Physical Sciences and Mathematics Commons^™

Volatile Cycling And Metasomatism In Flat-Slab Subduction Zones Of The Central Andes, Coleman Hiett

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

Flat-slab subduction, where an oceanic plate subducts horizontally below a continental margin for hundreds of kilometers, is an enigmatic but prevalent tectonic configuration in which chemical cycling and alteration of the continental plate is poorly constrained. Geochemical investigations in regions of modern and ancient flat-slab subduction in the Central Andes afford an opportunity to study this process. Certain elements naturally occur with varying number of neutrons in their nuclei (isotopes), and measurements of isotope ratios within geologic materials inform on chemical sources and geologic processes. This research leverages stable isotope analyses and other geochemical tools to investigate volatiles and other …

Snapshots Of Coastal Ecology During Glacial And Deglacial Intervals: A Multiproxy Assessment Of Northern Gulf Of Mexico Sediment Cores, Kendall Emilie Brome

LSU Master's Theses

Terrestrial ecosystems along exposed continental shelves during times of relatively low sea level and glaciation are rarely preserved due to the mechanically erosive nature of marine transgression and regression. In this study, I investigate the geochemical and palynological characteristics of two well-preserved sites in the northern Gulf of Mexico (NGOM) to determine the ecologic settings and subsequent mechanisms of preservation in this region. Both sites contain preserved terrigenous sediments of previously exposed coastal margins; the first is located at the Alabama Underwater Forest (~13 km south of Gulf Shores, AL, at ~15 mbsl), and optically stimulated luminescence dates to 72–56 …

Establishment Of Invasive Black Carp (Mylopharyngodon Piceus) In The Mississippi River Basin: Identifying Sources And Year Classes Contributing To Recruitment, Gregory W. Whitledge, Patrick T. Kroboth, Duane C. Chapman, Quinton E. Phelps, Wes Sleeper, Jennifer Bailey, Jill A. Jenkins

United States Geological Survey: Staff Publications

Black Carp (Mylopharyngodon piceus) was imported to the USA to control aquaculture pond snails. This species has escaped captivity and occurs in parts of the Mississippi River, several tributaries, and floodplain lakes, which is concerning due to potential competition with native fishes and predation on native mussels, many of which are imperiled. However, Black Carp captures have primarily been incidental by commercial fishers, and evidence of reproduction in the wild is limited. The objectives of this study were to assess relative abundance of aquaculture- origin and wild Black Carp using ploidy and otolith stable isotope analysis, identify spatial …

Effects Of Glutamine Deamidation On The Oxygen Isotope Compositions Of Bone Collagen, Curtis W. Russell

Electronic Thesis and Dissertation Repository

The oxygen (O) isotope composition of mammalian collagen has the potential to provide information about the drinking water and hence geographic location and climate during the life of modern and ancient animals. An accurate and reproducible O-isotope analysis of collagen, however, has been elusive. Here, the O-isotope compositions of collagen from cortical bone of four megaherbivores were compared using two extraction procedures: the traditional Longin (HCl) method and the less commonly employed EDTA method. Preservation of O-isotope compositions was evaluated by measuring collagen peptide-chain masses, specifically the glutamine deamidation level (GDL). The EDTA method yielded collagen with a GDL of …

A Study Of Stable Isotopes In Snow On Mt. Hood, Oregon, Maya Felix

University Honors Theses

Over the 2020-2021 Winter, event-based and end-of-season snow samples were collected on Mt. Hood near Government Camp, OR and analyzed for their stable isotopic compositions of ¹⁸O and ²H. It was found that surficial snow collected through the winter had higher variation in isotopic values than samples from a snow pit collected in spring. This suggests homogenization occurred in the snowpack over the season from snow metamorphism, sublimation, and/or melting. Homogenization of the snowpack will likely become more pronounced as temperatures increase and rain falls more often than snow due to climate change. Research that utilizes the snowpack …

Agricultural Irrigation Induced Evaporation In A Temperate Study Area: A Stable Isotope Approach, Lincoln Grevengoed

Masters Theses

In regions where groundwater is used for irrigation, significant water losses take place due to evaporation. Previous studies demonstrated the utility of stable oxygen and hydrogen isotopes in estimating evaporative water loss experienced during return flow back to an aquifer. Unlike arid regions where the other studies took place, this study examined the region around Kalamazoo, Michigan, the United States, which experiences a more temperate climate. Irrigation in the Kalamazoo area primarily uses center-pivot systems supplied by wells, unlike flood irrigation in previous study areas. Water samples were taken periodically from wells close to center-pivot irrigation systems. Water losses due …

Impact Of Interlayer Cation Composition And Strongly Bound Water On Smectite ẟ²H, As Determined By A Modified Tcea Method, Nadine J. Kanik

Electronic Thesis and Dissertation Repository

Interlayer cation composition and cation hydration enthalpy can potentially affect the excess hydrogen-yield and δ²H of smectitic clays. Complexities arise from condensed atmospheric water adsorbed on the clay, as it constitutes a potential additional source of hydrogen when attempting to measure the δ²H of structural OH groups. To approach this problem, the δ²H of different cation-saturated, dried forms of six Clay Minerals Society Source Clay smectites were measured. A modified sample drying and on-line High-Temperature-Conversion-Elemental-Analysis (TCEA) Continuous-Flow-Isotope-Ratio-Mass-Spectrometry protocol, facilitated isotopic measurements. A stronger interlayer cation hydration enthalpy (Ca²⁺>Na⁺>K⁺), …

Plio-Pleistocene Antarctic Ice-Ocean Interactions In The Ross Sea, Catherine Prunella

USF Tampa Graduate Theses and Dissertations

Warm, intermediate-depth Southern Ocean waters are implicated in recent Antarctic ice mass loss. Direct observations of Antarctic Ice Sheet (AIS) retreat are temporally limited, necessitating paleoceanographic records of ocean-ice interactions during past warm climate intervals. Deepsea and ice-proximal sediments record orbitally-paced glacial-interglacial fluctuations in AIS volume during the Plio-Pleistocene (last 5 million years; Ma), but the total contribution of the AIS and the role of ocean heat in these fluctuations remain unresolved. To address the response of Antarctica’s ice sheets to changing ocean temperatures during the Plio-Pleistocene, International Ocean Discovery Program (IODP) Expedition 374 recovered sediments from the Ross Sea …

Triple Oxygen Isotope Composition Of Carbonates, Jordan A.G. Wostbrock

Earth and Planetary Sciences ETDs

This dissertation presents a method of analyzing the triple oxygen isotope compositions of carbonates, presents an empirical calibration of the carbonate-water equilibrium fractionation line, presents a triple oxygen isotope equipped fluid-rock mixing model for carbonates to see-through diagenesis, and applies all these findings to ancient carbonate samples. Using modern carbonates and associate water, the following equations are calculated to describe equilibrium triple oxygen isotope fractionation of carbonates:

1000lnalpha¹⁸O_cc-wt=2.84x10⁶/T²-2.96 1),

Theta_cc-wt=-1.39/T+0.5305 2).

Using these fractionation equations provides an extremely useful tool to determine whether a carbonate sample is altered or preserves …

Paleoproductivity Of Late Holocene Lake Huron, Jamal Khaled Nigim

Electronic Thesis and Dissertation Repository

The paleolimnology of North America’s Lake Huron is described using lead-210 dating, mineralogy, magnetic susceptibility, total organic carbon (TOC), total nitrogen (TN), carbon:nitrogen (C/N) ratio, grain size, and the δ¹³C_OM and δ¹⁵N_TN of organic matter. Sediment cores from Lake Huron’s 6 depositional basins and Georgian Bay span the Medieval Warm Period, Little Ice Age, and Canadian-European settlement. The main organic matter source is lacustrine algae, as indicated by δ¹³C_OM, δ¹⁵N_TN and C/N. Prior to the 19th century, primary production changes are reflected only by small variations in …

Deuterium Excess And 17o-Excess Variability In Meteoric Water Across The Pacific Northwest, Usa, John Bershaw, Dougal Hansen, Andrew Schauer

Geology Faculty Publications and Presentations

High-precision triple oxygen isotope analysis of water has given rise to a novel second-order parameter, ¹⁷O-excess (often denoted as δ¹⁷O), which describes the deviation from a reference relationship between δ¹⁸O and δ¹⁷O. This tracer, like deuterium excess (d-excess), is affected by kinetic fractionation (diffusion) during phase changes within the hydrologic cycle. However, unlike d-excess, ¹⁷O-excess is present in paleowater proxy minerals and is not thought to vary significantly with temperature. This makes it a promising tool in paleoclimate research, particularly in relatively arid continental regions where traditional approaches have produced equivocal results. …

Basal Travertine Of The Bouse Formation: Geochemistry, Diagenesis And Implications For The Integration Of The Colorado River, Christina Ferguson

Earth and Planetary Sciences ETDs

The Pliocene Bouse Formation is discontinuously exposed in the lower Colorado River region and is a record of the first arrival of the Colorado River to the Gulf of California 5 million years ago. It consists broadly of a lower carbonate member (travertine, marl, and bioclastic units) and an upper siliciclastic member (claystone, mudstone, and Colorado River sands). This paper focuses on the basal travertine (synonymous with “tufa”) unit of the lower carbonate member. Because of its basal position and its chemical encrustation of pre-Bouse topography, the travertine can offer insight into the earliest depositional settings and may be a …

Holocene And Last Interglacial Climate Of The Faroe Islands From Sedimentary Plant Wax Hydrogen And Carbon Isotopes, Lorelei Curtin, William J. D'Andrea, Nicholas Balascio, Genevieve Pugsley, Gregory De Wet, Raymond Bradley

Geosciences: Faculty Publications

The Last Interglacial period (LIG) is Earth's most recent globally warm period and is analogous in some ways to projected future global warming. However, questions remain regarding the state of the climate during the LIG in the North Atlantic, a region that is extremely sensitive to changes in oceanic and atmospheric circulation. Here, we present hydrogen and carbon isotope (δD and δ13C) records from a suite of plant wax biomarkers preserved in Holocene and LIG lacustrine sediments from the North Atlantic Faroe Islands and interpret them as qualitative proxies for temperature and hydroclimate variability. These data are used to directly …

Stable Isotopic Characterization Of A Coastal Floodplain Forest Community: A Case Study For Isotopic Reconstruction Of Mesozoic Vertebrate Assemblages, Thomas M. Cullen, Fred Longstaffe, Ulrich G. Wortmann, Mark B. Goodwin, Li Huang, David C. Evans

Earth Sciences Publications

Stable isotopes are powerful tools for elucidating ecological trends in extant vertebrate communities, though their application to Mesozoic ecosystems is complicated by a lack of extant isotope data from comparable environments/ecosystems (e.g. coastal floodplain forest environments, lacking significant C₄ plant components). We sampled 20 taxa across a broad phylogenetic, body size, and physiological scope from the Atchafalaya River Basin of Louisiana as an environmental analogue to the Late Cretaceous coastal floodplains of North America. Samples were analysed for stable carbon, oxygen and nitrogen isotope compositions from bioapatite and keratin tissues to test the degree of ecological resolution that can …

Ductile Deformation In The Central Panamint Mountains - A Multi-Disciplinary Approach To A Multi-Dimensional Problem., Tai Antonia Subia

Open Access Theses & Dissertations

This study provides new insights into the geometry and timing of ductile, syn-metamorphic structures in the central Panamint Mountains of eastern California. The study focused on Surprise Canyon, where exposures of Meso- to Neoproterozoic miogeocline rocks, reworked crystalline basement, and syn-metamorphic granitoids record fabric overprints indicative of at least two distinct dynamo-thermal metamorphic events. Prograde metamorphism at greenschist and amphibolite metamorphic facies conditions occurred during Early Jurassic plutonism based on deformation of a dioritic pluton with a U-Pb date reported here of 175.6 ± 3.2 Ma. Mid Jurassic deformation (D1) generated the main continuous cleavage in the rocks (S1) as …

High-Dimensional Isotope Relationships, Yuyang He

LSU Doctoral Dissertations

High-dimensional isotope relationships describes the relationships of two or more element or position-specific (PS) elements in the same molecule or ion. It provides us more powerful tools to study reaction mechanisms and dynamics. Chapter 1 is about dual or multiple stable isotope relationship on δ-δ (or δ'-δ') space. While temporal data sampled from a closed-system can be treated by a Rayleigh Distillation Model (RDM), spatial data should be treated by a Reaction-Transport Model (RTM). Here we compare the results of a closed-system RDM to a RTM for systems with diffusional mass transfer by simulating the trajectories on nitrate's δ'^{18 …}

When, How, And Why Did The West Antarctic Ice Sheet Retreat In The Ross Sea Since The Last Glacial Maximum Using Foraminiferal And Porewater Geochemistry, Matthew Decesare

LSU Doctoral Dissertations

The Antarctic Ice Sheets (AIS) began to retreat from their Last Glacial Maximum (LGM) position sometime after 19,000 years ago. However, the corrosive waters circulating around Antarctica has prevented the recovery of radiocarbon-dateable material, hindering the development of deglacial chronologies. During Expedition NBP1502B to the eastern Ross Sea, an unprecedented quantity of fossil foraminifera and bivalves were recovered. Radiocarbon-dated specimens have been used to constrain the timing of West-AIS retreat from Whales Deep basin and Ross Bank. Whales Deep samples show that the WAIS retreated from its LGM position on the continental shelf edge by 14,700 ± 400 calibrated radiocarbon …

Geochemistry Of Volatiles Released By Incipient Continental Rifting And Subduction Processes, Hyunwoo Lee

Earth and Planetary Sciences ETDs

Volatiles (N2, CO2, and He) are released by volcanism and hydrothermal activity during continental rifting and subduction processes. Analyses of volatile components have been conducted to obtain gas contents (CO2, SO2, H2S, N2, Ar, He, and so on), stable isotope compositions (δ13C, δ15N, and so on), and noble gas isotopes (3He/4He, 40Ar/36Ar, and so on). This dissertation includes four chapters to report new nitrogen isotope fractionation factors of bubbling gases during gas-water transfer at various water temperatures (Chapter 1), first measurements of massive amounts of CO2 released by incipient continental rifting in the Magadi and Natron Basin, East African Rift …

Middle Miocene Paleoenvironmental Reconstruction Of The Central Great Plains From Stable Carbon Isotopes In Large Mammals, Willow H. Nguy

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Middle Miocene (18-12 Mya) mammalian faunas of the North American Great Plains contained a much higher diversity of apparent browsers than any modern biome. This has been attributed to greater primary productivity, which may have supported greater browser diversity that commonly corresponds with densely vegetated habitats. However, several lines of proxy evidence suggest that open woodlands or savannas dominated middle Miocene biomes; neither of which support many browsers today. Stable carbon isotopes in mammalian herbivore tooth enamel were used to reconstruct vegetation structure of middle Miocene biomes.

Stable carbon isotopes in C₃ dominated environments reflect vegetation density and herbivores …

Hydrologic And Chemical Interaction Between Waste Dumps And A Flooded Mine Pool At The Combination Mine, Philipsburg District, Montana, Corey Swisher

Graduate Theses & Non-Theses

The Combination Mine, located approximately 12 miles northwest of Philipsburg Montana, was intermittently mined for silver, gold, and copper from 1885 until the 1990s. After the Combination Mine was formally abandoned groundwater seeps downgradient of the mine and waste rock pile were found to be above the regulatory water quality standards. Since the groundwater seeps were downgradient of both the mine pool and waste rock pile the source of the groundwater seeps could have been from the mine pool or shallow flow paths through the waste rock pile. In order to properly plan and execute a remedial action on the …

Supergene Mineralization Of The Continental Pit, Butte, Silver Bow County, Montana, Kyle Eastman

Graduate Theses & Non-Theses

The Butte porphyry Cu-Mo-Ag deposit has been considerably altered by supergene processes that enriched Cu and Ag, and mobilized other metals. Supergene enrichment provided early miners with excellent ore grades, and contributes significantly to current mining operations in Butte. The Continental Pit exhibits the classic leached and enriched vertical zonation that is common in near-surface porphyry systems around the world. Although studied by the Anaconda Copper Mining Company during the mid-20th century, significant and economically relevant questions remain regarding this deposit’s supergene heavy metal geochemistry and its relationship to the local hydrology and tectonic history.

This thesis investigates the paragenesis …

Gypsum, Calcite, And Dolomite Caprock Fabrics And Geochemistry From The Gypsum Valley Salt Diapir, Paradox Basin, Southwestern Colorado, Kevin Lerer

Open Access Theses & Dissertations

Caprocks are found on top of or in a lateral position relative to salt diapirs. The caprocks predominantly comprise sulfate minerals such as anhydrite or gypsum, which presumably accreted during the dissolution of salt from evaporite sediments. In some cases, the sulfate minerals are replaced by carbonate minerals, referred to as "carbonate caprock". Carbonate caprocks associated with salt diapirs are important because they can act as reservoirs or conduits for hydrocarbons, and because they can be easily misidentified as carbonate lithologies belonging to the stratigraphy of the sedimentary sequences adjacent to the diapir, which can jeopardize the accurate interpretation of …

Genesis Of Unique Carbonate Fans In A Pre-Salt Reservoir Analogue, Indio Mountains, West Texas, Andre Llanos

Open Access Theses & Dissertations

Hydrocarbon exploration in pre-salt sediments of rift basins on the South Atlantic Margin have proven to be successful major oil plays. Located on the western margin of the rift, the Brazilian pre-salt reservoirs of the Santos, Campos, and Espirito Santo Basins are hosted by lacustrine/marine-influenced carbonates that comprise laterally extensive, laminated microbialite facies. The Indio Mountains, located in West Texas, provide well-exposed outcrops of Lower Cretaceous marine and non-marine rift basin strata that can be considered a reservoir-analog to the South Atlantic Margin pre-salt facies. Of particular interest for hydrocarbon exploration are unique carbonate features that have been discovered in …

Geochemical Attributes Of Hydraulically Active Fractures And Their Influence On Groundwater Quality, Amy L. Hudson

Doctoral Dissertations

This study utilized discrete interval diffusion sampling of a fractured bedrock well completed in schist to investigate if a natural weathering signal can be used to identify hydraulically active fractures. The open borehole well MFS-1, is the focus of the study, which is in close proximity to the recharge zone making it ideal for testing the hypotheses of this study. The hydraulically active fractures of Well MFS-1 were identified, and the dominant mixing force of the water column of the well was determined to be thermal convection in the upper portion of the well and upward gradients. The isotopic data …

Paragenesis And Geochemistry Of The Calvert Tungsten Skarn Deposit, Pioneer Mountains, Montana, Joshua Messenger

Graduate Theses & Non-Theses

The Calvert tungsten skarn deposit is located in the northern extent of the West Pioneer Mountains, approximately 40 miles southwest of Butte, Montana. The orebody was a significant tungsten producer from 1956-1957 and 1960-1962 during which time the mine produced a total of approximately 113,000 tons of ore averaging 1.10% WO₃. The mine has a measured reserve of 128,000 tons at 1.10% WO₃. The scheelite-bearing deposit occurs within skarn developed in the Pennsylvanian Amsden Formation near or in contact with a satellite pluton of the Late Cretaceous Pioneer Batholith.

Mineral paragenetic studies reveal at least three …

Paleoclimate Implications From Stable Isotope Analysis Of Sedimentary Organic Carbon And Vertebrate Fossils From The Cedar Mountain Formation, Ut, U.S.A., Garrett Andrew Hatzell

Graduate Theses and Dissertations

Oxygen and carbon isotopic compositions of fossilized vertebrate teeth and bone were analyzed to determine isotopic values of vertebrate faunal diet from the early Cretaceous Cedar Mountain Formation of Utah. Results for δ18O of PO4 (δ18Op) (Suarez et al., 2014) from the same data set have been compared to the δ18O of CO3 (δ18Oc) portion of teeth and turtle shell to determine if diagenetic alteration of the isotopes has occurred by plotting the line of best fit equation that models the relationship between unaltered δ18OP and δ18OC of modern mammals from Iacumin et al., 1996. Results indicate slight diagenesis of …

Geochemical Characterization Of The Mountain Home Geothermal System, Trevor Alex Atkinson

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

The Mountain Home (MH) geothermal system of the western Snake River Plain (SRP) magmatic province was discovered in 2012 by the Snake River Geothermal Drilling Project. Artesian flowing water with a temperature of 150°C was encountered at a depth of 1745 m below ground surface (mbgs) and extensive mineralized fracture networks of pectolite-prehnite, calcite, and laumontite were discovered in the recovered core. The objectives of this study are to: 1) describe the thermal and compositional history of past geothermal fluids, and 2) compare these fluids to modern fluids in order to characterize the evolution of the MH geothermal system and …

The Nature And Origin Of Pebble Dikes And Associated Alteration: Tintic Mining District (Ag-Pb-Zn), Utah, Douglas M. Johnson

Theses and Dissertations

In many ore deposits throughout the world, brecciation often accompanies or occurs in association with mineralization (Sillitoe, 1985). Such is the case in the Tintic Mining District (Ag-Pb-Zn) of north-central Utah, where unique breccia features called pebble dikes occur alongside significant mineralization. Pebble dikes are tabular bodies of breccia, which consist of angular to rounded clasts of quartzite, shale, carbonate, and minor igneous rock cemented in a fine-grained clastic matrix. All clasts now lie above or adjacent to corresponding source rocks. Dikes are thin, typically less than 0.3 m wide to as much as 1 m, and can exceed 100 …

Pore Water Extraction For Unsaturated Zone Isotope Research: An Investigation Using An Immiscible Displacement Fluid And A Centrifuge, Caitlin Burnett Weaver

Department of Earth and Atmospheric Sciences: Dissertations, Theses, and Student Research

Accurate and reliable pore water extraction techniques are important to an array of scientific fields including, but not limited to, hydrogeology, soil science, and paleoenvironmental research. The aim of the current project is to test the applicability of an immiscible displacement extraction technique for stable isotopes of water under a range of textural, hydrologic, and chemical conditions. In this study, laboratory experiments were conducted to establish the extent to which the proposed method 1) achieves sufficient yield for laboratory isotopic analyses, 2) results in isotopic exchange between water and the displacement fluid, 3) conserves initial isotopic compositions of spike test …

Modern To Late Pleistocene Stable Isotope Climatology Of Alaska, Alison Sloat

UNLV Theses, Dissertations, Professional Papers, and Capstones

Understanding modern controls on climate is necessary to interpret past climatic conditions. This project investigated the modern controls on δ18O and δD values in Alaskan surface waters to interpret the controls on Late Pleistocene climate variability. ArcGIS was used to develop an isoscape of modern δ18O and δD values of over 400 surface water samples collected across Alaska and the Yukon. It was found that winter temperature and precipitation have the greatest controls on δ18O and δD values in Alaska, resulting in high δ18O values along the coast of the Gulf of Alaska and low values inland toward Central Alaska. …