Physical Sciences and Mathematics Commons^™

Miocene-Pleistocene Diatom Oxygen Isotope And Biogenic Silica Record From Iodp Site U1523, Ross Sea, Antarctica, Donald James Mclennan

Graduate Research Theses & Dissertations

The West Antarctic Ice Sheet (WAIS) plays a significant role in Earth’s climate. WAIS is currently retreating due to changes in wind-driven oceanic currents resulting in an increasing flux of warm waters to ice margins. Brine rejection in the Ross Sea is also major source of High Salinity Shelf water (HSSW) and Antarctica Bottom Waters (AABW), which creates a stratified ocean and plays a significant role in regulating Earth’s climate. Currently, there are very limited proxies that can quantify the variable input of HSSW formation on geologic time scales. Here we provide a 18Odiatom and biogenic silica (BSi) record which …

Post-Impact Light Vapor Incorporation During Lunar Formation Based On Triple Oxygen Isotopes, Erick J. Cano

Earth and Planetary Sciences ETDs

Initial triple oxygen isotope analyses of lunar samples showed them to be indistinguishable from Earth, which led to numerous papers aimed at explaining the similarities. Recent high-precision analyses suggested either a subtle enrichment in Δ'¹⁷O or virtually no difference between the Earth and Moon. Herein we expand on previous studies by correlating the triple oxygen isotope measurements with different lunar lithologies. We show that these data can be explained by mixing between a light vapor phase, generated during the Giant Impact, and the residual material from the proto-lunar impactor ‘Theia’. There is a general decrease in Δ'^{17 …}

Ice And Guano Deposits In El Malpais Lava Tubes: Potential Paleoclimate Archives For The Southwest United States, Dylan S. Parmenter

USF Tampa Graduate Theses and Dissertations

Three ice cores and one guano core were obtained from lava tubes in El Malpais National Monument, New Mexico, in the Southwest United States. A large hiatus in the Bat Cave guano record, resulting from mining activities in the early 1900's, left us with only ~50 years of data (from AD 1955-2006) to use in analysis. 13C values in guano (-18 to -11.6‰) primarily fall within the range of C4 plants, and likely indicate a tendency of Tadarida brasiliensis to feed on insects over grasslands to the North or South of the park. Variations in 13C values for this period …

A Speleothem Record Of Climate Variability In Southwestern North America During Marine Isotope Stage 3, Justin G. Peinado

Earth and Planetary Sciences ETDs

During Marine Isotope Stage 3 (MIS-3) of the last glacial period, there were rapid transitions between warm and cold climates referred to as Dansgaard-Oeschgerr (DO) events. In Southwestern North America (SWNA), two speleothem paleoclimate records document changes in moisture source delivery in response to DO-events during MIS-3, but do not address potential changes in effective moisture for the region. In this study, we introduce a new high-resolution speleothem paleoclimate record from Carlsbad Cavern in the Guadalupe Mountains. The speleothem, sample BC-5, grew continuously from 46-31 kya during the latter half of MIS-3, based on U-Th dating. We also tied stable …

Hydrogen, Carbon, And Oxygen Isotopes In Prosopis Sp. Trees: A New Climate Proxy For Holocene Paleoclimate In The Atacama Desert, Chile, Elizabeth Joy Olson

Graduate Research Theses & Dissertations

The spatial ubiquity of trees in terrestrial ecosystems worldwide facilitates the use of stable isotope research in tree-rings to address a wide-range of interdisciplinary questions related to climate, ecology, archaeology, and hydrology. This dissertation focuses on the development and application of Prosopis tamarugo tree-ring stable isotope records as a paleoclimate proxy for the Atacama Desert, Chile. Current paleoclimate proxies from this region lack the spatial and temporal resolution to quantify a causal mechanism for observed Holocene hydroclimate variability. P. tamarugo tree-ring isotopes provide a high-resolution proxy that facilitates the reconstruction of hydroclimate variability at a regional scale. In order to …

Eclogites And Eclogites: Oxygen Isotope Evidence Of A Shared Subduction Origin For Franciscan Eclogites And Moses Rock Eclogite Xenoliths, William F. Hoover

Honors Papers

Eclogites can be found in two distinct tectonic settings in the western USA: in the Franciscan Complex as tectonic blocks in a fossil accretionary wedge, and in the Navajo Volcanic Field as xenoliths in diatremes. Intra-crystal oxygen isotope analyses of garnets from these two settings provide important information on the source, composition and timing of fluid interactions in both eclogite settings. Because of the well-documented relationship between Franciscan subduction and the volcanism in the Navajo Volcanic Field, the samples in this study can be directly compared to determine if they share a common origin. The Navajo eclogites in this study …

Stable Isotopes And Trace Elements In Tooth Enamel Bioapatite: Effects Of Diagenesis And Pretreatment On Primary Paleoecological Information, Jessica Norman Wilson

USF Tampa Graduate Theses and Dissertations

The geochemical analysis of bioapatite in vertebrate skeletal tissues is an important tool used to obtain ecological information from fossil animals. An important consideration when conducting stable isotope and trace element analyses is obtaining biogenic information that has been unaffected by diagenetic processes.

A two-step pretreatment procedure is commonly used remove diagenetically altered material by removing organic material, via an oxidation reaction with H2O2 or NaOCl, and secondary carbonate, via dissolution in dilute acetic acid, from bioapatite. While much work has been done to determine the efficacy of the pretreatment process, little research has been conducted to determine the potential …

Oxygen Enriched Atmosphere Roasting, Clarence Wells Jr

Bachelors Theses and Reports, 1928 - 1970

The possible benefits of oxygen enriched atmosphere roasting have been known to metallurgists for many years, but only since the development of equipment and processes to produce cheap oxygen in very large amounts has much ser­ious consideration been given this matter.

Age Hardening Of Silver-Platinum Alloys, Robert A. Wilson

Bachelors Theses and Reports, 1928 - 1970

The alloy system selected for study was the binary alloy of platinum and silver. An examination of the various silver alloy diagrams revealed that of several possible alloys, the silver platinum was the most suit­able with regard to solubility.

The Inhibitory Effects Of Carbonaceous Materials On The Cyaniding Of Gold Ores., David Currie Jr.

Bachelors Theses and Reports, 1928 - 1970

Carbon and carbonaceous material have been known to have a deleterious effect upon the cyanidation of gold and silver ores since the very beginning of the process. Organic matter is a common source of impu­rities in cyanide solution, its reducing effect being notorious.

A Study Of The Effect Of Oxygen On The Rate Of Dissolution Of Gold In Cyanide Solutions., John A. Cook

Bachelors Theses and Reports, 1928 - 1970

The accepted chemical reactions in the dissolution of gold by cyanide solutions require the presence of gold, cyanide, water, and oxygen. The importance of dissolved oxygen in cyanide solutions as a factor is recognized by those familiar with cyanidation. Manufacturers of cyanidation equipment realize the necessity of oxygen, as shown by the appliances they have developed which are attached to the agitators in order to saturate the cyanide solutions with air.