Physical Sciences and Mathematics Commons^™

Phase Equilibria, Compressibility, And Thermal Analysis Of Bastnaesite-(La), Richard Lee Rowland

UNLV Theses, Dissertations, Professional Papers, and Capstones

Understanding basic material properties of rare earth element (REE) bearing minerals such as the temperatures and pressures at which different phases are thermodynamically stable and how they respond to changes in temperature and pressure can assist in understanding how economically viable deposits might form, thereby potentially leading to the discovery of new deposits. Bastnaesite is the most common REE bearing mineral mined. The lanthanum-fluoride end member, bastnaesite-(La), was synthesized. Synthetic bastnaesite-(La) and lanthanum oxyfluoride was investigated using thermal analysis at ambient pressure and high temperature through the methods of thermogravimetric analysis, differential scanning calorimetry, and heated stage powder X-ray diffraction. …