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Faculty Publications

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2018

Articles 1 - 9 of 9

Full-Text Articles in Physical Sciences and Mathematics

Metallo-Polyelectrolytes As A Class Of Ionic Macromolecules For Functional Materials, Tianyu Zhu, Ye Sha, Jing Yan, Parasmani Pageni, Md Anisur Rahman, Yi Yan, Chuanbing Tang Oct 2018

Metallo-Polyelectrolytes As A Class Of Ionic Macromolecules For Functional Materials, Tianyu Zhu, Ye Sha, Jing Yan, Parasmani Pageni, Md Anisur Rahman, Yi Yan, Chuanbing Tang

Faculty Publications

The fields of soft polymers and macromolecular sciences have enjoyed a unique combination of metals and organic frameworks in the name of metallopolymers or organometallic polymers. When metallopolymers carry charged groups, they form a class of metal-containing polyelectrolytes or metallo-polyelectrolytes. This review identifies the unique properties and functions of metallo-polyelectrolytes compared with conventional organo-polyelectrolytes, in the hope of shedding light on the formation of functional materials with intriguing applications and potential benefits. It concludes with a critical perspective on the challenges and hurdles for metallo-polyelectrolytes, especially experimental quantitative analysis and theoretical modeling of ionic binding.

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Nickel Exposure Reduces Enterobactin Production In Escherichia Coli, Clorissa L. Washington-Hughes, Geoffrey T. Ford, Alsten D. Jones, Kimberly Mcrae, Franklin Wayne Outten Jul 2018

Nickel Exposure Reduces Enterobactin Production In Escherichia Coli, Clorissa L. Washington-Hughes, Geoffrey T. Ford, Alsten D. Jones, Kimberly Mcrae, Franklin Wayne Outten

Faculty Publications

Escherichia coli is a well- studied bacterium that can be found in many niches, such as industrial wastewater, where the concentration of nickel can rise to low- millimolar levels. Recent studies show that nickel exposure can repress pyochelin or induce pyo-verdine siderophore production in Pseudomonas aueroginosa. Understanding the mo-lecular cross- talk between siderophore production, metal homeostasis, and metal toxicity in microorganisms is critical for designing bioremediation strategies for metal- contaminated sites. Here, we show that high- nickel exposure prolongs lag phase duration as a result of low- intracellular iron levels in E. coli. Although E. coli cells respond to low- …

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Evolving Paradigms In Biological Carbon Cycling In The Ocean, Chuanlun Zhang, Hongyue Dang, Farooq Azam, Ronald Benner, Louis Legendre, Uta Passow, Luca Polimene, Carol Robinson, Curtis A. Suttle, Nianzhi Jiao Jul 2018

Evolving Paradigms In Biological Carbon Cycling In The Ocean, Chuanlun Zhang, Hongyue Dang, Farooq Azam, Ronald Benner, Louis Legendre, Uta Passow, Luca Polimene, Carol Robinson, Curtis A. Suttle, Nianzhi Jiao

Faculty Publications

Carbon is a keystone element in global biogeochemical cycles. It plays a fundamental role in biotic and abiotic processes in the ocean, which intertwine to mediate the chemistry and redox status of carbon in the ocean and the atmosphere. The interactions between abiotic and biogenic carbon (e.g. CO2, CaCO3, organic matter) in the ocean are complex, and there is a half-century-old enigma about the existence of a huge reservoir of recalcitrant dissolved organic carbon (RDOC) that equates to the magnitude of the pool of atmospheric CO2. The concepts of the biological carbon pump (BCP) …

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Facially Amphiphilic Polyionene Biocidal Polymers Derived From Lithocholic Acid, Mitra S. Ganewatta, Md Anisur Rahman, Louis Mercado, Tinom Shokfai, Alan W. Decho, Theresa M. Reineke, Chuanbing Tang Jun 2018

Facially Amphiphilic Polyionene Biocidal Polymers Derived From Lithocholic Acid, Mitra S. Ganewatta, Md Anisur Rahman, Louis Mercado, Tinom Shokfai, Alan W. Decho, Theresa M. Reineke, Chuanbing Tang

Faculty Publications

Bacterial infections have become a global issue that requires urgent attention, particularly regarding to emergence of multidrug resistant bacteria. We developed quaternary amine-containing antimicrobial poly(bile acid)s that contain a hydrophobic core of lithocholic acid in the main-chain. Interestingly, by choosing appropriate monomers, these cationic polymers can form core-shell micelles. These polymers exhibited biocidal activity against both Gram-positive and Gram-negative bacterial species. It is demonstrated that the micelles can deliver hydrophobic antibiotics that functionally have dual antimicrobial activities. Cytotoxicity assays against HeLa cells showed dosage-dependent toxicity for polymers with longer linkers.

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Physical Processes Dictate Early Biogeochemical Dynamics Of Soil Pyrogenic Organic Matter In A Subtropical Forest Ecosystem, Jason Stuart, Russell Anderson, Patrick Lazzarino, Kevin A. Kuehn, Omar R. Harvey May 2018

Physical Processes Dictate Early Biogeochemical Dynamics Of Soil Pyrogenic Organic Matter In A Subtropical Forest Ecosystem, Jason Stuart, Russell Anderson, Patrick Lazzarino, Kevin A. Kuehn, Omar R. Harvey

Faculty Publications

Quantifying links between pyOM dynamics, environmental factors and processes is central to predicting ecosystem function and response to future perturbations. In this study, changes in carbon (TC), nitrogen (TN), pH, and relative recalcitrance (R50) for pineand cordgrass-derived pyOM were measured at 3–6 weeks intervals throughout the first year of burial in the soil. Objectives were to (1) identify key environmental factors and processes driving early-stage pyOM dynamics, and (2) develop quantitative relationships between environmental factors and observed changes in pyOM properties. The study was conducted in sandy soils of a forested ecosystem within the Longleaf pine range of the United …

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Mixing It Up In The Ocean Carbon Cycle And The Removal Of Refractory Dissolved Organic Carbon, Yuan Shen, Ronald Benner Feb 2018

Mixing It Up In The Ocean Carbon Cycle And The Removal Of Refractory Dissolved Organic Carbon, Yuan Shen, Ronald Benner

Faculty Publications

A large quantity of reduced carbon is sequestered in the ocean as refractory dissolved molecules that persist through several circuits of global overturning circulation. Key aspects of the cycling of refractory dissolved organic carbon (DOC) remain unknown, making it challenging to predict how this large carbon reservoir will respond to climate change. Herein we investigate mechanisms that remove refractory DOC using bioassay experiments with DOC isolated from surface, mesopelagic and deep waters of the Atlantic Ocean. The isolated DOC was refractory to degradation by native microbial communities, even at elevated concentrations. However, when the refractory DOC was introduced to a …

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Modeling The Disappearance Of The Neanderthals Using Concepts Of Population Dynamics And Ecology, Michael F. Roberts, Stephen E. Bricher Jan 2018

Modeling The Disappearance Of The Neanderthals Using Concepts Of Population Dynamics And Ecology, Michael F. Roberts, Stephen E. Bricher

Faculty Publications

Current hypotheses regarding the disappearance of Neanderthals (NEA) in Europe fall into two main categories: climate change, and competition. Here we review current research and existing mathematical models that deal with this question, and we propose an approach that incorporates and permits the investigation of the current hypotheses. We have developed a set of differential equations that model population dynamics of anatomically modern humans (AMH) and NEA, their ecological relations to prey species, and their mutual interactions. The model allows investigators to explore each of the two main categories or combinations of both, as well as various forms of competition …

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Site Factors Influence On Herbaceous Understory Diversity In East Texas Pinus Palustris Savannas, Brooke Mccalip, Brian Oswald, Kathryn R. Kidd, Yuhi Weng, Kenneth Farrish Phd Jan 2018

Site Factors Influence On Herbaceous Understory Diversity In East Texas Pinus Palustris Savannas, Brooke Mccalip, Brian Oswald, Kathryn R. Kidd, Yuhi Weng, Kenneth Farrish Phd

Faculty Publications

Longleaf pine (Pinus palustris) savannas were once dominant across the southeastern U.S., including East Texas and parts of western and central Louisiana. The diverse understory associated with these historical savannas may occasionally be seen today, but not often in longleaf pine ecosystems. This project aimed to define east Texas site characteristics that are necessary to support these ecosystems with a dense and diverse herbaceous understory with little to no midstory cover. Fifty-nine plots across three study sites were established to evaluate the influence of overstory cover, basal area, aspect, elevation, and slope on the number of plant genera present. Forest …

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Accuracy Of Unmanned Aerial System (Drone) Height Measurements, Daniel Unger, I-Kuai Hung, David Kulhavy, Yanli Zhang, Kai Busch-Peterson Jan 2018

Accuracy Of Unmanned Aerial System (Drone) Height Measurements, Daniel Unger, I-Kuai Hung, David Kulhavy, Yanli Zhang, Kai Busch-Peterson

Faculty Publications

Vertical height estimates of earth surface features using an Unmanned Aerial System (UAS) are important in natural resource management quantitative assessments. An important research question concerns both the accuracy and precision of vertical height estimates acquired with a UAS and to determine if it is necessary to land a UAS between individual height measurements or if GPS derived height versus barometric pressure derived height while using a DJI Phantom 3 would affect height accuracy and precision. To examine this question, height along a telescopic height pole on the campus of Stephen F. Austin State University (SFASU) were estimated at 2, …

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