Physical Sciences and Mathematics Commons^™

Cytotoxicity And Mutagenicity Of Disinfection Byproduct Mixtures Formulated Using Free Chlorine And Monochloramine, Yonas Ghebremedhin

Graduate Theses and Dissertations

Bioassays have been used extensively to assess various toxicity endpoints of drinking water disinfection byproducts (DBPs), but an emphasis on single compounds prevails. In this research, DBP mixtures were assessed using a cytotoxicity test with Chinese Hamster Ovary (CHO) cells and an Ames fluctuation test with Salmonella typhimurium TA-98 and TA-100 with and without S9 rat liver homogenate. Seven whole mixture DBP concentrates were formulated using reconstituted natural organic matter (NOM) extracts from the Upper Mississippi River using scaled disinfectant dosing protocols with free chlorine and monochloramine in the presence and absence of added bromide. DBPs were identified by gas …

Determining Water Requirements In Turfgrass Systems, Tyler Quinn Carr

Graduate Theses and Dissertations

Turfgrass lawns are commonly utilized for home and commercial applications because of the aesthetic, environmental, and recreational benefits grasses provide, but many people perceive turfgrass as solely an aesthetic benefit that requires significant water inputs. It is important to identify and use turfgrass cultivars that have known drought tolerance, and also fine-tune and throughout development. A series of field experiments were conducted to determine the water requirements of turfgrass lawn systems with the following objectives: 1) investigate differences in chronic drought resistance and irrigation recommendations among cultivars of Kentucky bluegrass (Poa pratensis L.) and tall fescue (Festuca arundinacea Schreb.) 2) …

Observable Persistent Effects Of Habitat Management Efforts In The Ozark Highlands After 10 Years, Maxwell Carnes-Mason

Graduate Theses and Dissertations

I investigated the lasting impacts of a management plan designed to improve oak regeneration and benefit wildlife in the Ozark Highlands in Madison, Co., AR. To assess the efficacy of the management plan, I used variables relevant to the success and establishment of oak trees. Controlled burns and selective logging were used to thin the canopy, increase ground level productivity, and increase the abundance of small mammals. I used measurements of overstory and understory densities, light availability, and the density of mice in the genus Peromyscus across time to look at the lasting impacts of management. Different treatment plots were …

Strategies To Improve Forage Utilization By Sheep Offered Forage Mixtures, Valens Niyigena

Graduate Theses and Dissertations

In the first experiment, alfalfa and novel endophyte-infected tall fescue (NE+) forages were harvested after a killing frost, then mixed to formulate 4 different treatments; alfalfa alone, 67% alfalfa +33% fescue, 33% alfalfa + 67% fescue, or 100% fescue. After 3 months of storage as silage, Dorper ewe lambs (n = 20; mean BW = 34.7 ± 6.65 kg) were fed silage for ad libitum consumption, using 5 animals per treatment. Increasing the proportion of NE+ tall fescue improved (P < 0.05) silage total acids and lactic acid concentrations and decreased silage ammonia concentration. Digestible dry matter and organic matter intake and nitrogen utilization parameters decreased with increasing inclusion of NE+ in diet. In the second experiment, 16 Dorper ewe lambs (41.8 ± 4.61 kg BW) were assigned to 4 different treatments; alfalfa silage alone (0 g/kg; CONT) or alfalfa silage mixed with chopped sericea lespedeza (SL) hay to provide 90 (LOW), 180 (MED), or 270 g/kg SL (HIGH) on a dry matter basis in a randomized complete block design experiment with 2 period to provide 4 observations per treatment for each experimental period. Increasing the proportion of sericea lespedeza in the diet decreased dry matter and organic matter digestibility but did not affect feed intake. Fecal nitrogen (g/kg N intake) increased linearly (P < 0.01) while urinary N (g/ day and g/ kg of N intake) tended to decreased linearly and quadratically (P ≤ 0.1) with increasing the proportion of SL in diet. In the third experiments, 16 gestating Dorper ewe lambs (49.1 ± 4.61 kg BW) were allocated to 4 treatments; alfalfa silage alone (0% g/kg; CONT) or alfalfa silage mixed with lablab purpureus(LP) hay to provide 90 (LOW), 180 (MED), or 270 g/kg LP (HIGH) on a dry matter (DM) basis, in a randomized complete block design experiment with a total 8 replication per treatment. Supplementation of LP in diet increased quadratically (P ≤ 0.04) forage dry matter, organic matter intake, digestible dry matter and digestible organic matter intake (P < 0.05). Nitrogen apparently absorbed and urinary N both decreased linearly (P < 0.01) with adding more LP hay in diet. Harvesting and mixing alfalfa and fescue after a killing frost improved silage fermentation characteristics and supplementation of tannins from SL and polyphenol from LP altered N excretion.

Key words: lablab, sericea lespedeza, alfalfa silage, nitrogen, sheep.

Probing Of Carbohydrate-Protein Interactions Using Galactonoamidine Inhibitors, Jessica B. Pickens

Graduate Theses and Dissertations

Glycoside hydrolases are ubiquitous and one of the most catalytically proficient enzymes known, and thus understanding their mechanisms are crucial. Most research has focused on the interaction of the glycon of substrates and their inhibitors within the active site of glycoside hydrolases. The inhibitors employed to probe these interactions generally had small aglycons (i.e. a hydrogen atom, amidines, small aliphatic groups, or benzyl groups). Here, the interactions of the aglycon with glycoside hydrolases are examined by probing the active sites with a library of 25 galactonoamidines. The studies described in this dissertation aim to increase the understanding of stabilization of …

Eastern Collared Lizard (Crotaphytus Collaris) Population Declines In Ozark Landscapes: An Assessment Of Environmental Constraints., Casey L. Brewster

Graduate Theses and Dissertations

The Eastern Collared Lizard (Crotaphytus collaris) has experienced extensive population declines over the past half century in the Ozark Mountains. Previous research suggests that glade habitat degradation through woody vegetation encroachment is an important factor resulting in population declines. In this dissertation I used information on time-energy budgets to investigate the link between habitat degradation and shifts in life history traits likely resulting in population declines of Eastern Collared Lizards (Crotaphytus collaris) in the Ozarks. In chapter one, I addressed the influence of dense woody vegetation encroachment on age-specific growth, body size, body condition and reproduction of C. collaris in …

Mammal Species Inventory Using Various Trapping Methods In Zone 4 Of Billy Barquedier National Park, Belize During Rainy Season, Mersady Redding

Animal Science Undergraduate Honors Theses

Belize is a small country, but it is extremely ecologically diverse. Based on the few studies conducted in Belize, the abundance of mammals is low but diversity is high. Particular findings note the number and identity of species differed between four sites in the Maya Mountains of Belize, indicating that a data set from a single site is not representative of the Neotropical region. Insufficient data is available to estimate current species richness of many areas in Belize, including Billy Barquedier National Park (BBNP). The objective of this study was to explore trapping and documentation methods of terrestrial mammals in …

Rotational Tuning Of Transmembrane Helix Properties Based On The Precise Placements Of Aromatic And Charged Residues, Matthew J. Mckay

Graduate Theses and Dissertations

Designed model transmembrane peptides and oriented 2H and 15N solid-state nuclear magnetic resonance (NMR) spectroscopy were used to analyze how simple sequence modifications can influence peptide structure, behavior and dynamics as well as for determining the pKa of glutamic acid at the membrane interface. The GW5,19ALP23 (acetyl-GGALW(LA)6LWLAGA-amide) peptide framework adopts a well-defined tilted orientation in lipid bilayers (DLPC, DMPC and DOPC) and undergoes low amounts of dynamic motion. The sequence was initially modified by moving the Trp residues outwards to positions 4 and 20. This new sequence GW4,20ALP23 (acetyl-GGAW(AL)7AWAGA-amide) displays high amounts of signal averaging of NMR observables caused by …

Asymmetric Synthesis Of The C29-C34 Moiety Of Fragment A Of The Antascomicin B & Thermal Azole Based Claisen Rearrangements, Dharma Theja Nannapaneni

Graduate Theses and Dissertations

The dissertation describes asymmetric synthesis towards C29-C34 moiety of fragment A of the Antascomicin B and Thermal azole based Claisen rearrangements. In chapter 1, we describes asymmetric synthesis towards C29-C34 moiety of fragment A of the Antascomicin B. The non-immunosuppressant Rapamycin, Ascomycin, and Tacrolimus (FK506), strongly binds with FKBP12, the ligand FKBP12 complexes responsible for immunosuppressive activity. Antascomicin B structurally related to Rapamycin, Ascomycin, and Tacrolimus (FK506), binds strongly to FKBP12, yet does not shown immunosuppressive activity. The ligand FKBP12 binding complexes shown to have potent neuroprotective and neurogenerative properties in mouse models of Parkinson’s disease. The linear synthesis of …

Nematode Populations As Affected By Residue And Water Management In A Long-Term Wheat-Soybean Double Crop In Eastern Arkansas, Lucia Emperatriz Escalante Ortiz

Graduate Theses and Dissertations

Soybeans (Glycine max) are one of the major row crops in the United States, particularly in Arkansas. Soybean cyst nematode (SCN, Heterodera glycines) and southern root-knot nematode (RKN, Meloidogyne incognita) are two of the most damaging pests that cause major economic losses in soybeans. Little is known concerning the effects of common and alternative agronomic practices on nematodes in fields with nematode population densities below threshold levels. Therefore, the objective of this study was to evaluate the effects of the combination of tillage (conventional tillage and no-tillage), irrigation (irrigated and non-irrigated), wheat (Triticum aestivum) residue burning (burned and no burned), …

Cost Effectiveness Of Greenhouse Gas Reductions Through Afforestation Of Agricultural Land In The Arkansas Delta, Karli A. Moore

Graduate Theses and Dissertations

Sequestration of atmospheric carbon in forested lands offsets carbon emissions from other industries. Conversion of private lands, particularly agricultural tracts in marginal areas, to forests can bolster carbon abatement. The United States government agencies administer some voluntary, incentive-based programs to encourage landowners to adopt production practices with positive environmental outcomes. This policy stream can be used to increase transition of marginal agricultural land to forests, thereby creating new carbon sinks. We analyze an eleven-county study area in the Arkansas Delta to determine feasibility for a subsidy focused on carbon abatement through afforestation. This study area is significant for two reasons: …

Nesting Success Of Dickcissel (Spiza Americana) And Non-Breeding Grassland Bird Use Of Northwest Arkansas’ Remnant And Restored Tallgrass Prairies, Alyssa L. Derubeis

Graduate Theses and Dissertations

Dwindling populations of North American grassland birds are linked to habitat loss. Tallgrass prairie only covers 3% of its pre-settlement-era range. Small-scale restoration projects attempt to increase acreage for prairie avifauna, and while some breeding grassland species are present at these sites, nesting success and non-breeding use are still largely unknown. Both life history aspects are required for effective grassland bird conservation. My first objective was to access nest success of the Dickcissel (Spiza americana) at two remnant and two restored tallgrass prairies in Northwest Arkansas. From May-August 2017 and 2018, I found 114 nests that I monitored to determine …

Impact Of Excitation-Inhibition Balance/Imbalance On Dynamics Of Cortical Neural Networks, Vidit Agrawal

Graduate Theses and Dissertations

The purpose of this research is to study the implications of Excitation/Inhibition balance and imbalance on the dynamics of ongoing (spontaneous) neural activity in the cerebral cortex region of the brain.

The first research work addresses the question that why among the continuum of Excitation-Inhibition balance configurations, particular configuration should be favored? We calculate the entropy of neural network dynamics by studying an analytically tractable network of binary neurons. Our main result from this work is that the entropy maximizes at regime which is neither excitation-dominant nor inhibition-dominant but at the boundary of both. Along this boundary we see there …

Impact Of Sanitizers On Salmonella Enterica Contamination And Microbial Populations Of Poultry Processing Reuse Water, Andrew Micciche

Graduate Theses and Dissertations

As human populations increase in numbers, access to clean, fresh water is becoming increasingly difficult to balance between agricultural and municipal demands. Water scarcity is a limiting factor of food production in many countries, whether they are emerging or established economies. In conventional poultry processing systems, access to water is particularly critical for the maintenance and disinfection of processing areas, as well as in processing operations such as scalding, chilling, and carcass washing. The need for sustainable alternatives to single-use water supplies is becoming increasingly more urgent, and as a result, the implementation of water reuse in poultry processing plants …

On The Path To A Resilient Urban Food System In A Rural State: A Mixed-Method Needs Assessment Of Urban Producers And County Extension Agents In Arkansas, Catherine Elizabeth Dobbins

Graduate Theses and Dissertations

This project utilized a mixed-method needs assessment approach to urban agriculture in Arkansas, a predominately-rural state. Chapter II was a qualitative study, using semi-structured, in-depth interviews, that investigated the perceptions, needs, and experiences of Arkansas urban farmers and their interactions with the University of Arkansas Division of Agriculture Cooperative Extension Service (CES). Interviews were conducted with 16 urban farmers in Northwest and Central Arkansas. The interview data revealed individualized needs based on the size, years in operation, and mission of each urban farmer interviewed. General needs were determined, such as market pricing, co-ops, and access to appropriate equipment, but generally …

Factors Influencing The Spatial Distribution Of Southern Rust In Corn, Justin Bailey

Graduate Theses and Dissertations

Southern rust caused by the fungus Puccinia polysora (Underwood) is the most economically important foliar disease in corn (Zea mays) (Linnaeus) (Cyperales: Poaceae)) for Arkansas. The objective of this work was to determine distribution of southern rust in corn and to determine factors that may control its distribution.

During the 2017 and 2018 season, seven corn fields in Arkansas were rated for southern rust. After disease confirmation, fields were marked with GPS sample point locations in a grid pattern across the entire field. Ratings for disease severity were taken below, at, and above the ear leaf at each point every …

Producer Preferences For Alternative Irrigation Practices In The Arkansas Delta, Robert Edward Rosene

Graduate Theses and Dissertations

We use a bivariate sample selection model to address peer network effects on participation in and/or intensity of use of land being irrigated by alternative irrigation practices in the state of Arkansas. As groundwater in the state becomes more limited, the use of scientific scheduling, flowmeters, and more efficient row crop water application systems will allow producers to better manage water resources. We find relatively large, positive relationships between belonging to a peer network of the same irrigation practice and participation in that practice. Intensity of use of alternative irrigation techniques is mostly influenced by which crop type the practice …

Analysis And Conservation Of Native Forests At Kessler Mountain Fayetteville, Arkansas, Alan James Edmondson

Graduate Theses and Dissertations

Kessler Mountain in Fayetteville Arkansas has long been recognized for its beauty and natural resources. Parts of Kessler Mountain have been homesteaded and developed in the past, but most of the mountain has remained relatively undisturbed. The planned development of over 4,000 housing units to cover Kessler Mountain stimulated controversy and consideration of other management alternatives. A twist of fate involving an economic recession, a dedicated group of outdoor recreation enthusiasts, and environmental conservationists led to the permanent protection of 384 acres in the Kessler Mountain Regional Park. To help evaluate the natural resources at Kessler Mountain, forest composition, structure, …

Biogeography Of Endemic Dragonflies Of The Ozark-Ouachita Interior Highlands, Wade Alexander Boys

Graduate Theses and Dissertations

A common pattern across many taxonomic groups is that relatively few species are widespread while the majority are restricted in their geographic ranges. Such species distributions are used to inform conservation status, which poses unique challenges for rare or cryptic species. Further, priority status is often designated within geopolitical boundaries, which may include only a portion of a species range. This, coupled with lack of distributional data, has resulted in species being designated as apparently rare throughout some portions of their range, which may not accurately reflect their overall conservation need. The Interior Highlands region of the central United States …

Daily To Seasonal Moisture Signals Present In Sub-Annual Tree-Ring Data, Ian Howard

Graduate Theses and Dissertations

In recent decades, there has been an increase in the development of sub-annual earlywood (EW) and latewood (LW) width tree-ring chronologies that have been used to make long-term inferences about discrete seasonal moisture variability for different regions of North America. This doctoral research developed a new network of EW, LW, and adjusted latewood (LWa) tree-ring chronologies from the western Great Plains. These chronologies were used to reconstruct 300+ years of spring and summer moisture variability over the northern and southern Plains. The reconstructions document new information about the long-term seasonal climate history of the Great Plains, including the unusual nature …

Amphibian And Reptile Community Responses To Forest And Riparian Disturbance, Jacquelyn Christine Guzy

Graduate Theses and Dissertations

Riparian zones are transitional, semi-terrestrial areas regularly influenced by freshwater. These areas serve as dispersal corridors for many animal and plant species and ultimately function as important reservoirs of biodiversity in altered landscapes. While much of the riparian habitat in the United States has been affected by anthropogenic activities, management actions may mitigate potentially negative influences of these activities. For example, Streamside Management Zones (i.e., riparian buffers; SMZs) are commonly implemented within managed forests to protect water quality, but may also provide habitat for riparian-associated wildlife. Yet, little research has rigorously addressed the value of SMZs for wildlife, particularly cryptic …

Feedforward And Feedback Signals In The Olfactory System, Srimoy Chakraborty

Graduate Theses and Dissertations

The conglomeration of myriad activities in neural systems often results in prominent oscillations. The primary goal of the research presented in this thesis was to study effects of sensory stimulus on the olfactory system of rats, focusing on the olfactory bulb (OB) and the anterior piriform cortex (aPC). Extracellular electrophysiological measurements revealed distinct frequency bands of oscillations in OB and aPC. However, how these oscillatory fluctuations help the animal to process sensory input is not clearly understood. Here we show high frequency oscillations in olfactory bulb carry feedforward signals to anterior piriform cortex whereas feedback from the aPC is predominantly …

The Evaluation Of Low-Use-Rate Zinc Fertilization Strategies On Seedling Canopy Coverage, Zn Concentration, Biomass, And Grain Yield, Maxwell David Coffin

Graduate Theses and Dissertations

Zinc (Zn) is the most common micronutrient deficiency in flooded rice (Oryza sativa L.). Some new Zn fertilization methods have been advertised, but have limited research supporting their efficacy. This study mainly compared the effect of Zn-seed treatment rate in combination with other low-use-rate Zn-fertilization methods to the standard of 11 kg Zn ha-1 as ZnSO4 on rice early-season canopy cover, tissue-Zn concentration, and grain yield. A secondary objective evaluated an alternative method (to seed treatment with ZnO) of enhancing seed-Zn concentration using post-heading foliar-Zn application on seedling tissue-Zn concentration and grain yield. For the main objective, rice seed was …

Using Cover Crops To Recycle Nutrients In An Arkansas No-Till Corn System, Kelsey Lynn Hoegenauer

Graduate Theses and Dissertations

Cover crops can provide many benefits to cropping systems including erosion control, weed suppression, and increased soil organic matter. Regardless of the intended goal for using cover crops, the changes to the nutrient flux in a cropping system caused by cover crops retaining and recycling nutrients needs to be considered in order to maximize the productivity of the following commodity crops. This research encompassed complementary greenhouse, field, and laboratory experiments to evaluate nutrient uptake and release by tillage radish (Raphanus sativus) and cereal rye (Secale cereale) cover crops, as well as the subsequent early-season recovery of recycled nutrients by the …

Anthocyanin Stability In Food Products Made With Freeze-Dried Blueberry Powder, Samantha Findley

Food Science Undergraduate Honors Theses

This study evaluated the stability of anthocyanins in six blueberry products (gummy, graham bar, oatmeal bar, rice krispy bar, ice pop and juice) prepared with freeze-dried wild blueberry powder during processing and over eight weeks storage. Total anthocyanins were determined by HPLC before processing and at day 0 and 2, 4, 6, and 8 weeks of storage. Thermal processing of gummy and graham bar products resulted in significant losses of anthocyanins (50% and 31%, respectively). An eight-week storage time also resulted in a significant decrease in anthocyanins (7% to 51%) in products stored at ambient temperature. The ice pop, which …

A Hidden Markov Factor Analysis Framework For Seizure Detection In Epilepsy Patients, Mahboubeh Madadi

Graduate Theses and Dissertations

Approximately 1% of the world population suffers from epilepsy. Continuous long-term electroencephalographic (EEG) monitoring is the gold-standard for recording epileptic seizures and assisting in the diagnosis and treatment of patients with epilepsy. Detection of seizure from the recorded EEG is a laborious, time consuming and expensive task. In this study, we propose an automated seizure detection framework to assist electroencephalographers and physicians with identification of seizures in recorded EEG signals. In addition, an automated seizure detection algorithm can be used for treatment through automatic intervention during the seizure activity and on time triggering of the injection of a radiotracer to …

Cool And Warm Season Climate Signals In Tree Rings From North America, Max Carl Arne Torbenson

Graduate Theses and Dissertations

Earlywood (EW) and latewood (LW) ring-width chronologies have become an increasingly important proxy in paleoclimate reconstructions. These subannual variables can provide estimates of past hydroclimate variability for seasonal windows that total ring-widths cannot resolve. The strength of the relationship between EW and LW series may influence what type of paleoclimate information is embedded within the tree-ring series. High correlations (> 0.70) between EW and LW are recorded for much of the continent but the magnitude of correlation varies greatly across space and species boundaries. Using four LW chronologies from shortleaf pine, the North American conifer species displaying the lowest EW-LW …

Wayne E. Sabbe Arkansas Soil Fertility Studies 2018, Nathan A. Slaton

Arkansas Agricultural Experiment Station Research Series

Rapid technological changes in crop management and production require that the research efforts be presented in an expeditious manner. The contributions of soil fertility and fertilizers are major production factors in all Arkansas crops. The studies described within will allow producers to compare their practices with the university’s research efforts. Additionally, soil-test data and fertilizer sales are presented to allow comparisons among years, crops, and other areas within Arkansas.

Anthocyanin Stability In Food Products Made With Freeze-Dried Blueberry Powder, Samantha R. Findley, Luke Howard

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

This study evaluated the stability of anthocyanins in six blueberry products (gummy, graham bar, oatmeal bar, rice krispy bar, ice pop and juice) prepared with freeze-dried wild blueberry powder during processing and over eight weeks storage. Total anthocyanins were determined by HPLC before processing and at day 0 and 2, 4, 6, and 8 weeks of storage. Thermal processing of gummy and graham bar products resulted in losses of anthocyanins (50 and 31%, respectively). An eight-week storage time also resulted in a decrease in anthocyanins (7 to 51%) in products stored at ambient temperature. The ice pop, which was stored …

Academy Presidents And Institutional Members List, Academy Editors

Journal of the Arkansas Academy of Science

No abstract provided.