Open Access. Powered by Scholars. Published by Universities.®

Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Articles 1 - 11 of 11

Full-Text Articles in Physical Sciences and Mathematics

Influence Of Physical Variability Of Highly Weathered Sedimentary Rock On Nitrate In Area 3 Of The Enigma Field Research Site At Y-12, Erin Kelly Dec 2021

Influence Of Physical Variability Of Highly Weathered Sedimentary Rock On Nitrate In Area 3 Of The Enigma Field Research Site At Y-12, Erin Kelly

Masters Theses

Uranium processing and waste storage in unlined waste ponds leached contaminants into the groundwater at Y-12, Oak Ridge, Tennessee, from the 1950s to 1980s. Groundwater wells near the S-3 ponds have had the highest nitrate concentrations of groundwater anywhere in the world (>10,000 mg/L). For reference, the maximum contaminant level for nitrate in drinking water set by the U.S. Environmental Protection Agency is 10 mg/L. Since 2012, the ENIGMA (Ecosystems and Networks Integrated with Genes and Molecular Assemblies) group has been characterizing, monitoring, and conducting field experiments to understand the interactions between contaminants, microbes, and the subsurface. The goals …


The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan Aug 2020

The Legacy Of Mining In Southwest Missouri: Past And Present Conditions Of The Tri-State Mining District, Anastasia M C Mcclanahan

MSU Graduate Theses

The historic Tri-State Mining District (TSMD) of southwestern Missouri, southeastern Kansas, and northeastern Oklahoma has a history of lead and zinc mining that extended over a hundred years. During the district’s peak production period, the TSMD was one of the world’s largest producers of lead and zinc. The mining activities in the TSMD produced economic growth that supported the local communities and were essential to the victory of the Allied Forces during World War I and World War II. Beginning in the 1920s, the mining activities in the district slowly began to cease due to depletion of metal ores and …


The Dynamics And Speciation Of Arsenic In Drinking Water Wells In Eastern Wisconsin, Evvan Plank Dec 2019

The Dynamics And Speciation Of Arsenic In Drinking Water Wells In Eastern Wisconsin, Evvan Plank

Theses and Dissertations

Arsenic typically develops in Eastern Wisconsin groundwater as a result of oxidation of sulfide bearing minerals in the limestone bedrock (Schreiber et al. 2000). Naturally occurring arsenic exists in groundwater as oxyanions which have two oxidation states, As(III) and As(V). Under ambient pH conditions As(V) is primarily present as an anion (i.e., H2AsO4-) while As(III) tends to be uncharged (i.e., H3AsO3), making it much more difficult to remove through the existing treatment techniques such as adsorption and reverse osmosis (RO). Although many studies exist establishing arsenic concentrations across Wisconsin, there is a lack of investigations into the concentrations of each …


Potential Contamination Risk In Tennessee Aquifers From Oil And Gas Drilling, Emma Reed May 2019

Potential Contamination Risk In Tennessee Aquifers From Oil And Gas Drilling, Emma Reed

Chancellor’s Honors Program Projects

No abstract provided.


Estimating Watershed Mercury Contribution To Lake Fort Smith State Park, Arkansas, Usa, William Miles Harmon Aug 2018

Estimating Watershed Mercury Contribution To Lake Fort Smith State Park, Arkansas, Usa, William Miles Harmon

Graduate Theses and Dissertations

Mercury contamination associated with human activities poses global human health and environmental risks. A fish-consumption advisory has been in effect at Lake Fort Smith in central west Arkansas for more than a decade due to observed methylmercury concentrations in fish tissue. Lake Fort Smith is an important municipal drinking water supply and recreational resource. Water samples from the majority contributing tributary stream, Frog Bayou creek, were collected periodically, under differing hydrologic conditions in order to quantify the allochthonous mercury load delivered to the lake. Temperature, specific conductance, and turbidity data were collected and used to estimate dissolved organic carbon, methylmercury …


Evaluation Of Non-Ionic Surfactants With And Without Hydrogen Peroxide For The In-Situ Remediation Of Napl Contaminants, Charles E. Holada Apr 2017

Evaluation Of Non-Ionic Surfactants With And Without Hydrogen Peroxide For The In-Situ Remediation Of Napl Contaminants, Charles E. Holada

Masters Theses

Laboratory studies were conducted on Quillaja saponins and nine other surfactants commonly used to remove non-aqueous phase liquids (NAPLs) from soils and aquifers. The NAPL contaminant tested was diesel fuel. Static batch reactors containing an aged diesel-contaminated soil was treated with saponins and nine other commercially available surfactants to determine how much diesel fuel could be removed with the pore fluids after 1 day and 10 days of contact time. Of all the surfactants tested, saponins achieved the greatest removal of diesel fuel after 1 day and 10 days. There was large disparity in the diesel fuel removed by the …


Effects Of Road Salt On Asylum Lake Geochemistry, Davina A. Wyman Aug 2014

Effects Of Road Salt On Asylum Lake Geochemistry, Davina A. Wyman

Masters Theses

Several studies indicate that seasonal applications of road deicers can lead to saline runoff entering surface water and groundwater, which can in turn change the chemistry, density, and physical mixing patterns of urban lakes. An investigation at Asylum Lake, an urban lake located near three major roadways, was conducted to determine the degree of road salt contamination in the lake, to determine if salt loading disrupts seasonal mixing patterns, and to determine the extent of redox stratification present due to eutrophic conditions. Samples were collected monthly from the deepest point in Asylum Lake over a 19-month period and analyzed for …


Hydrogeology Of The Little River Animal Agriculture Environmental Research Unit And Impacts Of Dairy Operations On Groundwater, Robert Wesley Hunter Dec 2013

Hydrogeology Of The Little River Animal Agriculture Environmental Research Unit And Impacts Of Dairy Operations On Groundwater, Robert Wesley Hunter

Masters Theses

This thesis describes the development of an integrated hydrogeologic/hydrologic site assessment and groundwater/surface water quality monitoring program at the University of Tennessee – Little River Dairy Farm, located near Townsend, TN. Hydrologic/hydrogeologic investigations of streams and groundwater at the site have been underway for more than 5 years, and these are expected to provide background data for assessing impacts of dairy wastes. The lower half of the ~180 ha site consists of low-relief fields used for row crops, which are underlain by 4 – 9 m of alluvial deposits on top of black shale or limestone that include sinkhole features. …


The Extent Of Phosporus Redox Chemistry In West Central Florida Waters, Jacqueline Marie Sampson Jan 2013

The Extent Of Phosporus Redox Chemistry In West Central Florida Waters, Jacqueline Marie Sampson

USF Tampa Graduate Theses and Dissertations

Phosphorus (P) has long been acknowledged as a vital nutrient for living organisms and is a key factor responsible for the fresh water eutrophication. Our understanding of the phosphorus cycle has been limited by: (1) the common assumption that all P in the environment occurs primarily as phosphates and (2) by the limited analytical methods available to identify P speciation. In an attempt to understand the distribution and chemistry of phosphorus within a freshwater system we must be able to identify individual P species. To this end, we used a coupled High Performance Liquid Chromatograph (HPLC) - Inductively Coupled Plasma …


The History Of Mining In Cerro De Pasco And Heavy Metal Deposition In Lake Junin Peru, Erin M. Delman Jun 2012

The History Of Mining In Cerro De Pasco And Heavy Metal Deposition In Lake Junin Peru, Erin M. Delman

Honors Theses

Lake Junín covers 530-km2 and is located at 4,430-m in an intermontane basin between the eastern and western cordillera of the central Peruvian Andes. The lake sits between the large sulfide mining districts of La Oroya and Cerro de Pasco. Designated a National Reserve in 1974, Lake Junín drains northward to the Río San Juan, which joins the Río Mantaro within several kilometers of the lake. Dam construction by the Cerro de Pasco Copper Corporation on the Río Mantaro in 1932 caused the Río San Juan, the principal river draining Cerro de Pasco, to back up into the lake. Using …


Mineral-Scale Sr Isotopic Study Of Plagioclase In The Mafic Dikes Of The North American Wall And The Diorite Of The Rockslides, Yosemite Valley, California., Wendy Rae Nelson Mar 2006

Mineral-Scale Sr Isotopic Study Of Plagioclase In The Mafic Dikes Of The North American Wall And The Diorite Of The Rockslides, Yosemite Valley, California., Wendy Rae Nelson

Theses and Dissertations

The North American Wall mafic dikes and the diorite of the Rockslides mafic complex in the intrusive suite of Yosemite Valley show evidence of mixing with their host granites as well as with earlier components. Whole rock major element variation diagrams indicate the mafic rocks mixed with a more silicic component, but extrapolating to the silica end member does not yield the same result with each element. Trace element concentrations show a wide variation in concentration of Cr and Ni, with two samples showing enrichment in Cr (>300 ppm) and Ni (~44 ppm) compared to other samples (Cr =13-94 …