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Geochemistry

UNLV Theses, Dissertations, Professional Papers, and Capstones

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Limestone

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Full-Text Articles in Physical Sciences and Mathematics

Carbon Isotope Variations Associated With A Middle Ordovician Karstic Unconformity, Patricia Suzanne Williams May 2015

Carbon Isotope Variations Associated With A Middle Ordovician Karstic Unconformity, Patricia Suzanne Williams

UNLV Theses, Dissertations, Professional Papers, and Capstones

Large negative carbon isotope (δ13C) excursions have been documented from late Neoproterozoic-Paleozoic successions. These δ13C excursions have been widely used for regional and global stratigraphic correlation, particularly in strata with limited paleontological and radiometric age controls. Recent studies, however, argued that some negative δ13C excursions from stratigraphic record may have been resulted from meteoric/burial diagenesis, which commonly shifts both carbon and oxygen isotopes toward lower values. Testing the diagenetic origin of δ13C excursions in stratigraphic successions without independent stratigraphic framework has been difficult because it evolves into circular arguments about stratigraphic completeness …


The Origin Of Brucite In Hydrothermally Altered Limestone Near Devil Peak, Nevada, Rhonda L. Knupp May 1999

The Origin Of Brucite In Hydrothermally Altered Limestone Near Devil Peak, Nevada, Rhonda L. Knupp

UNLV Theses, Dissertations, Professional Papers, and Capstones

Open-space brucite was identified in veins crosscutting hydrothermally altered limestone near the Devil Peak rhyolite plug in southern Nevada. The brucite occurs with serpentine, calcite, chalcedony, hydromagnesite, dolomite, and clinochlore.

Brucite usually forms as a replacement mineral, but textural evidence indicates that the brucite at Devil Peak precipitated in open space. The presence of chalcedony in veins indicates the temperature of the hydrothermal fluid was <180oC during and after mineral deposition. Thermodynamic modeling shows this temperature is too low for replacement brucite to form, thus the low temperature of alteration may be a factor in this unusual occurrence of …