Physical Sciences and Mathematics Commons^™

Terrestrial Craters As Analogues For Degraded Craters On Titan, Taylor M. Duncan

Electronic Thesis and Dissertation Repository

Besides Earth, Titan is the only planetary body in our Solar System to currently have flowing liquid on its surface. Previous works note that dendritic and rectangular stream networks are present on a global scale on Titan, but do not map networks in the vicinity of Titan’s impact craters: Selk and Sinlap. The objective of this work is to understand how stream networks form adjacent to Titan’s impact craters. This information will inform future missions to Titan (i.e., Dragonfly) about the fluvial morphology of streams near their landing site. I conduct an analogue study with the stream networks at three …

Reconstructing Carbon Dynamics Of Alpine And Temperate Zone Lakes Using Stable Isotopic Analysis, Rebecca M. Doyle

Electronic Thesis and Dissertation Repository

Lake sediments integrate signals from the catchment, atmosphere and water column, offering a unique window through which to view changes in the carbon cycle. Carbon dynamics in lakes are changing due to nitrogen loading and anthropogenic climate warming (ACW), threatening the water quality of lakes. This thesis identifies how the carbon dynamics of lakes have responded to anthropogenically-driven forcings by comparing pre- and post- AD 1850 records preserved in lake sediments. First, the carbon dynamics of Barry Lake (Ontario, Canada), a low-elevation temperate lake, are investigated. Effective moisture (the net of water inputs and evaporation) is reconstructed using the carbon …

Quantification Of Septic System Contribution To Nutrient Loads In Surface Waters, Archana Tamang

Electronic Thesis and Dissertation Repository

Freshwater systems worldwide are threatened by excessive nutrient (nitrogen and phosphorus) loading. This study evaluated the contribution of septic systems to stream nutrient loads in nine subwatersheds. Stream sampling was conducted during low and high discharge conditions, with samples analyzed for total phosphorus (TP), soluble reactive phosphorus (SRP), nitrate (NO₃-N), and acesulfame (ACE; wastewater tracer). Higher septic effluent reached the subwatershed outlets during high discharge conditions. Subwatersheds with newer households had a lower percentage of septic effluent reaching the stream compared with subwatersheds with older households. Seasonal and event-based ACE concentration-discharge relationships revealed that the hydrological pathways delivering …

The Periglacial Landscape Of Mars: Insight Into The 'Decameter-Scale Rimmed Depressions' In Utopia Planitia, Arya Bina

Electronic Thesis and Dissertation Repository

Currently, Mars appears to be in a ‘frozen’ and ‘dry’ state, with the clear majority of the planet’s surface maintaining year-round sub-zero temperatures. However, the discovery of features consistent with landforms found in periglacial environments on Earth, suggests a climate history for Mars that may have involved freeze and thaw cycles. Such landforms include hummocky, polygonised, scalloped, and pitted terrains, as well as ice-rich deposits and gullies, along the mid- to high-latitude bands, typically with no lower than 20o N/S. The detection of near-surface and surface ice via the Phoenix lander, excavation of ice via recent impact cratering activity as …

Modelling The Thermal Transport Of A Thawing Permafrost Plateau, Joelle E. Langford

Electronic Thesis and Dissertation Repository

Permafrost covers approximately 24% of the Northern Hemisphere and is in a state of decay which has large implications. To characterize the processes involved in the transitional period of permafrost decay, a three-dimensional finite element numerical model is developed. The model is based on the Scotty Creek Research Basin in the Northwest Territories, Canada (61°18'N, 121°18'W). FEFLOW groundwater flow and heat transport modelling software is used in conjunction with the piFreeze plug-in, to account for phase changes between ice and water. As transiently simulating actual permafrost evolution would require 100’s of years of climate variations over an evolving landscape, whose …

Methylmercury Production In Two Northern Fen Peatlands, Mikhail J. Mack

Electronic Thesis and Dissertation Repository

Northern peatlands provide conditions favourable for sulphate reducing bacteria, microorganisms responsible for producing methylmercury, an aquatic pollutant. An expected climate driven shift from moss- to sedge-dominance may alter mercury biogeochemistry. Observations from a moss-dominated poor fen and sedge-dominated intermediate fen were used to compare methylmercury to assess if contrasting plant communities, nutrients status and/or hydrologic regime control production. Chapter 2 compared porewater methylmercury and ancillary chemistry across two Northern Ontario fens. The lower water table, greater dissolved organic carbon, and lower pH in the poor fen resulted in 3.1 times greater methylmercury. Chapter 3, riparian zones in intermediate fen were …

Channel Form And Processes In A Formerly Glaciated Terrain, Nathaniel Bergman

Electronic Thesis and Dissertation Repository

Despite that many places around the world in general, and North America in particular, were glaciated during the last ice age, relatively little is known about rivers that evolved over these landscapes once they deglaciated. These rivers are commonly categorized as alluvial with a glacial legacy, and often described as plain gravel-bed or sand-bed rivers. Alternatively, they are considered to be bedrock rivers when the glacial deposits were eroded and underlying rock was exposed. However, ignoring the glacial history of these rivers is scientifically wrong and they should be termed "semi-alluvial". This work shows that classification is important, not only …

Hydraulic And Electrokinetic Delivery Of Remediants For In-Situ Remediation, Ahmed I. A. Chowdhury

Electronic Thesis and Dissertation Repository

Nano-scale zero valent iron (nZVI) has shown promising mobility and in-situ reactivity with chlorinated volatile organic compounds when injected into saturated porous media. The current study evaluated nZVI mobility and subsequent reactivity with in-situ contaminants in a variably saturated porous media. The nZVI particles, synthesized onsite at subzero temperatures, demonstrated complete trichloroethene (TCE) degradation within the target area. Furthermore, a three dimensional finite difference model (CompSim) was utilized to investigate nZVI mobility in variably saturated zones. Model predicted well head data were in very good agreement with field observations. Simulation results showed that the injected slurry migrated radially outward from …

Dissolved Organic Matter In Subarctic Streams And Rivers: Direct And Proxy Measures Of Quantity, Quality, And Mercury, Tara M. Despault

Electronic Thesis and Dissertation Repository

The drainage network of the Hudson Bay Lowlands (HBL) peatland complex regulates the transport of freshwater and solutes, including dissolved organic matter (DOM) and mercury, to Hudson Bay. Due to the remoteness and areal extent of the HBL, traditional, campaign-based sampling programs are unable to fully elucidate the region’s hydrology and biogeochemistry. This study investigated seasonal variability of DOM quantity and quality in two distinct stream orders to explore DOM sources to surface waters in the region, and assessed optical measurements as proxies for riverine DOM and mercury. In-stream primary production and enhanced microbial processing influenced DOM characteristics during base …

Silver Nanoparticle Transport Through Soil: Illuminating The Governing Pore-Scale Processes, Ian L. Molnar

Electronic Thesis and Dissertation Repository

Engineered nanoparticles are widely used and will eventually be released to the subsurface environment and contaminate groundwater resources. However, the transport of engineered nanoparticles through soil is currently not well understood and cannot be modelled in any fundamental manner, placing groundwater resources at risk from nanoparticle contamination. This inability to accurately simulate transport is due to a lack of experimental information on nanoparticle interactions in the pore spaces of real soils.

This thesis illuminates the pore-scale processes governing silver nanoparticle transport through soil. In addition, it examines the influence of surface chemistry and grain/pore distributions on those processes. For the …

Field Scale Application Of Nanoscale Zero Valent Iron: Mobility, Contaminant Degradation, And Impact On Microbial Communities, Chris M.D. Kocur

Electronic Thesis and Dissertation Repository

This thesis began by verifying that nanoscale zero valent iron (nZVI) synthesis methods could be scaled up and implemented at the field scale in a safe manner. This led to successful demonstration of nZVI injection and mobility under constant head gravity injection into a contaminated utility corridor in Sarnia, Ontario. Where field studies have fallen short in the past was linking the somewhat qualitative field geochemical parameters to other evidence of nZVI transport. Definitive nZVI detection was elusive in previous field studies due to the highly reactive nature of the particles caused by their high surface area. nZVI was detected …

Exploration Of Spatial And Temporal Changes In Trophic Status Of Lakes In The Northern Temporal Forest Biome Using Remote Sensing, Aleksey Paltsev

Electronic Thesis and Dissertation Repository

There is a critical need for detailed surveys of lakes covering large spatial (>100 km²) and temporal scales (decades) to determine if there is an increase in the magnitude and frequency of phytoplankton blooms. Remote sensing was used to: (1) develop a regression model that relates chlorophyll a (chl-a) as a proxy of lake phytoplankton biomass to Landsat TM and ETM+ optical reflectance (r²=0.85, p

Runoff Generation In A Tropical Dry Forest Watershed: Processes, Patterns And Connectivity, Kegan K. Farrick

Electronic Thesis and Dissertation Repository

The lack of understanding regarding the controls that govern runoff generation in tropical dry forests represent a critical gap in the hillslope and catchment hydrology literature. Tropical dry forests account for approximately 42% of the global tropical forests, but represent less than 1% of the forest hydrology literature. Three complementary studies were undertaken in a small tropical dry forest watershed, Mexico, to assess the controls that govern the retention and release of a rainfall in the catchment as runoff. In the first study, the high soil surface hydraulic conductivities, absence of a water repellent surface and low rainfall intensities during …

Peatland-Stream Hydrological And Biogeochemical Connectivity In The James Bay Lowland, Ontario, Meghan Kline

Electronic Thesis and Dissertation Repository

The Hudson-James Bay Lowlands are the second largest peatland dominated area on the planet, and are expected to be particularly vulnerable to future climate change. Changes in climate will affect peatland hydrology and biogeochemistry, impacting the aquatic ecosystems this region supports, however there is limited information about the hydrology and biogeochemistry of this landscape under current conditions. This thesis focuses on assessing the nature of hydrological and biogeochemical connectivity between a fen and 2^nd order channel in the Central James Bay Lowland, Ontario. Specifically the study focuses on the role of preferential hydrological flowpaths in the riparian area, such …

Hydrology And Biogeochemistry Of A Bog-Fen-Tributary Complex In The Hudson Bay Lowlands, Ontario, Canada, Thomas A. Ulanowski

Electronic Thesis and Dissertation Repository

The Hudson Bay Lowlands (HBL) contains 26 Gt C sequestered in a 2 meter thick layer of peat which blankets a quarter of Ontario, Canada. The hydrological and chemical influence of the HBL peatlands to surface waters is recognized, but information on peatland runoff processes and the evolution of groundwater through this vast, carbon-rich landscape remain scant. This study focused on elucidating the groundwater flow patterns of a bog-fen-tributary complex in the central region of the HBL, and estimating exports of groundwater, dissolved organic carbon (DOC), total (THg), and methyl (MeHg) mercury during the 2011 ice-free season. Hydrometric data, combined …

Isotopic Fingerprinting Of Shallow And Deep Groundwaters In Southwestern Ontario And Its Applications To Abandoned Well Remediation, Mitchell E. Skuce

Electronic Thesis and Dissertation Repository

Abandoned hydrocarbon wells in southwestern Ontario can act as conduits for Sulphur water, brines, and hydrocarbons from deep Paleozoic bedrock aquifers. Such leakage may pose a threat to shallow groundwater and the environment. Cost-effective plugging of these wells requires knowledge of the sources of the leaking fluids. This study characterizes the isotopic compositions (δ18OH2O, δ2HH2O, δ34SSO4, δ18OSO4, δ13CDIC, 87Sr/86Sr) of groundwaters in the region, which are distinct in different bedrock formations. A Bayesian mixing model was applied to these data to develop a tool for identifying the source(s) of leaking fluids. The geochemical data also improve our understanding of groundwater …

Mitigating Permafrost Degradation Due To Linear Disturbances In Sub-Arctic Peatlands, Aaron A. Mohammed

Electronic Thesis and Dissertation Repository

The presence or absence of permafrost significantly influences the hydrology and ecology of northern watersheds. Linear disturbances resulting from tree canopy removal have led to widespread permafrost degradation in northern peatlands. Seismic lines resulting from oil and gas exploration now account for large portions of the drainage density of sub-arctic basins, and affect the region’s water and energy balances. As these peatlands represent some of the most sensitive ecosystems to climate and human disturbances, the ability to simulate perturbations to natural systems in a controlled lab environment is particularly important. This study presents a method that is able to simulate …

Hydrogeological And Thermal Sustainability Of Geothermal Borehole Heat Exchangers, S. Emad Dehkordi

Electronic Thesis and Dissertation Repository

Assessment of the current approach taken by guidelines and design methods of vertical closed loop heat exchangers shows that often groundwater flow is either disregarded or is not methodically incorporated. The state of scientific research in this arena reveals that overlooking the groundwater flow in the design procedure may not always be a correct assumption. The significance of advective heat transport compared to conduction is defined by the groundwater flux or Darcy velocity which heavily depends on the hydraulic conductivity of the ground, followed by the hydraulic gradient which has a relatively limited range. A sensitivity analysis on ground and …

Topographic Influences On Trends And Cycles In Nutrient Export From Forested Catchments On The Precambrian Shield, Samson G. Mengistu

Electronic Thesis and Dissertation Repository

This dissertation explored topographic controls on spatial and temporal patterns in water yield and nutrient (carbon, nitrogen and phosphorus) export from forested headwater catchments in the Turkey Lakes Watershed in central Ontario, where other factors contributing to differences in water yield and nutrient export, including climate, geology, forest, and soils, are relatively constant. Topographic characteristics, including (a) hydrological flushing potential (expansion of water table into nitrate-N producing areas); (b) hydrological storage potential (area of wetlands, which can alternatively allow water and nutrients to bypass wetlands when storage capacity is filled with water or to trap them when not filled); and …

Thermal Plume Transport From Sand And Gravel Pits Potential Thermal Impacts On Cool-Water Streams, Jeffrey M. Markle

Electronic Thesis and Dissertation Repository

Potential thermal impacts from below-water-table aggregate extraction on a cool-water stream were investigated by monitoring thermal plumes, moving through an unconfined glacial-outwash aquifer, and assessing their subsurface persistence. The growing demand for aggregate and increased pressure to pursue extraction in ecologically sensitive areas has driven the need for this work. During a 10-year period, ground and surface water temperatures were measured monthly, including two periods of intensive monitoring (22 months and 2.5 years). The aquifer hydraulic conductivity (K) is quantified at the laboratory and field scale. The mean K’s from the multi-scale tests depend on test-support volume and …

Coupled Heat And Water Transport In Frozen Soils, Ranjeet M. Nagare

Electronic Thesis and Dissertation Repository

The effect of freezing on soil temperature and water redistribution was examined in four Mesocosms maintained at different initial water content profiles. An innovative experimental setup involving use of a frozen base layer acting as a proxy to permafrost beneath an active layer made up of packed and undisturbed peat cores was used. The experimental setup was successfully validated for its ability to maintain one dimensional change in temperature and soil water content in frozen soil. There was a substantial amount of water redistribution towards the freezing front, enough to create an impermeable frozen, saturated zone within 15 cm of …

Uncertainty Estimation Of Extreme Precipitations Under Climate Change: A Non-Parametric Approach, Tarana A. Solaiman

Electronic Thesis and Dissertation Repository

Assessment of climate change impacts on hydrology at watershed scale incorporates (a) downscaling of global scale climatic variables into local scale hydrologic variables and (b) assessment of future hydrologic extremes. Atmosphere-Ocean Global Climate Models (AOGCM) are designed to simulate time series of future climate responses accounting for human induced green house gas emissions. The present study addresses the following limitations of climate change impact research: (i) limited availability of observed historical information; (ii) limited research on the detection of changes in hydrologic extremes; and (iii) coarse spatio-temporal resolution of AOGCMs for use at regional or local scale. Downscaled output from …