shown that vibrations are produced and transmitted through the mud during such displays in one species, Periophthalmodon septemradiatus. To see if similar vibrations are produced in other species of mudskippers, I recorded the behavioral interactions of pairs of the mudskipper Periophthalmus barbarus via digital video and acoustic signals via accelerometer. Comparative analysis of fish mass, sex, contest length, and contest outcome coupled with acoustic characteristics within dyadic pairings …

Synthetic Pathways For Potential Platinum 1,10-Phenanthroline Compounds, Jacob Young

Mahurin Honors College Capstone Experience/Thesis Projects

There are extremely important uses for platinum when it comes to the treatment of cancers and dementias. One potential therapeutic combines platinum with a structure known as phenanthroline. This platinum phenanthroline structure is normally extremely water-insoluble, rendering it difficult to study and use in biological systems. The Williams’ Biochemistry Laboratory endeavored to find a simpler synthetic pathway for a water-soluble phenanthroline product. While unsuccessful in identifying a product as of yet, many synthetic pathways have been ruled out, and more hypothetical pathways are being formulated for testing.

Among the strategies analyzed are varying solvent, reagents, apparatus, methodology, and temperature in …

Informing Sustainable Urban Forestry Policy With Carbon Sequestration Analysis, Ellen Danford

Mahurin Honors College Capstone Experience/Thesis Projects

Urban forestry is an environmental solution for an increasingly city-centered world. The ecosystem services that trees provide in natural settings, including carbon sequestration, oxygen production and aesthetic beauty, also apply in urban settings. Every tree in the Western Kentucky University (WKU) urban forest provides these services and each tree was measured to determine how much carbon they sequestered a year on average between 2015 and 2020. With an interactive map of the forest and its carbon sequestration, the condition of the forest and change over the five year period was analyzed. Comparing the welfare of the forest with the plans …

Enhancing Wku Sustainable Food Systems Through Education And Local Agriculture Development, Chloe Cooper

Mahurin Honors College Capstone Experience/Thesis Projects

In an effort to increase the amount of locally sourced food utilized by dining services at WKU, the Office of Sustainability, WKU Restaurant Group, and the WKU Agriculture & Research Education Center have partnered to establish garden spaces on campus properties. This project developed a detailed plan for implementation of this effort. In addition, this project established a plan to educate students and the local community alike on the benefits of sustainable farming and locally-sourced food, while also creating profiles on local farmers from whom the university could buy crops in order to further supplement items for dining services. Using …