Physical Sciences and Mathematics Commons^™

Phyllosilicate Mineralogy, 40ar/39ar Geochronology, And Genesis Of Petrocalcic Soils In The Southwest U.S.A., Colin R. Robins

UNLV Theses, Dissertations, Professional Papers, and Capstones

Obtaining isotope ages for arid soils and paleosols, including carbonate-cemented (calcic and petrocalcic) horizons, constitutes a significant challenge for soil scientists, geomorphologists, and stratigraphers. Carbonate-cemented soils foster diverse suites of authigenic minerals with exciting potential for geochronology, however, this potential has not been realized. This dissertation describes the timing of pedogenic palygorskite and sepiolite crystallization in extremely old, extant petrocalcic soils of the southwest U.S.A., and assumes that these fibrous, high-magnesium phyllosilicates contain sufficient lattice-bound K to warrant vacuum-encapsulated 40Ar/39Ar geochronology. This three-part study evaluated the (1) selective extraction, (2) 40Ar/39Ar analysis, and (3) pedogenesis of palygorskite and sepiolite.

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