Physical Sciences and Mathematics Commons^™

Experimental Investigation Of High-Temperature Brine-Shale Interactions, Anna Atasha Hoffmann

Doctoral Dissertations

"Hydrofracturing (fracking), a common practice in the Petroleum Industry to induce or improve fluid flow in tight formations, creates chemical disequilibrium that further alters the porosity and permeability of host rocks and results in the production of saline and contaminated produced waters (PW). The PW of the Tuscaloosa Marine Shale (TMS) are Na-Ca-Mg-K-Cl brines with mean concentrations of approximately 16% Total Dissolved Solids (TDS) and circumneutral pH. Analysis of composition suggests the PW result from a 20 to 80% dilution of formation waters (relict brines of the Louann Salt) by fracking fluid. Trace element concentrations generally show moderate to strong …

Applied Geochemistry, Geochronology And Biostratigraphy: Case Studies From The 38th Parallel Structures In Missouri And Orange Basin, Offshore Western South Africa, Marissa Kay Spencer

Doctoral Dissertations

"The unique alignment of the Decaturville, Crooked Creek, and Weaubleau geological structures in central Missouri, three of nine known such structures along the 38th parallel in Illinois, Missouri, and Kansas, has puzzled geoscientists for decades. Research using palynology (palynomorphs and particulate organic matter) and radiometric dating of impact spherules were used to constrain age and a relationship between these enigmatic structures and infer their paleoenvironmental conditions. Novel melting damages, unique to impact, were documented in the palynomorphs in all the three structures. Early Ordovician acritarchs with melted processes correlate with ⁴⁰Ar-³⁹Ar stepwise heating age of impact spherules …

Hydroclimate Variability In Central America During The Holocene Inferred From Lacustrine Sediments In Lake Izabal, Eastern Guatemala, Edward Fernando Duarte

Doctoral Dissertations

"Holocene hydroclimate reconstructions have contributed to our understanding of the mechanisms controlling precipitation in Central America. Recent hydroclimate proxy records from the region, however, have revealed considerable spatiotemporal complexity in precipitation variability. This complexity is hypothesized to result from the interaction between multiple oceanic-atmospheric processes that converge in the region. This project analyzed three sediment cores from Lake Izabal, eastern lowland Guatemala, with the goal of understanding changes in precipitation, lake productivity, and lake water chemistry during the Holocene. Our proxy results indicate that precipitation in the region increased from the early to the middle Holocene, when Lake Izabal became …

Mantle Flow And Transition Zone Discontinuities Beneath The Carribean Plate: Constraints From Shear Wave Splitting And Receiver Function Analyses, Tu Xue

Doctoral Dissertations

"Azimuthal anisotropy quantified by teleseismic SKS, SKKS, PKS (“XKS”) and local S wave splitting parameters is used to investigate lithospheric deformation and asthenospheric flow beneath the boundary zone of the North American and Caribbean plates and adjacent areas. A total of 4915 XKS and 1202 pairs of local S wave splitting parameters were obtained at 24 broad band seismic stations. The XKS observations can be divided into two groups based on the spatial distribution of the resulting fast polarization orientations. Those observed on the Caribbean Plate are mostly WNW-ESE which are roughly trench-parallel. In contrast, the fast orientations observed on …

The Kanarra Fold-Thrust System -- The Leading Edge Of The Sevier Fold-Thrust Belt, Southwest Utah, William Joseph Michael Chandonia

Doctoral Dissertations

“The Jurassic to Eocene Sevier fold-thrust belt is the subject of continued scientific curiosity in tectonics, stratigraphy, and industry. Understanding its development in southwest Utah is hindered in part due to the multiple origins proposed for the Kanarra anticline, a major leading edge structure -- a drag fold along the Hurricane fault, Laramide monocline, Sevier fault propagation fold, or a combination of these -- which have confused its tectonic significance and regional context. This confusion results from the structural complexity of its exposed eastern limb, as well as displacement and burial of its crest and western limb beneath Neogene sediments …

Application Of Machine Learning In Geophysics: Ranking Teleseismic Shear Wave Splitting Measurements And Classifying Different Types Of Earthquakes, Yanwei Zhang

Doctoral Dissertations

"During the past decades, applications of Machine Learning have been explosively developed to solve various academic and industrial problems, and over-human performance has been shown in diverse areas. In geophysical research, Machine Learning, especially Convolutional Neural Network (CNN), has been applied in numerous studies and demonstrated considerable potential. In this study, we applied CNN to solve two geophysical problems, ranking teleseismic shear splitting (SWS) measurements and classifying different types of earthquakes.

For ranking teleseismic SWS measurements, we utilized a CNN-based method to automatically select reliable SWS measurements. The CNN was trained by human-verified teleseismic SWS measurements and tested using synthetic …

Depositional Conditions, Stratigraphic Evolution, And Allo- And Autogenic Controls Of Lower Permian Non-Marine Carbonate Rocks, Lucaogou Low-Order Cycle, Bogda Mountains, Nw China, Yiran Lu

Doctoral Dissertations

"The overall objective of this study is to interpret the depositional conditions of lacustrine carbonate deposits of the lower Permian Lucaogou low-order cycle in the greater Turpan-Junggar continental rift basin, NW China. The depositional environments of ten carbonate lithofacies in the Tarlong-Taodonggou half graben and the Zhaobishan section were interpreted. Allo- and autogenic factors were identified. They controlled characteristics and distribution pattern of carbonate deposits in regional and local scale, respectively. Allogenic factors include the amount and direction of regional siliciclastic input, basin geometry, cyclic humidity/aridity oscillation, temperature, and regional tectonics. Autogenic factors include local siliciclastic input, local topography, local …

Laterally Heterogeneous Seismic Anisotropy Investigated By Shear Wave Splitting Analyses, Yan Jia

Doctoral Dissertations

"Numerous geophysical studies suggest that seismic anisotropy is a nearly ubiquitous property of the Earth’s crust and upper mantle. In this study, we utilize the shear wave splitting technique to investigate the piercing-point-dependent azimuthal anisotropy beneath the northeastern edge of the Sichuan Basin in central China, and the spatial and temporal variations of anisotropy near the 2019 M7.1 Ridgecrest earthquake in California, respectively. A clear back azimuthal dependence of the splitting parameters and the lack of a 90° or 180° periodicity of azimuthal variation in the observed fast orientations provide strong evidence for the existence of piercing-point-dependent anisotropy beneath the …

The Pilot Knob Magnetite, Pilot Knob Hematite, And Shepherd Mountain Iron Oxide Deposits In Southeast Missouri -- Local Expressions Of A Magmatic-Hydrothermal Plumbing System?, Bolorchimeg N. Tunnell

Doctoral Dissertations

“The Southeast Missouri Iron Metallogenic Province in the Midwestern USA contains seven major and several minor IOA/IOCG-type deposits, all of which are spatially associated with the early Mesoproterozoic (1.50-1.44 Ga) magmatism in the St. Francois Mountains terrane. This Ph.D. project focuses on the Pilot Knob deposits, i.e., the deeper largely massive Pilot Knob Magnetite (PKM) and the shallower Pilot Knob Hematite (PKH) deposits, and the Shepherd Mountain deposit that are located less than 2.1 km distance from one another. The first precise age for the formation of the PKM ore is constrained at 1438±5.8 Ma using apatite U-Pb method. Petrographic …

Neogene Dinoflagellate Cysts From The Tropical Americas, Damian Cardenas

Doctoral Dissertations

"Marine palynomorphs, mainly dinoflagellate cysts and acritarchs, constitute excellent proxies for biostratigraphic and paleoceanographic studies in neritic sequences. Neogene marine palynological studies have mostly focused on the Northern Hemisphere, resulting in the scarcity of dinoflagellate cysts and acritarchs from tropical latitudes. Forty samples encompassing the late Chattian-late Burgidalian time interval (~24.1- 17.3 Ma) in the Southern Caribbean were analyzed for their marine palynological contents. A biostratigraphic scheme for the region is proposed and includes the upper Chattian-lower Aquitanian Minisphaeridium latirictum Interval Zone (~23.9-22.0 Ma), the upper Aquitanian Achomosphaera alcicornu Interval Zone (~22.0-20.3 Ma), and the Burdigalian Cribroperidinium tenuitabulatum Interval Zone …

An Integrated Wellbore Stability Study To Mitigate Expensive Wellbore Instability Problems While Drilling Into Zubair Shale/Sand Sequence, Southern Iraq, Ahmed Khudhair Abbas

Doctoral Dissertations

”The Zubair Formation is the most prolific reservoir in Iraq, which is comprised of sandstones interbedded with shale sequences. Due to the weak nature of the shale sequence, the instability of a wellbore is one of the most critical challenges that continuously appears during drilling across this formation. Historically, over 90% of wellbore problems in the Zubair Formation were due to wellbore instability. Problems associated with wellbore instability, such as tight hole, shale caving, stuck logging tools along with subsequent fishing, stuck pipe, and sidetracking result in increasing the non-productive time. This non-productive time has cost an enormous amount of …

Predictive Geohazard Mapping Using Lidar And Satellite Imagery In Missouri And Oklahoma, Usa, Olufeyisayo B. Ilesanmi

Doctoral Dissertations

”Light Detection and Ranging (LiDAR) and satellite imagery have become the most utilized remote sensing technologies for compiling inventories of surficial geologic conditions. Point cloud data obtained from multi-spectral remote sensing methods provide a detailed characterization of the surface features, in particular, the detailed surface manifestations of underlying geologic structures. When combined, point clouds eliminate bias from visual inconsistencies and/or statistical values. This research explores the competence of point clouds derived from LiDAR and Unmanned Aerial Systems (UAS) as a predictive tool in evaluating various geohazards. It combines these data sets with other remote sensing techniques to evaluate the sensitivity …

A Broad Iceland Plume Associated With Two Phase Transitions At The 660 Km Discontinuity: Constraints From Receiver Functions, Dan Wang

Doctoral Dissertations

"In spite of the fact that Iceland is frequently regarded as the archetypal example of mantle plumes, the existence, depth extent, origin, dimension and excess temperature of the hypothesized plume remain enigmatic and hotly debated. The controversy mostly originates from the limited vertical resolution of seismic tomography techniques and the associated uncertainty in the depth and lateral extents of the lower wavespeed anomaly. Here we utilize a robust receiver-function-based technique to image the topography of the 410 and 660 km discontinuities bordering the mantle transition zone beneath Iceland and surrounding oceanic regions, and construct thermal and seismic wavespeed models of …

Seismological Investigations Of Lithospheric Structure Beneath The East African Rift System And The Kalahari Craton, Tuo Wang

Doctoral Dissertations

"In spite of numerous geophysical studies have been conducted in East African Rift System and Southern Africa, the structure and evolution of the crust and upper mantle are still controversial. In this study, we applied multiple seismological techniques to investigate the structure in the crust and uppermost mantle beneath the East African Rift System and Kalahari Craton in southern Africa. First, the technique of ambient noise tomography was applied to image shear wave velocity model from surface to the depth of 40 km beneath the Malawi and Luangwa rift zones. For the first time, a high-resolution 3-D shear wave velocity …

History Of Natural And Anthropogenic Activities In Lake Izabal, Eastern Guatemala: Using Geochemical Evidence To Record Recent Contamination, Elisandra Hernandez

Doctoral Dissertations

”Water is essential for human subsistence. Stable freshwater supplies are needed as a source of food, drinking water, for transportation, recreation and economic development. Despite their recognized importance, anthropogenic activities have altered freshwater ecosystems around the world. Lake Izabal is the habitat for diverse aquatic species of flora and fauna, some of which are endemic and endangered. Its importance notwithstanding, anthropogenic activities developed in Lake Izabal’s catchment in recent years have compromised its status. This study used paleolimnological techniques to link past and recent anthropogenic activities such as mining operations and recent tilapia aquaculture. Relative abundances and concentrations of Pb, …

Provenance, Redox Conditions, And Diagenesis Of Shales In Chang 7 Member Of Upper Triassic Yanchang Formation, Ordos Basin, China, Bin Sun

Doctoral Dissertations

“This study aims to decipher provenance, redox conditions, and burial history of shales in Chang 7 Member of Upper Triassic Yanchang Formation, Ordos Basin, China. The first paper discusses the origins of single-channeled, vertical, sinuous, and calcite-bitumen-filled cracks in the shales. Results show that in early diagenesis, unconsolidated mud was expanded open by escaping gases produced during organic matter maturation under hydrothermal influences. Calcite initially filled the cracks; bitumen and pyrite came in later and occupied the cracks in various ways. Compaction occurred next and folded the calcite- and bitumen-filled cracks into sinuous shapes. The second paper uses geochemical and …

Seismic Attribute Assisted Depositional Facies Identification And Stratigraphic Correlation In The Central Gulf Coast Region Of Texas, Yani Lin

Doctoral Dissertations

"The sandstone deposits in the fluvial-dominated delta systems in the Lower Wilcox Group above the Cretaceous carbonate shelf edges of the Texas Gulf Coast Region are considered as high exploration potential reservoir bodies. However, the multi-phase regression and transgression during the late Paleocene to the early Eocene complicate the local depositional structure. The depositional facies is hard to be identified in details using the traditional seismic stratigraphic interpretation method. Seismic attributes are effective in detecting depositional facies, especially in mapping channels and investigating reservoir characteristics. In this study, we utilize seismic attributes to identify the principal depositional facies in the …

Fault Imaging Enhancement In Taranaki Basin, New Zealand And Rock Physics And Inversion Based Reservoir Characterization In The Central Gulf Coast Region Of Texas, Tianze Zhang

Doctoral Dissertations

"Fault imaging technique and reservoir characterization based on rock physics analysis and pre-stack inversion has been widely used hydrocarbon exploration. For the fault imaging technique, the ant tracking has been widely used in fault interpretation. However, the reliability of the results is highly dependent on appropriately choosing a signal processing method and volume attributes. In our study area, which lies in the southern Taranaki Basin, we applied Graphic Equalizer as the processing tool and the Chaos attribute before running the ant tracking algorithm. Results show that the procedure provides a better result and can map both the major and minor …

Paleoenvironment And Paleoclimate Of Ne Pangea In Early Permian-Linking Chemo- And Cyclo-Stratigraphy, Bogda Mountains, Nw China, Xin Zhan

Doctoral Dissertations

"The overall objective of this study is to understand physical and chemical responses of Earth Systems to environmental and climatic perturbations of diverse magnitudes and time scales in Bogda Mountains, NE Pangea. Field investigations, petrographic observations, and geochemical analyses have been used to interpret paleoenvironment and paleoclimate in cm-m-scale high-order cycles (HCs: 0.1-100 kyrs), low-order cycles (LCs: 1-10 Myr), and critical events of late Paleozoic ice age (LPIA: 320-260 Myr ago). Four organo-facies are one-to-one correlated with the four lithofacies in the meter-scale HCs, suggesting litho- and organo-facies are genetically linked and fundamentally controlled by environmental changes associated with lake …

Provenance And Depositional Environments Of The Upper Permian-Lowermost Triassic Fluvial And Lacustrine Sandstones, Wutonggou Low-Order Cycle, Bogda Mountains, Nw China, Dongyu Zheng

Doctoral Dissertations

"This work integrates petrographic and fieldwork studies and documents the spatial and temporal distributions of compositions and textures of the upper Permian-lowermost Triassic fluvial-lacustrine sandstones, Wutonggou low-order cycle (WTG LC), Bogda Mountains, NW China. In the first part, three petrofacies are identified on the basis of the relative abundances of quartz, feldspar, and lithics and conglomerate compositions and paleocurrent directions are documented. These data indicate that rocks of the eastern North Tianshan Suture (ENTS) and rift shoulders were the provenance lithology. Moreover, the upsection changes of petrofacies and conglomerate compositions suggest that the lithology of ENTS changed. During approximately Wuchiapingian, …

Origin Of Periclines In The Ozark Plateau, Missouri: A Field And Numerical Modeling, Chao Liu

Doctoral Dissertations

"A series upright sub-horizontal folds in sandstones of the early Ordovician Roubidoux Formation are exposed in road cuts along US Highway 63 in the northern part of the Salem Plateau of central Missouri for over a distance of approximately 10 km. These folds are in marked contrast to the more typical horizontal to sub-horizontal Ordovician strata of the Ozark Plateau. The origin of those folds remains enigmatic. The inspection of the characteristics of these folds using stereographic analysis revealed a non-cylindrical geometrical pattern than a near cylindrical fold. Structural data of 54 folds indicate an alternating basin and dome pattern. …

Crustal Structure Beneath The Eastern Margin Of The Tibetan Plateau And Adjacent Areas From Receiver Function Stacking And Gravity Modeling, Yunxin Peng

Doctoral Dissertations

"To provide constraints on the mechanisms responsible for the uplift and crustal thickening of the eastern Tibetan Plateau, the thickness and Vp/Vs values of the Moho beneath 153 seismic stations are obtained by stacking P-to-S converted phases from the Moho and gravity modeling. The resulting crustal thickness generally decreases from the northwest to the south-east, from about 60 km in the Bayan Har Block to 30 km in the Sichuan Basin. The crustal Vp/Vs measurements in the Qinling Orogenic Belt, Bayan Har Block, Chuxiong Basin, and Yangtze Platform indicate an overall intermediate to felsic crustal composition. With a relatively thick …

3d Seismic Attribute Analysis And Machine Learning For Reservoir Characterization In Taranaki Basin, New Zealand, Aamer Alhakeem

Doctoral Dissertations

"The Kapuni group within the Taranaki Basin in New Zealand is a potential petroleum reservoir. The objective of the study includes building a sequential approach to identify different geological features and facies sequences within the strata, through visualizing the targeted formations by interpreting and correlating the regional geological data, 3D seismic, and well data by following a sequential workflow. First, seismic interpretation is performed targeting the Kapuni group formations, mainly, the Mangahewa C-sand and Kaimiro D-sand. Synthetic seismograms and well ties are conducted for structural maps, horizon slices, isopach, and velocity maps. Well log and morphological analyses are performed for …

Paleogene-Early Neogene Palynomorphs From The Eastern Equatorial Atlantic And Southeastern Florida, Usa: Biostratigraphy And Paleoenvironmental Implications, Walaa K. Awad

Doctoral Dissertations

"The transition from greenhouse conditions (Paleocene-Eocene Thermal Maximum, PETM) to icehouse conditions (Early Oligocene) is not well documented in tropical-subtropical regions. One hundred and five samples from Ocean Drilling Program (ODP) Site 959 (Hole 959A and Hole 959D) in the Cote d'Ivoire-Ghana Transform Margin, Alo-1 Well in the northern Niger Delta (Anambra) Basin, Nigeria, and W-17001 in southeastern Florida were studied for their palynological contents. Dinoflagellate cysts were mainly utilized for age refinement and to detect subtle changes in paleoenvironment and paleoclimate during the Paleocene-Early Eocene (ODP Hole 959D and Alo-1 Well) and Late Eocene-Early Miocene (ODP Hole 959A and …

Lithospheric Layering And Thickness Beneath The Contiguous United States, Lin Liu

Doctoral Dissertations

"The Upper Mississippi Embayment (UME), where the seismically active New Madrid Seismic Zone resides, experienced two phases of subsidence commencing in the Late Precambrian and Cretaceous, respectively. To provide new constraints on models proposed for the mechanisms responsible for the subsidence, we computed and stacked P-to-S receiver functions recorded by 49 USArray and other seismic stations located in the UME and the adjacent Ozark Uplift and modeled Bouguer gravity anomaly data. The inferred thickness, density, and Vp/Vs of the upper and lower crustal layers suggest that the UME is characterized by a mafic and high-density upper crustal layer of ∼30 …

Layered Crustal And Mantle Structure And Anisotropy Beneath The Afar Depression And Malawi Rift Zone, Cory Alexander Reed

Doctoral Dissertations

"Although a wealth of geophysical data sets have been acquired within the vicinity of continental rift zones, the mechanisms responsible for the breakup of stable continental lithosphere are ambiguous. Eastern Africa is host to the largest contemporary rift zone on Earth, and is thus the most prominent site with which to investigate the processes which govern the rupture of continental lithosphere. The studies herein represent teleseismic analyses of the velocity and thermomechanical structure of the crust and mantle beneath the Afar Depression and Malawi Rift Zone (MRZ) of the East African Rift System. Within the Afar Depression, the first densely-spaced …

Geophysical Interpretation And Static Reservoir Modeling Of Structurally Complex Reservoir, Rg Oil Field Area, Sirte Basin, Libya, Abdalla A. Abdelnabi

Doctoral Dissertations

"Cambrian-Ordovician and Upper Cretaceous reservoir formations are found in the central western Sirte Basin, the main oil producing region in the Sirte Basin, Libya. As a result of changes in sedimentary environments and structural activities, a number of irregularities in reservoir continuity have developed, which negatively affected the overall performance of the reservoir. Effective simulation of such complex reservoirs can be achieved by integrating geophysical, geological, and petrophysical data to construct a reliable full-field static model, which has the potential to simulate the vertical and lateral variations in the reservoir formations. In this study, 2D and 3D seismic data acquired …

Depositional Systems, Sequence Architecture, And Controlling Factors Of An Eocene Stratigraphic Sequence At Minfeng Steep Margin Of Dongying Depression, Eastern China, Zhixin Li

Doctoral Dissertations

“This study is carried out in Minfeng area, the steep margin of Dongying half graben, eastern China, by integrating 3-D seismic, wireline log, and core data, and aims to interpret the depositional systems, reconstruct sequence stratigraphic architecture, and understand the controlling processes and factors at the steep margin of a rift basin. In the first part of this work, an Eocene stratigraphic sequence is divided into three systems tracts, corresponding to different stages of lake evolution, as early expansion (EEST), late expansion-early contraction (LEECST), and late contraction (LCST). EEST is the thickest and diagnostic by the best-developed marginal and basinal …

Receiver Function Imaging Of Mantle Transition Zone Discontinuities Beneath Alaska, Haider Hassan Faraj Dahm

Doctoral Dissertations

"Subduction of tectonic plates is one of the most important tectonic processes, yet many aspects of subduction zone geodynamics remain unsolved and poorly understood, such as the depth extent of the subducted slab and its geometry. The Alaska subduction zone, which is associated with the subduction of the Pacific Plate beneath the North America plate, has a complex tectonic setting and carries a series of subduction episodes, and represents an excellent target to study such plate tectonic processes. Previous seismological studies in Alaska have proposed different depth estimations and geometry for the subducted slab. The Mantle transition zone discontinuities of …

Phytoforensics: Applications In Vapor Intrusion Assessment, Jordan Lee Wilson

Doctoral Dissertations

"Vapor intrusion (VI) occurs when contaminants in the vapor phase migrate in the shallow subsurface and enter buildings through cracks, seams, and gaps and has been recognized as a serious human-health threat as occupants are exposed to potentially harmful concentrations over long periods of time. The VI pathway has recently (2017) been identified as a primary exposure pathway and implemented into the Hazard Ranking System for inclusion on the Nation Priorities List. However, assessing VI and human exposure is not simple and current methods are time-, cost-, and labor-intensive; intrusive; and temporally and spatially variability. Trees are ideal candidates for …