Physical Sciences and Mathematics Commons^™

Inclusive Chemical Characterization Of Tourmaline: Mossbauer Study Of Fe Valence And Site Occupancy, M D. Dyar, M E. Taylor, Tim Lutz, C A. Francis, C V. Guidotti, M Wise

Earth & Space Sciences Faculty Publications

We report here the results of a series of inclusive chemical characterizations, including all elements except oxygen, for a suite of 54 tourmaline samples. A combination of analytical techniques was used to analyze for major and light elements (electron microprobe), Fe3+ and Fe2+ (Mossbauer spectroscopy), H (U extraction), and B, Li, and F (ion microprobe, or SIMS). The B content of the tourmalines studied ranges from 2.86 to 3.26 B per formula unit (pfu) with 31 anions; excess boron is believed to reside in the Si site. Li ranges from 0.0 to 1.44 Li pfu and F contents are 0.0-0.91 …