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Full-Text Articles in Physical Sciences and Mathematics

Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky Dec 2021

Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky

Theses and Dissertations

Mississippi Valley Type (MVT) lead and zinc deposits provide a significant source of sedimentary galena and sphalerite. However, geochemical characteristics and genesis including the source and production of hydrogen sulfide required for galena and sphalerite ore formation and the reasoning for quick, episodic mineralization is not fully understood. By simulating regional MVT brines, the input and effect of biological by-products during the development of these ores as well as the cause of cyclicity within MVT deposits have been observed. Experiments using compositions from MVT fluid inclusions were conducted over two-week periods. Variables during the experiments included temperature, CO2, hydrogen sulfide …


The Legacy Of Contamination By Lead Smelters In Missouri, Robert S. Armstrong Dec 2020

The Legacy Of Contamination By Lead Smelters In Missouri, Robert S. Armstrong

MSU Graduate Theses

Missouri has a rich history of lead mining. In the smelting process lead particles are emitted, which may be toxic to plants and animals. This study focuses on two primary lead smelters, Herculaneum and Glover, in Missouri. Smelting operations have ceased at these two sites, and unlike Herculaneum, Glover has no reported lead concentrations. Findings from air and sediments of these two sites were compared to background conditions and to each other. Thirty-three samples were collected from Herculaneum and Glover (thirty samples and three replicates) and eleven samples (ten samples and one replicate) for background. For Herculaneum sediment, lead levels …


The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan Aug 2020

The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan

MSU Graduate Theses

The historic Tri-State Mining District (TSMD) of southwestern Missouri, southeastern Kansas, and northeastern Oklahoma has a history of lead and zinc mining that extended over a hundred years. During the district’s peak production period, the TSMD was one of the world’s largest producers of lead and zinc. The mining activities in the TSMD produced economic growth that supported the local communities and were essential to the victory of the Allied Forces during World War I and World War II. Beginning in the 1920s, the mining activities in the district slowly began to cease due to depletion of metal ores and …


Microscale Controls On Lead Speciation In Soils: A Framework For Sustainable Remediation, Grant Reeder Jan 2018

Microscale Controls On Lead Speciation In Soils: A Framework For Sustainable Remediation, Grant Reeder

Graduate College Dissertations and Theses

The potential of a soil to immobilize heavy metal ions is dependent on the presence of adsorption sites, and the stability of metal species over the range of geochemical conditions present in the soil over time. Lead (Pb) is a cumulative toxin that is enriched in much of the urban pedosphere due to historical use of Pb-based paint and Pb-amended gasoline. Because in-situ remediation of Pb is possible if the bioavailable fraction can be rendered inert, understanding Pb-sorbent interactions is necessary to accurately and efficiently alter Pb speciation in soils. The objectives of this study are to 1) determine efficient …


Airborne Lead In El Paso, Texas, Usa, Lisa Marie Paz Jan 2017

Airborne Lead In El Paso, Texas, Usa, Lisa Marie Paz

Open Access Theses & Dissertations

Despite significant strides to minimize lead in our air, water, soil, food, homes, workplaces, and consumer products, sporadic and systemic lead poisoning persists in industrial societies, e.g., the contemporary Flint (Michigan, USA) municipal water tragedy. Because lead exposure is cumulative, the sum of exposure from all sources, it is important to document and update potential community or neighborhood exposure levels from such environmental compartments as air, water, and housing. Here we present ambient airborne lead levels in El Paso, Texas, USA, parsed by particulate matter (PM) size fraction, geography, and season. Dichotomous samplers at 8 stations collected particulate matter continuously …


Speciation, Distribution, Prediction, And Mobility Of Lead In Urban Soils: A Multiscale Study, Jennifer Bower Jan 2017

Speciation, Distribution, Prediction, And Mobility Of Lead In Urban Soils: A Multiscale Study, Jennifer Bower

Graduate College Dissertations and Theses

Lead (Pb), a trace metal notorious for its impacts on human health, has achieved worldwide environmental dispersal resulting from centuries of use by human society. The toxicity of Pb is governed largely by its mineral form, which is in turn controlled by pH, localized reactivity and soil processes that differ according to soil type, location and Pb source. Given the context of these localized dependencies, or site specificity, efforts to predict Pb toxicity and refine sustainable remediation techniques are most useful when Pb behavior is constrained and predicted within environments with homogeneous conditions, such as a single soil. I evaluated …


Source Constraints Of Ore Metals In Mississippi Valley-Type Deposits In Central And Eastern Tennessee Using Pb Isotopes, Austin Moyers May 2015

Source Constraints Of Ore Metals In Mississippi Valley-Type Deposits In Central And Eastern Tennessee Using Pb Isotopes, Austin Moyers

Graduate Theses and Dissertations

The Mississippi Valley-Type (MVT) Central and East Tennessee (TN) Districts contain economically significant lead-zinc deposits that occur in the Early Ordovician carbonates of the Knox Group. Although both districts share similar host rock, have similar temperatures of formation, and typically fill open spaces of collapse breccias or replace their host carbonates, previous studies may suggest that these ores did not form from the same mineralizing fluids and may have different Pb sources. Nu Plasma MC-ICP-MS Pb isotopic analyses on sulfides from Central and East TN were conducted and the metal sources evaluated. Results were plotted on covariation diagrams with respect …


A Study Of The Effects Of The Chloride Ion On The Lead-Silver Anodes And On The Lead Tenor Of The Zinc Deposit In Zinc Electrolysis, William A. Mitchell May 1953

A Study Of The Effects Of The Chloride Ion On The Lead-Silver Anodes And On The Lead Tenor Of The Zinc Deposit In Zinc Electrolysis, William A. Mitchell

Bachelors Theses and Reports, 1928 - 1970

The electrolyte used in the commercial production of electrolytic zinc from zinc sulphate solutions contains small amounts of impurities each of which has its own effects upon the process. Impurities such as antimony, cobalt, nickel, and iron tend to lower the current efficiency while other impurities such as chlorine, fluorine, and nitrates tend to increase the corrosion of the lead anodes and thereby increase the lead tenor of the zinc deposit.


Benefication Of An Oxidized Lead Ore From The Franklin Mine Lewis And Clark County, Jack D. Mclenegan May 1949

Benefication Of An Oxidized Lead Ore From The Franklin Mine Lewis And Clark County, Jack D. Mclenegan

Bachelors Theses and Reports, 1928 - 1970

This thesis is concerned with the beneficiation of an oxidized lead ore. Emphasis was placed upon concentration by flotation rather than by gravity methods, although some investigation was made with the Wilfley shaking table. The concentration of lead minerals received most consideration in the problem, but wherever possible attempts were made to increase the silver and gold concentration along with the lead.


The Electroformation Of Lithium-Lead Alloys From Molten Electrolytes, Thomas Prater May 1941

The Electroformation Of Lithium-Lead Alloys From Molten Electrolytes, Thomas Prater

Bachelors Theses and Reports, 1928 - 1970

An attempt was made to make lead-lithium alloys by electrodeposition of lithium using a molten bath and a molten lead cathode.The variables taken into consideration were: composition of the melt, temperature of the melt, and current density. The purpose of changing these factors was to determine what effect each had on the current efficiency.


Structure Of Eutectics, Dilip K. Das May 1939

Structure Of Eutectics, Dilip K. Das

Bachelors Theses and Reports, 1928 - 1970

The present paper is a result of work done on the study of structures of eutectics of a certain eutectic-forming binary systems. In this research work no systems with intermetallic compounds have been studied.


A Study Of Solders, John D. Prater May 1939

A Study Of Solders, John D. Prater

Bachelors Theses and Reports, 1928 - 1970

The purpose of this paper is to furnish a qualitative method of comparing the degree of wetting of various solders upon different plate metals when several fluxes are used.


Electrolytic Recovery Of Copper And Zinc From Brass., V. Kent Loughran May 1938

Electrolytic Recovery Of Copper And Zinc From Brass., V. Kent Loughran

Bachelors Theses and Reports, 1928 - 1970

The reclamation of metals from scrap is becoming increasingly important in the metallurgical industry. Copper, because it does not corrode readily and is electronegative to most common metals, is peculiarly adapted to reclamation.


The Effects Of Lime On The Amalgamation Of Gold., Rollien R. Wells May 1936

The Effects Of Lime On The Amalgamation Of Gold., Rollien R. Wells

Bachelors Theses and Reports, 1928 - 1970

An amalgam is an alloy of mercury with other metals, and amalgamation is the art of making or forming amalgams. In metallurgical language the word is limited to the means adopted for the recovery of gold and silver from their ores by the use of mercury.


A Metallurgical Study Of Gold Ores, Alfred A. Bloom May 1935

A Metallurgical Study Of Gold Ores, Alfred A. Bloom

Bachelors Theses and Reports, 1928 - 1970

Gold is widely distributed in the earth's crust in small quantities. Gold is found in nature in two forms; the element itself and the compound gold telluride. In all cases, silver in some proportion is an alloying constituent.