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Full-Text Articles in Physical Sciences and Mathematics

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan Aug 2014

Carbon Cycling Dynamics Inferred From Carbon Isotope Sourcing In A Mid-Latitude Karst-Influenced River, Kegan N. Mcclanahan

Masters Theses & Specialist Projects

As ever-increasing levels of carbon dioxide alter the chemistry of the Earth’s atmosphere, understanding the global carbon cycle becomes increasingly important. A particularly important component is the riverine carbon cycle, as rivers are the primary conduits for dissolved inorganic carbon from terrestrial watersheds to ocean basins. Stable carbon isotopes (13C/12C) were collected weekly and input into the mixing model IsoSource to delineate seasonal carbon sourcing along two nested basins in the upper Green River System, Kentucky. In the more siliciclastic upstream catchment, dissolved inorganic carbon (DIC) was primarily derived from soil respiration (34%). Groundwater dissolving carbonate bedrock and carbonate dissolution/precipitation …


Geochemistry And Stable Isotopes Of Surface Water And Groundwater In The Continental Pit In Butte, Montana, Usa, Amber Mcgivern Jul 2014

Geochemistry And Stable Isotopes Of Surface Water And Groundwater In The Continental Pit In Butte, Montana, Usa, Amber Mcgivern

Graduate Theses & Non-Theses

The Continental porphyry Cu‐Mo mine, located 2 km east of the famous Berkeley Pit lake of Butte, Montana, contains two small lakes that vary in size depending on mining activity. In contrast to the acidic Berkeley Pit lake, the Continental Pit waters have near-neutral pH and relatively low metal concentrations. The main reason is geological: whereas the Berkeley Pit mined highly‐altered granite rich in pyrite with no neutralizing potential, the Continental Pit is mining weakly‐altered granite with lower pyrite concentrations and up to 1‐2% hydrothermal calcite. The purpose of this study was to gather and interpret information that bears on …


Isotopic Fingerprinting Of Shallow And Deep Groundwaters In Southwestern Ontario And Its Applications To Abandoned Well Remediation, Mitchell E. Skuce Mar 2014

Isotopic Fingerprinting Of Shallow And Deep Groundwaters In Southwestern Ontario And Its Applications To Abandoned Well Remediation, Mitchell E. Skuce

Electronic Thesis and Dissertation Repository

Abandoned hydrocarbon wells in southwestern Ontario can act as conduits for Sulphur water, brines, and hydrocarbons from deep Paleozoic bedrock aquifers. Such leakage may pose a threat to shallow groundwater and the environment. Cost-effective plugging of these wells requires knowledge of the sources of the leaking fluids. This study characterizes the isotopic compositions (δ18OH2O, δ2HH2O, δ34SSO4, δ18OSO4, δ13CDIC, 87Sr/86Sr) of groundwaters in the region, which are distinct in different bedrock formations. A Bayesian mixing model was applied to these data to develop a tool for identifying the source(s) of leaking fluids. The geochemical data also improve our understanding of groundwater …