Physical Sciences and Mathematics Commons^™

In Situ Ion Exchange In A Micro-Porous Transition Metal Silicate Framework, Jason M. Lively

Masters Theses & Specialist Projects

Ion selectivity of minerals has traditionally been utilized in industry as a catalyst, metal separation, and environmental reclamation/sequestration tool. There is an increased interest in understanding ion selectivity mechanisms of micro-porous minerals and mineral-like structures and how they can be applied in various industries: environmental and, potentially, pharmaceutical. This study seeks to understand the ion exchange mechanisms in micro-porous zirconosilicates using time-resolved Raman spectroscopy and X-ray diffraction. The thesis material was exchanged with H+, Na+, K+, and Cs+ in order to better understand structural changes as well as the influence of the H+-bonding during the exchange process. It is hypothesized …

Evaluating The Influences Of Karst Hydrogeology On Freshwater Harmful Algal Blooms In Kentucky Lakes, Robert T. Schaefer

Masters Theses & Specialist Projects

A problem exists in Nolin River Lake and Rough River Lake in Kentucky, due to the increasing prevalence of cyanobacterial-based harmful algal blooms (CyanoHABs) and the threats they pose to local communities. These lakes were developed as artificial reservoirs from embankment. Further complicating the issue, the lakes are located within a heavily karstified region and there exists no plan or method currently for monitoring or managing CyanoHABs in a karst region with regard to groundwater inputs to the lake systems or their tributaries. A mixture of techniques and analysis methods was used to determine the best way to monitor and …

Devonian Hydrocarbon Production In South Central Kentucky: A Gis Study, Andrew David Reeder

Masters Theses & Specialist Projects

Historically, Devonian Corniferous hydrocarbon production in south-central Kentucky has been a major contributor to the total hydrocarbon resources within Butler, Edmonson, and Warren counties. The Corniferous adds to the already large hydrocarbon totals produced from the Illinois Basin; however, this hydrocarbon contribution does not come without major pitfalls and inconsistencies. The south-central Kentucky Devonian Corniferous rocks comprise a diverse and complex hydrocarbon system made up of multiple migration pathways, trapping mechanisms, and seals. The multiple Corniferous units all derive production from the same source rock: the New Albany Shale.

A Geographic Information System (GIS) containing data on surface elevations, structure …

Linking In-Situ Data With Remote Sensing To Analyze Tropical Glacier Stability And Retreat In The Cordillera Blanca, Peru, Chandler H. Santos

Masters Theses & Specialist Projects

Glaciers are a major source of freshwater around the world, but they are melting at an increased rate due to atmospheric warming resulting from anthropogenic climate change. In addition to temperature increases, light-absorbing particulates on glaciers also are contributing to glacial melt. This research examines how black carbon, released into the air through partial combustion of biofuels, is affecting the surface albedo of glaciers. I also delineate possible sources of black carbon in the Cordillera Blanca region of Peru. Ground data were collected each year from 2011 to 2013 during the local dry season. Effective black carbon (eBC) values were …

Karst Landscape Influence On The Planetary Boundary Layer Atmosphere, Zachary S. Sullivan

Masters Theses & Specialist Projects

Karst landscapes cover approximately 20% of the ice-free land area worldwide. The soluble nature of the bedrock within a karst landscape allows for the formation of caverns, joints, fissures, sinkholes, and underground streams, which affect the hydrological behavior of the region. Currently, the Noah Land-Surface Model (Noah- LSM), coupled with the Weather Research and Forecasting (WRF) model, does not provide a representation of the physical behavior of a karst terrain. Previous research has attempted to model karst behavior through soil moisture and land cover/land use changes to determine the influence this unique landscape may have on atmospheric phenomenon. This highlights …

The Role Of Diagenesis In Reservoir Development Of The Big Clifty (Jackson) Sandstone In South-Central Kentucky, Kort H. Butler

Masters Theses & Specialist Projects

The Big Clifty is a Chesterian-age Mississippian sandstone member of the Golconda Formation that extends from south-central Kentucky into adjacent Illinois and Indiana. Asphaltic deposits and conventional petroleum plays are distributed along the Pennyrile Fault System and Plateau in the southeastern portion of the Illinois basin. In south-central Kentucky anomalous oil-saturation geometries are observed in cored sections of the Big Clifty from wells in Warren and Butler counties along the margin of the Pennyrile Plateau. Petrographic study of the cores has revealed several diagenetic processes that have contributed to, or are directly responsible for, the anomalous oil saturation geometries and …

Petrographic Controls On Weathering Of The Haney Limestone, Steven M. Devine

Masters Theses & Specialist Projects

Although karst processes in south central Kentucky have been studied extensively, the Haney Limestone Member of the Golconda Formation has not been studied in detail in contrast to limestones stratigraphically below it that are thicker. In addition, the relationship between petrographic features of the Haney Limestone and the formation of caves and karst features has not been studied extensively compared to lithographic, petrographic, or structural variables

Petrographic data were collected using core and surface exposures across the study area of south central Kentucky from northern Logan and Warren counties up toward the Rough Creek Graben region, and stratigraphic columns were …

Reservoir Study And Facies Analysis Of The Big Clifty Sandstone In South Central Kentucky, Tyler S. Bodine

Masters Theses & Specialist Projects

The Big Clifty (Jackson) Sandstone Member of the Golconda Formation is the most important of the Mississippian (Chesterian) heavy-oil reservoirs in the southeastern Illinois Basin. Heavy oil reservoirs, or asphalt rock deposits, have been studied extensively in south central and western Kentucky, and ~2 billion barrels of original oil in place (OOIP) have been proposed to occur in the Big Clifty Sandstone. Despite high OOIP estimates, heterogeneities in the reservoir negatively impact the production of heavy oil deposits. Heterogeneities related to depositional facies changes are poorly understood in the Big Clifty Sandstone of Kentucky, where it has been mostly described …