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Physical Sciences and Mathematics Commons

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Geology

Theses/Dissertations

2011

Carbon

Articles 1 - 2 of 2

Full-Text Articles in Physical Sciences and Mathematics

Risks Posed To Drinking Water Aquifers Due To Leakage Of Dissolved Co2 In Improperly Abandoned Wellbores, Kirk Ellison Aug 2011

Risks Posed To Drinking Water Aquifers Due To Leakage Of Dissolved Co2 In Improperly Abandoned Wellbores, Kirk Ellison

All Theses

In order to ensure safe long-term storage of carbon dioxide in geologic formations, the risks posed by improperly abandoned wells must be understood and minimalized. In addition to supercritical and gaseous CO2, brine containing dissolved CO2 poses a leakage risk. CO2 dissolution in brine leads to denser brine and better long-term storage security, but its leakage risk is not zero. Under specific circumstances with formation overpressure or overlying aquifer drawdown, dissolved brine can flow up improperly abandoned wells where it can potentially enter and contaminate drinking water aquifers. The possibility that depressurization in the wellbore may cause CO2 exsolution from …


Carbon And Sulfur Cycling In Early Paleozoic Oceans, Cara Kim Thompson May 2011

Carbon And Sulfur Cycling In Early Paleozoic Oceans, Cara Kim Thompson

Doctoral Dissertations

Here, I evaluate biospheric evolution during the Ordovician using high-resolution inorganic carbon and sulfur (carbonate-associated sulfate and pyrite) isotope profiles for Early Ordovician to early Late Ordovician strata from geographically distant sections in Western Newfoundland and the Argentine Precordillera. Additionally, I present new, high-resolution U-Pb ages for volcanic ash beds within strata of the Argentine Precordillera. Carbon isotope data record subdued variation that is typical of Early- to Middle Ordovician strata worldwide. By contrast, sulfur-isotopic compositions of carbonate-associated sulfate reveal a complex signal of short-term, rhythmic variation superimposed over a longer-term signal. This short-term, rhythmic variation occurs in all sections …