Physical Sciences and Mathematics Commons^™

Immobilization Of Uranium And Iodine By Calcium Phosphate Minerals, Angel L. Jimenez-Arroyo

Theses and Dissertations

This dissertation is comprised of three independent but interconnected studies with the scope of further understanding uranium and iodine partitioning between apatite and fluid. The studies herein presented investigated: 1) brushite to apatite crystallization method; 2) the degree of uranium incorporation into apatite; 3) the degree of iodine incorporation into apatite. The importance of this work is assessing the role of apatite in immobilizing these elements, where uranium is a major component of spent nuclear fuel and iodine is a chemical analog of its radioactive isotope (¹²⁹I). Once we understand the incorporation mechanisms, we will provide data that …

Investigating The Impact Of Meteoric Diagenesis On The Geochemistry Of Carbonate Eolianites, Eleuthera And Water Cay, The Bahamas, Graham S. Bonnot

LSU Master's Theses

The geochemical signatures imparted in major, minor, and trace elements, combined with light isotopes, suggest promising applications regarding the stabilization of meteorically altered limestone eolianites. Previous high-resolution studies have indicated that elements associated with carbonate diagenesis such as Mg and Sr can be valuable proxies for salinity and aragonite dissolution, respectively. In addition to testing these proxies, the analyses of several temperature-, diagenetic-, bioactive-, and redox-sensitive elements were evaluated using laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) to identify additional indicators during carbonate diagenesis. Two geochemical drivers of U were identified; (1) aragonite dissolution similar to Sr and (2) oxidation …

Prospecting For Coal Bed Uranium In Kansas Through The Use Of Arcgis And Uranium Proxies, Logan Howell

Master's Theses

The potential implications for the discovery of coal bed uranium in Kansas not only have a significant scientific and human health interest impact, but also a possible future economic one as well. This study sought to look for coal bed uranium within the Cretaceous Dakota Formation located in north-central of Kansas. This study utilized the two coal bed uranium proxies of historic subbituminous coal production and radon, and ArcGIS to produce a field-site selection map. This map was used to pick counties within Kansas to collect samples from. Once samples were collected, they were scanned for radiation using all available …

Investigating Uranium Incorporation In Modern Carbonates By Sequential Extraction: Applied To The Permian - Triassic Boundary In Lung Cam, Vietnam, Christopher Michael Wray

LSU Master's Theses

The Uranium (U) isotopic system can be used to model the extent of global-scale ocean anoxia by utilizing the 238U/235U ratios as a paleo-redox indicator (δ238U). While recent studies have shown promise with the use of this novel proxy, variability is seen in modern carbonate sediment samples suggesting that more work is needed in order to understand elemental U uptake during early marine diagenesis. This thesis utilizes a sequential extraction methodology in order to understand the distribution of authigenic U within carbonate sediments.

This thesis consists of four parts, (1) an evaluation and modification of a sequential extraction methodology for …

Abrupt Ocean Anoxia During The Late Ordovician Mass Extinction Detected Using Uranium Isotopes Of Marine Carbonates, Rickey Bartlett, Maya Elrick, Yemane Asmerom, Viorel Atudorei

Earth and Planetary Sciences ETDs

The Ordovician witnessed an explosion in marine biodiversity punctuated by the first of the ‘big-5’ Phanerozoic mass extinctions, the Late Ordovician mass extinction (LOME). The LOME consists of two discrete pulses occurring at the beginning and end of the Hirnantian. Lithologic and geochemical evidence suggests widespread marine anoxia triggered the second LOME pulse; however, most of these redox proxies record local bottom water or porewater conditions rather than global seawater conditions. To evaluate global redox trends, we utilize uranium (U) isotopes and trace element geochemistry of marine carbonates as a global marine redox proxy.

Bulk carbonate samples were collected from …

The Mass Flux Of Non-Renewable Energy For Humanity, Edwin Dale Solomon

Graduate Theses and Dissertations

The global energy supply relies on non-renewable energy sources, coal, crude oil, and natural gas, along with nuclear power from uranium and these finite resources are located within the upper few kilometers of the Earth’s crust. The total quantity of non-renewable energy resources consumed relative to the total quantity available is an essential question facing humanity. Analyses of energy consumption was conducted for the period 1800 – 2014 using data from the U. S. Energy Information Administration (EIA) and World Energy Production, 1800-1985 to determine the balance between non-renewable energy resources consumed and ultimately recoverable reserves. Annual energy consumption was …

Modeling Background Radiation Using Geochemical Data, Kara Marsac

UNLV Theses, Dissertations, Professional Papers, and Capstones

Aerial gamma ray surveys have many applications in geology and science in general, such as locating mining prospects, defining radioactive plumes, and detecting nuclear weapons. Unfortunately there is currently no simple way to separate the natural gamma radiation of soil and rocks from that of contaminants such as radioactive plumes. This project used geochemical data (uranium, potassium and thorium concentrations) collected from national databases, private companies, and the NURE (National Uranium Resource Evaluation) Survey, to create forward models of exposure rates measured by aerial gamma ray surveys. We developed these techniques using an area in north central Arizona known as …

Transformation Of Uranium In A Geological Environment, Derrell Hood

All Theses

Incorporation of uranium into iron oxide minerals is a promising mechanism for the environmental immobilization of U(VI). In this study, synthesized hematite was doped with uranium and analyzed with SEM-EDS, TEM, XRD, and ICP-MS. The results of this analysis strongly indicate uranium incorporation into the mineral, as well as the possible presence of a co-precipitated uranium mineral clarkeite. Preliminary results also shows an increase in the amount of uranium associated with the hematite particles as a function of mineral aging. Cyclic Voltammetry (CV) was used to induce and characterize electrochemical changes of uranium in the doped hematite system; these changes …

Natural Radioactivity In Groundwater, Rocks And Sediments From Some Areas In The Uae: Distribution, Sources And Environmental Impact, Dalal Matar Al Shamsi

Dissertations

Groundwater contains a certain amount of natural radioactivity that generally results from the decay of uranium, thorium and 40K isotopes. Knowledge of concentration levels, spatial distribution and sources of these isotopes in groundwater is crucial for environmentally safe and sustainable groundwater resources in the United Arab Emirates (UAE). This dissertation focuses on investigating the distribution, environmental impact and sources of 235U, 238U, 232Th, as well as the activity of gross β and α in groundwater in some locations in the UAE. Additionally, groundwater samples from Oman and selected aquifer rocks and sediments from the UAE were analyzed for comparison. A …

2000 Year Moisture Source Record From A Central Nevada Speleothem, Paul Pribyl

UNLV Theses, Dissertations, Professional Papers, and Capstones

The goal of this study was to determine the moisture source of winter precipitation in the central Great Basin for the past 2000 years, and to elucidate the role of Pacific Ocean and North American climate variability modes in driving observed droughts of the region around the Medieval Climatic Anomaly (MCA, ~900-1300 CE). Here a high resolution (~2-4 year) precisely dated moisture source reconstruction is presented from the δ18O values of speleothem LC-1 collected from Leviathan Cave in central Nevada, which reveals significant δ18O variability. I attribute the δ18O variability to changes in winter-season moisture circulation over the past 2000 …

The Effects Of Changes In Water Content On Uranium(Vi) Leaching In Sediment Mixtures Containing Gravel, Andrew Weber Moore

Masters Theses

This study is aimed at understanding the physical and chemical effects that changes in water content have on uranium leaching in sediment containing gravel. It was hypothesized that leaching will be more efficient under unsaturated conditions because flow will be restricted to the smallest pores and will have the most contact with the uranium contaminated sediment. Under saturated conditions, a large portion of the flow will bypass the < 2 mm material, and in turn not come into contact with uranium contaminated material. Batch adsorption and desorption experiments were performed on < 2 mm ERDF sediment to determine the linearity and reversibility of sorption processes and to aid in the interpretation of the leaching experiments. Results of the desorption experiments on aged, contaminated sediments show that the mass percent of sorbed U(VI) released to solution decreased as the sorbed concentration of U(VI) decreased. The opposite trend was observed on freshly contaminated sediments. This indicated that aging increased U(VI) affinity for the solid phase and was attributed to either the crystallization of calcite, which incorporated a portion of the sorbed U(VI) as it crystallized, or the presence of voids in basaltic lithic fragments accessed by diffusion. Column leaching experiments were performed at two water contents on artificially contaminated sediment collected from the Department of Energy’s (DOE) Hanford Site, Washington state. The sediment contained 81.3% gravel (> 2 mm) by mass. Non-reactive tracers were well fit with the convection-dispersion equation (CDE) at both high and low water contents indicating physical equilibrium. The column experimental data were fitted to an …

Pluton Zonation Unveiled By Gamma-Ray Spectrometry And Magnetic Susceptibility; A Case Study Of The Sheeprock Granite, Western, Utah, Paul D. Richardson

Theses and Dissertations

A radiometric survey of the zoned 21 Ma, A-type Sheeprock granite, western Utah, combined with measurements of magnetic susceptibility and field observations were analyzed using a geographic information system. The intrusion spans 25 square km and is roughly eliptical in shape with its long axis trending northwest. Concentration maps (composed of more than 500 survey stations) of eU, eTh, texture, magnetic susceptibility, color, and joint density help to constrain magmatic and post-magmatic processes related to its chemical and physical zonation. Uranium ranges from 3.9 to 26.9 ppm (mean 12.7) and thorium from 1.7 to 125.7 ppm (mean 45.5). Similarities in …