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Articles 1 - 22 of 22
Full-Text Articles in Physical Sciences and Mathematics
Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery
Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery
Earth and Planetary Sciences ETDs
The 1.2 Ma Valles Caldera in north-central New Mexico hosts a young igneous volcanic hydrothermal system after the model proposed in Goff and Janik (2000). The Sulphur Springs area within Valles Caldera is an acid-sulfate area typical of this model, discharging acidic waters (pH 1.5-3) formed by oxidation of magmatic H2S at the surface. We report on samples obtained from springs and streams collected between October 2021 and May 2023 in the Sulphur Creek and Alamo watersheds. Sulphur Creek receives input from Sulphur Springs and exhibits low pH (2-4) and high concentrations of Al (≤110 mg/L), Fe (≤60 …
Metagenomic Investigation Of Microbial Dark Carbon Fixation, Viral Interactions, And Horizonal Gene Transfer Within A Convergent Margin Subsurface Ecosystem, Timothy Joseph Rogers
Metagenomic Investigation Of Microbial Dark Carbon Fixation, Viral Interactions, And Horizonal Gene Transfer Within A Convergent Margin Subsurface Ecosystem, Timothy Joseph Rogers
Doctoral Dissertations
Convergent margins are geological regions where two or more tectonic plates collide, and the denser “subducting slab” is pushed beneath the less dense overriding plate. As the slab descends, it devolatilizes under higher temperatures and pressures, allowing dissolved inorganic carbon (DIC) and redox active volatile rich fluids to cycle between the upper crust and Earth’s mantle. These fluids migrate through cracks and fissures in the upper mantle and crust, fueling chemolithoautotrophy-based microbial ecosystems in the subsurface before they are expelled on the surface in the form of hydrothermal seeps and springs. Chemolithoautotrophic ecosystems, such as those in the Costa Rican …
Understanding The Connection Between Gypsum Blooms And Human Health At The Salton Sea, Isabel Ichiyama
Understanding The Connection Between Gypsum Blooms And Human Health At The Salton Sea, Isabel Ichiyama
Undergraduate Honors Theses
The Salton Sea is a closed hypersaline lake in Southern California that has been receiving little input over the past few decades, leading to desiccation that is rapidly increasing every year. This large-scale evaporation of the sea has led to increased dissolved solutes, high salinity, and gypsum blooms. Gypsum blooms, the precipitation of gypsum (CaSO42H2O) in the sea, have been a prominent facet of the sea and their distribution is well known. However, much of their chemistry and potential health hazards are still undetermined. Potential health effects from gypsum salt, an atmospheric dust particle present at the sea, have known …
Geochemical Analysis And Numerical Modeling Of Central And East Tennessee Mississippi Valley-Type Ore Districts: Constraints On Ore Genesis, Jackson Price Copeland
Geochemical Analysis And Numerical Modeling Of Central And East Tennessee Mississippi Valley-Type Ore Districts: Constraints On Ore Genesis, Jackson Price Copeland
Geosciences Undergraduate Honors Theses
A simple two-way stochastic mixing model is presented for analysis of the lead (Pb) isotope compositions of the North American Mississippi Valley-Type (MVT) districts of East Tennessee, Central Tennessee, and Central Kentucky. Four distinct mixing scenarios were run to critically evaluate the stochastic model and examine different hypotheses regarding the genesis of Central Tennessee and Central Kentucky MVT deposits. Additionally, Pb isotope analysis was conducted on sphalerite samples from the Central and East Tennessee MVT districts. Model and sampling results suggest that Central Tennessee and Central Kentucky ores likely formed by mixing of three fluids. In contrast to conclusions from …
A Geochemical And Statistical Investigation Of The Big Four Springs Region In Southern Missouri, Jordan Jasso Vega
A Geochemical And Statistical Investigation Of The Big Four Springs Region In Southern Missouri, Jordan Jasso Vega
MSU Graduate Theses
The Big Four Springs region hosts four major first-order magnitude springs in southern Missouri and northern Arkansas. These springs are Big Spring (Carter County, MO), Greer Spring (Oregon County, MO), Mammoth Spring (Fulton County, AR), and Hodgson Mill Spring (Ozark County, MO). Based on historic dye traces and hydrogeological investigations, these springs drain an area of approximately 1500 square miles and collectively discharge an average of 780 million gallons of water per day. The rocks from youngest to oldest that are found in Big Four Springs region are the Cotter and Jefferson City Dolomite (Ordovician), Roubidoux Formation (Ordovician), Gasconade Dolomite …
High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon
Masters Theses
Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …
Isotopic And Geochemical Tracers Of Groundwater Flow In The Shivwits Plateau, Grand Canyon National Park, Jonathan W. Wilson
Isotopic And Geochemical Tracers Of Groundwater Flow In The Shivwits Plateau, Grand Canyon National Park, Jonathan W. Wilson
Theses and Dissertations--Earth and Environmental Sciences
As the impacts of global climate change on water resources continue to become more apparent, proper understanding and management of groundwater resources will be needed as supplies become more strained. Traditional methods of characterizing groundwater systems are time-intensive, costly, and can be difficult to complete in remote areas. Using ambient geochemical tracers from discrete sampling could aid in characterizing spring systems through determining flow paths, recharge areas, and carbon cycling. However, using discrete seasonal samples to understand the hydrogeology of complex, mixed-lithology aquifers has not been extensively examined. Here we explore using δ13C of dissolved organic carbon (DOC), …
The Paleozoic Sedimentary Rocks Of The Ouachita Mountains And Their Genetic Relationship To The Mississippi Valley-Type Mineralization In The Southern Ozark Region: Insights From Radiogenic Pb Isotopes And Trace Elements Studies, Christophe Wakamya Simbo
The Paleozoic Sedimentary Rocks Of The Ouachita Mountains And Their Genetic Relationship To The Mississippi Valley-Type Mineralization In The Southern Ozark Region: Insights From Radiogenic Pb Isotopes And Trace Elements Studies, Christophe Wakamya Simbo
Graduate Theses and Dissertations
Cluster of Pb and/or Zn deposits of the well-known Tri-State and Northern Arkansas Mississippi Valley Type (MVT) districts located north of the Arkoma basin and the Ouachita fold-thrust belt in north America are genetically connected to the Pennsylvanian-Permian Ouachita orogeny which triggered a South-North topographic gradient flow of basinal brines, leaching metal rich sediments en route. The objective of the research is twofold. First, to ascertain whether the organic-rich shales and sandstones from the study area provided metals during the mineralization event, which was coeval with the Ouachita orogeny. Second, to assess the depositional environment of the potential source rocks, …
Natural Salinization Of The Jemez River, New Mexico: An Insight From Trace Element Geochemistry, Jon K. Golla
Natural Salinization Of The Jemez River, New Mexico: An Insight From Trace Element Geochemistry, Jon K. Golla
Earth and Planetary Sciences ETDs
The Jemez River, a tributary of the Rio Grande in north-central New Mexico, receives thermal water input from the geofluids of the Valles Caldera, an active, high-temperature, liquid-dominated geothermal system. We focus on a ∼50-km portion of the northern Jemez River. This research extends previous decadal work (Crossey et al., in prep., 2013) on major chemistry in the river by characterizing the response of 16 trace elements to geochemical contributions from geothermal waters (McCauley, Spence, Soda Dam, and Jemez Springs springs and San Ysidro mineral waters), an area with copious hydrothermal degassing (Hummingbird), and two major tributaries (Rio San Antonio …
Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna
Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna
Theses and Dissertations--Earth and Environmental Sciences
Understanding how karst aquifers store and transmit water and contaminants is an ongoing problem in hydrogeology. Flowpath and recharge heterogeneity contribute to the complexity of these systems. This thesis explores karst-conduit connectivity and water chemistry variability in the Houzhai catchment in Guizhou province, China. Artificial tracer tests were conducted during both the monsoon and dry seasons to understand temporal variability in connectivity and water velocity between karst features. Multiple flowpaths through the catchment are activated during the monsoon season and partially abandoned during the dry season. Additionally, gradient reversals during monsoonal high-flow events and as a result of pumping can …
Chemical And Statistical Analysis Of Karst Groundwater Basin Signatures - Springfield, Mo, Benjamin E. Lockwood
Chemical And Statistical Analysis Of Karst Groundwater Basin Signatures - Springfield, Mo, Benjamin E. Lockwood
MSU Graduate Theses
Springfield, MO is located on the Springfield Plateau physiographic province. The Springfield plateau contains a number of Mississippian aged units and is mainly capped by the Burlington-Keokuk Formation. The Burlington-Keokuk is a highly fossiliferous limestone with nodular and interbedded chert. Beneath the Burlington-Keokuk lies the Elsey, Reeds Spring, and Pierson Formations respectively which comprise the Springfield Plateau aquifer hydrostratigraphic unit. Within the Springfield Plateau aquifer, a well-developed karst system includes springs, sinkholes, and caves. The Springfield Plateau aquifer is the predominant source for springs and seeps in the Springfield area. The purpose of this study was to understand the differences …
Qualitative And Quantitative Analysis Of Carbonate Waters In The Peters Mountain Region Of Monroe County, Wv, Emily A. Bausher
Qualitative And Quantitative Analysis Of Carbonate Waters In The Peters Mountain Region Of Monroe County, Wv, Emily A. Bausher
Graduate Theses, Dissertations, and Problem Reports
Water in Monroe County, WV is used extensively for public and private supply and requires quantification, chemical analysis, and assessment for contamination susceptibility. Over 250 springs were previously identified in the eastern side of Monroe County on or near Peters Mountain; 14 were continuously monitored in this study. Springs were grouped based on geologic and spatial distribution: interbedded clastic-rock springs on the mountain flanks, carbonate springs in the valley, and a thermal spring associated with the St. Clair thrust fault. Clastic and carbonate springs have calcium-magnesium-bicarbonate chemistries, neutral pHs and high alkalinities; the thermal spring has calcium-magnesium-sulfate-carbonate chemistry, low pH, …
Using Strontium Isotopes In Conjunction With Major, And Trace Elements To Identify Water/Rock Interaction In The Upper Kittitas County, Washington, James Patterson, Carey Gazis
Using Strontium Isotopes In Conjunction With Major, And Trace Elements To Identify Water/Rock Interaction In The Upper Kittitas County, Washington, James Patterson, Carey Gazis
All Master's Theses
The complex bedrock lithologies in the Upper Kittitas County provide an ideal setting for developing isotopic methodology to identify groundwater sources and track flow paths through water-rock interaction. A wide range of 87Sr/86Sr (0.7040 to 0.7068) in surface waters, springs, and groundwater from wells was found, allowing for identification of the individual signatures of lithologic units. Rock leachates from different lithology were compared to water samples to determine a general 87Sr/86Sr signature of the water-rock interaction for that lithology. The signatures identified were systematically lower than their associated waters, but similar enough to identify the expected 87Sr/86Sr of water-rock interaction …
Geochemical Attributes Of Hydraulically Active Fractures And Their Influence On Groundwater Quality, Amy L. Hudson
Geochemical Attributes Of Hydraulically Active Fractures And Their Influence On Groundwater Quality, Amy L. Hudson
Doctoral Dissertations
This study utilized discrete interval diffusion sampling of a fractured bedrock well completed in schist to investigate if a natural weathering signal can be used to identify hydraulically active fractures. The open borehole well MFS-1, is the focus of the study, which is in close proximity to the recharge zone making it ideal for testing the hypotheses of this study. The hydraulically active fractures of Well MFS-1 were identified, and the dominant mixing force of the water column of the well was determined to be thermal convection in the upper portion of the well and upward gradients. The isotopic data …
An Investigation Of Hydrogeologic, Stratigraphic, And Structural Controls On Acer Grandidentatum Communities In A Karst Landscape, Owl Mountain Province, Fort Hood Military Installation, Texas, Melinda S. Faulkner
Electronic Theses and Dissertations
The Owl Mountain Province is located within the Fort Hood Military Installation, an approximately 880 km2 installation established in the 1940s in Bell and Coryell counties, Texas, which has undergone extensive land use changes associated with military training, maintaining much of the vegetation in early succession. This study investigates thelithologic, stratigraphic, and structural controls on the hydrologic, hydrogeologic, and geomorphologic evolution of the Owl Mountain Province as expressed by mesic vegetation communities, including Pleistocene relicts Acer grandidentatum, within karst terrains. These systems exhibit complexly overprinted speleogenetic evolutions within a dynamic groundwater regime resulting from regional climate shifts throughout the …
Natural Acid Rock Drainage And Ferricrete Deposit Chemistry Of The Judith Mountains, Montana, Sara Edinberg
Natural Acid Rock Drainage And Ferricrete Deposit Chemistry Of The Judith Mountains, Montana, Sara Edinberg
Graduate Theses & Non-Theses
The Judith Mountains are a low-elevation “island” mountain range in east-central Montana composed of a series of laccoliths and stocks cut by coarse-grained alkali granite and tinguaite dikes. The geology of the Judith Mountains in the vicinity of Red Mountain and Judith Peak, two of the tallest mountains in the range, is conducive to the creation of headwater streams that are naturally acidic. Extensive limonite staining on Red Mountain attests to the widespread presence of disseminated pyrite in hydrothermally altered porphyry rock. However, no major historical mining operations are known to the area. The acidic streams undergo neutralization in pH …
Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin
Metal Mobilization In Groundwater, Bauxite, Ar, Steven Alexander Hamlin
Graduate Theses and Dissertations
The Wilcox Aquifer of Bauxite, AR contains bauxite ore deposits that may contribute heavy metals to groundwater. Twenty-four wells were sampled for aluminum, iron, manganese, zinc, lead, barium, nitrate, sulfate, sodium, alkalinity, calcium, magnesium, chloride, pH, total organic carbon, and total dissolved solids. A Wilcoxon Rank-Sum compared the similarity of the three geographic areas covered in the study. All parameters for wells in Bauxite and Sardis failed to reject the null hypothesis, signifying that wells all occupy the Saline Formation. 2/3rds of the parameters from BFI261 and the Bauxite region did not agree, suggesting the two areas do not occupy …
Geochemistry And Stable Isotopes Of Surface Water And Groundwater In The Continental Pit In Butte, Montana, Usa, Amber Mcgivern
Geochemistry And Stable Isotopes Of Surface Water And Groundwater In The Continental Pit In Butte, Montana, Usa, Amber Mcgivern
Graduate Theses & Non-Theses
The Continental porphyry Cu‐Mo mine, located 2 km east of the famous Berkeley Pit lake of Butte, Montana, contains two small lakes that vary in size depending on mining activity. In contrast to the acidic Berkeley Pit lake, the Continental Pit waters have near-neutral pH and relatively low metal concentrations. The main reason is geological: whereas the Berkeley Pit mined highly‐altered granite rich in pyrite with no neutralizing potential, the Continental Pit is mining weakly‐altered granite with lower pyrite concentrations and up to 1‐2% hydrothermal calcite. The purpose of this study was to gather and interpret information that bears on …
Isotopic Fingerprinting Of Shallow And Deep Groundwaters In Southwestern Ontario And Its Applications To Abandoned Well Remediation, Mitchell E. Skuce
Isotopic Fingerprinting Of Shallow And Deep Groundwaters In Southwestern Ontario And Its Applications To Abandoned Well Remediation, Mitchell E. Skuce
Electronic Thesis and Dissertation Repository
Abandoned hydrocarbon wells in southwestern Ontario can act as conduits for Sulphur water, brines, and hydrocarbons from deep Paleozoic bedrock aquifers. Such leakage may pose a threat to shallow groundwater and the environment. Cost-effective plugging of these wells requires knowledge of the sources of the leaking fluids. This study characterizes the isotopic compositions (δ18OH2O, δ2HH2O, δ34SSO4, δ18OSO4, δ13CDIC, 87Sr/86Sr) of groundwaters in the region, which are distinct in different bedrock formations. A Bayesian mixing model was applied to these data to develop a tool for identifying the source(s) of leaking fluids. The geochemical data also improve our understanding of groundwater …
Assessment And Conceptualization Of Groundwater Flow In The Edwards Aquifer Through The Knippa Gap In Uvalde County, Texas, Jennifer Raye Adkins
Assessment And Conceptualization Of Groundwater Flow In The Edwards Aquifer Through The Knippa Gap In Uvalde County, Texas, Jennifer Raye Adkins
Graduate Theses and Dissertations
The Edwards aquifer is one of the major regional karst aquifers in the United States, with an average withdrawal of 950 million liters per day (L/d). This investigation focuses on the connection between the Uvalde pool and the San Antonio pool of the Edwards aquifer, known as the Knippa Gap, west of the San Antonio metropolitan area in Uvalde County. This is a major zone of recharge to the Edwards aquifer and is approximately 6.4 km wide. The Knippa Gap is bounded by northeast trending faults of the Balcones Fault Zone (BFZ) on the north (specifically the Cooks and Trio …
Geochemical Constraints On Groundwater Recharge In The Royal Slope Area, Grant County, Washington, Zoe Danielle Weis
Geochemical Constraints On Groundwater Recharge In The Royal Slope Area, Grant County, Washington, Zoe Danielle Weis
All Master's Theses
Groundwater, the primary source for potable water in the Columbia Plateau, has experienced significant declines over the past 25 years. Groundwater geochemistry and multivariable statistics were employed to identify and characterize the hydrofacies present, constrain recharge sources, and assess mixing of groundwater in the Royal Slope area of the Columbia Plateau. Geochemical analyses for major ions, stable isotopes, and radiogenic isotopes (14C and tritium) for age dating were performed on groundwater samples collected in 2010 from 24 wells in the study area. The results confirmed that the groundwater evolution in the study area follows the typical Columbia River Basalt Group …
Implications Of Surface Runoff Recharge In Semi-Arid Regions On Groundwater Sustainability, Omar M. Al-Qudah
Implications Of Surface Runoff Recharge In Semi-Arid Regions On Groundwater Sustainability, Omar M. Al-Qudah
Open Access Theses & Dissertations
Amargosa Desert, Nevada regional groundwater studies show that the surface runoff infiltration occurring in the arroyos following runoff producing storms, and this infiltration is considered to be a major source of groundwater recharge. Groundwater infiltration through alluvium was investigated in the Amargosa Desert using borehole drill cuttings, groundwater chemistry, and applying a novel method for collecting runoff water. The sampling process included sediment, precipitation, and runoff water. In total, 176 runoff, 182 sediment, and 45 precipitation samples were collected between January, 2009 and January, 2011.Water chemistry, chloride concentrations, and stable isotopes of water collected from specially designed runoff samplers, placed …