Physical Sciences and Mathematics Commons^™

The Upper Ocean At The End Of An Ice Age: Using Proxies In Benthic Foraminifera To Investigate Intermediate Water Changes During The Last Glacial Termination, Cassandre R. Stirpe

Electronic Theses and Dissertations

The ocean is an important component of the global climate system and plays a key role as a storage reservoir for heat and carbon. Under glacial conditions, the ocean sequestered carbon from the atmosphere, contributing to a cooler global climate. During the last glacial termination, that carbon was released back into the atmosphere, but the exact timing and mechanisms of this transfer are still not fully understood. This study examines waters from the intermediate depths of the Southern Ocean to gain insight into deglacial processes. Intermediate waters are capable of reacting to climate change on decadal timescales, making them a …

Investigating Mercer's Paradox: A 10be Chronology Of Moraines Deposited During The Last Glaciation At Soda Lake, Wind River Range, Wyoming, U.S.A., Lauren M. Woods

Electronic Theses and Dissertations

Here I use geomorphic mapping and ¹⁰Be surface-exposure dating to address the paradox that lies within the general understanding of the mechanisms driving ice-age climate and glacial cycles. The long-standing and widely accepted Murphy-Milankovitch hypothesis suggests glacial cycles are controlled by the local intensity of summer-time insolation. By this hypothesis, glacier maxima should be achieved at times of low insolation intensity and asynchronously between the polar hemispheres, a pattern which is inconsistent with the glacial geomorphic record. The ¹⁰Be chronology I have constructed of moraines at Soda Lake, Wind River Range, Wyoming, U.S.A. shows nine glacial advances to …

Glaciochemical Investigations In Three Southern Hemisphere Mountain Sites, Mariusz Potocki

Electronic Theses and Dissertations

The research presented in this dissertation focuses on glaciochemical records of trace elements, major ions, and stable water isotopes from three mountain regions: the Antarctic Peninsula, the Central Chilean Andes, and South Georgia Island.

The first section reports a significant increase in U concentration over 27 years on Detroit Plateau, Antarctic Peninsula. U concentrations in the ice core increase by as much as 102 between the 1980s and 2000s, accompanied by increased variability in recent years. The U concentration increase coincides with expanded open pit mining in the Southern Hemisphere, most notably Australia. Since other land-source dust elements do not …

Sulfur Isotope Composition Of Sulfides In Mafic Cumulates, Lesser Antilles Arc, Tyler Pollock

Electronic Theses and Dissertations

The sulfur isotope composition of sulfides in igneous rocks from magmatic arcs can be difficult to constrain due to the tendency for sulfur isotopes to fractionate during magma ascent and degassing. Cumulate xenoliths from the lower arc crust are representative of the most primitive magmas of the arc system. The Lesser Antilles arc presents a unique opportunity to investigate the sulfur isotope composition of arc magmas along a magmatic arc with many different magma plumbing systems. Here we present sulfur isotope compositions for primary magmatic sulfide inclusions and secondary interstitial hydrothermal sulfides in mafic cumulates from ten islands along the …

Geology And Lithogeochemistry Of The Pickett Mountain Volcanogenic Massive Sulfide Deposit, Northern Maine, Michael J. Mccormick

Electronic Theses and Dissertations

The Pickett Mountain deposit is a volcanogenic massive sulfide (VMS) base-metal deposit located 15 miles north of Patten, ME. The deposit, discovered in 1979, was abandoned in 1989. The deposit remained abandoned until 2017, when Wolfden Mt. Chase LLC purchased the land for further development after Maine mining regulations changed. This project is a collaboration between the University of Maine, the University of Maine – Presque Isle, Wolfden Resources Corp., and the University of New Brunswick to better understand the regional and deposit-scale geology related to the deposit to fill in gaps of the geologic story of northern Maine as …

Sulfur And Trace Metal Cycling At Convergent Margins, Jesse B. Walters

Electronic Theses and Dissertations

Subduction zones are the site of long-term chemical exchange between Earth’s surface and interior geochemical reservoirs. Subducting slabs are progressively depleted in volatiles and other mobile elements through dehydration and melting reactions. These elements are then introduced to the mantle wedge and volcanic arc. One consequence of this cycle is that volcanic arcs produce the most oxidized magmas on Earth. Sulfur, which exhibits a range in valence states from S^2- to S⁶⁺, is one of the few elements in the subducting slab capable of oxidizing the arc and mantle wedge. Sulfides in the slab may also act …

Variations In The Southern Hemisphere Westerlies Over The Last 23,000 Years From Lake Records In The Falkland Islands, Meghan M. Spoth

Electronic Theses and Dissertations

The Southern Hemisphere Westerlies (SHW) are an important driver of climate in the mid-latitudes of the Southern Hemisphere. Abrupt latitudinal migration of this coupled atmospheric-oceanic system is thought to be linked to the onset of the Termination at the end of the last ice age and to subsequent climatic variation through the late-glacial period and Holocene. However, the timing and spatial extent of these shifts, as well as variations in wind intensity, are poorly constrained, hindering our understanding of abrupt climate change in the Southern Hemisphere. In addition, future changes in the position and intensity of the SHW are a …

Mechanisms Of Ice Core Stable Isotope Variability In The Upper Kaskawulsh-Donjek Region, St. Elias Mountains, Yukon, Canada, Erin A. Mcconnell

Electronic Theses and Dissertations

I use instrumental and ice core records to examine drivers of observed isotope variability in the Upper Kaskawulsh-Donjek (UKD) region of the St. Elias Mountains, Yukon, Canada over the time frame of instrument-proxy overlap (mid-1900s to present). One of the drivers of post-depositional isotope signal alteration is the vertical percolation of meltwater from the glacier surface through shallow layers of snow, which causes a reduction in the amplitude of the isotope signal recorded in ice cores. I examine isotope signal preservation in two sites in the St. Elias Mountains: Eclipse Icefield and Icefield Divide. These sites are relatively close (~30 …

Fractures, Fluids, And Metamorphism: Shear Zone Initiation In The Marcy Anorthosite Massif, Adirondacks, New York, Usa, James Hodge

Electronic Theses and Dissertations

Localized shear zones are important rheological features that influence deformation behavior throughout the Earth’s middle-to-lower crust. Therefore, the processes through which shear zones initiate and localize remains an important geologic question. The study of strain localization and shear zone initiation is made difficult due to continued deformation overprinting the microstructures which lead to initiation and obfuscating the context in which localization occurred. The Marcy anorthosite in the Adirondack Highlands, New York, is a nominally granulite-facies, plagioclase-rich massif cut by centimeter-to-meter scale shear zones which provides a natural example of shear zone localization within the middle-to-lower crust. My work focuses on …

A Glacial History Of Roberts Massif, Central Transantarctic Mountains, Antarctica, Using Cosmogenic 3he, 10be, And 21ne Surface Exposure Ages, Alexandra M. Balter

Electronic Theses and Dissertations

Ice-free areas at high elevation in the central Transantarctic Mountains preserve moraines and drift deposits that delineate the former thickness and extent of the East Antarctic Ice Sheet (EAIS); cosmogenic exposure ages on these features indicate when the ice sheet was as or more extensive than today. Approximately 30 existing cosmogenic-nuclide exposure ages from scattered locations within these deposits suggest that some moraines and drift sheets are at least 5 Ma old. Those ages imply that the age range of these deposits may span warm periods during the Miocene and Pliocene, during which the EAIS is hypothesized to have been …

Late Holocene Climate And Environmental Reconstruction Derived From The Asian Ice Core Array (Aica), Bjorn Grigholm

Electronic Theses and Dissertations

Recent climate change has impacted natural and human systems across the Earth, emphasizing the need for greater understanding of both the existing and changing natural and anthropogenic forcing mechanisms and subsequent responses of the Earth’s climate system. High-resolution, multi-parameter ice core records retrieved and analyzed from two Asian Ice Core Array (AICA) sites, Geladaindong (central Tibetan Plateau) and Inilchek (central Tien Shan) were utilized to reconstruct atmospheric chemical concentrations and composition over the past ~100-500 years, improving the understanding of late Holocene climate and environmental variability in Asia. Both ice cores were analyzed for major and trace elements, major soluble …

Reconstructing Late Holocene Hydrographic Variability Of The Gulf Of Maine, Nina Millicent Whitney

Electronic Theses and Dissertations

I present an annually resolved reconstruction of seawater temperatures in the

western North Atlantic from 1695-1915. This paleoclimate record was constructed

using oxygen isotopes measured in precisely dated Arctica islandica shells collected

off of Seguin Island in the western Gulf of Maine. The temperature reconstruction

was derived from this oxygen isotope time series using a modern d¹⁸O_w-salinity

mixing line developed for coastal waters in the Gulf of Maine from water samples

collected over the last decade. The d¹⁸O_w and salinity composition of these water

samples indicate that coastal surface waters consist of a …

Characterization Of Firn Microstructure Using Scanning Electron Microscopy: Implications For Physical Properties Measurements And Climate Reconstructions, Nicole Spaulding

Electronic Theses and Dissertations

Samples from 12 East Antarctic firn and ice cores were analyzed using scanning electron micrcoscopy (SEM) in order to first develop a technique for the accurate characterization of physical properties and then to investigate the relationship between the physical microstructure and chemical properties. Both physical properties, such as grain size and porosity, and chemical properties, such as major ion and trace element concentration, provide information about atmospheric temperature changes, impurity content, accumulation rate and deformation history; therefore the characterization of both types of properties is necessary. Further, knowledge of the relationship between the physical and chemical properties may increase our …

Spatial And Temporal Changes In Stream Chemistry At Three Watersheds During High Discharge Episodes, Mollie Kate Laird

Electronic Theses and Dissertations

A longitudinal study of first order streams in three forested watersheds was conducted to determine spatial and temporal trends in geochemistry during high discharge acidic episodes. The watersheds were East Bear Brook and Hadlock Brook (Maine, USA), and Fernow WS3 (West Virginia, USA). Watersheds were selected based on soil type, stream pH, and historical chemistry. Stream sampling sites were distributed along an elevational gradient and sampled simultaneously during a high discharge episode. Base flow samples were collected prior to the start of the hydrological event. The Maine watersheds, East Bear Brook and Hadlock Brook, were sampled during fall 2005 rain …

Stable Sulfur Isotope Rations From West Antarctica And The Tien Shan Mountains: Sulfur Cycle Characteristics From Two Environmentally Distinct Areas, Lee Pruett

Electronic Theses and Dissertations

Continuous snow pit and ice core samples from two distinct environments (West Antarctica and the Tien Shan mountains in central Asia) were analyzed for 6 3 4 ~ and used to assess different regional sulfur cycle characteristics. In West Antarctica, 18 continuous samples were obtained from the RIDSA ice core (78.73"S, 116.33"W, 1740 m asl), covering the years 1935 to 1976. Each sample represents from 2 to 3 years of snow deposition, and the combination of summer and winter seasons varies by sample. 6 3 4 ~ values range from 3.1 %O to 9.9%0, and reflect the overall isotopic composition …