Physical Sciences and Mathematics Commons^™

Spectral Analysis Of Ground Penetrating Radar Response To Thin Sedimentary Layers, Swagata Guha, Sarah E. Kruse, E. E. Wright, U. E. Kruse

Geology Faculty Publications

Ground penetrating radar (GPR) systems utilized in studies of sedimentary deposits generate wavelengths (tens of centimeters) that are commonly much longer than the thickness of bedding (often millimeters to centimeters) within the target strata. Where this is the case, radar profiles represent interference patterns. Simple models of radar response to sequences of thin beds such as those found in coastal deposits show potentially detectable spectral shifts toward higher frequencies in radar returns. Spectral analysis of radar data over barrier beach deposits at Waites Island, South Carolina, shows that returns from packages with heavy mineral laminations are shifted toward higher frequencies …

Tunnel Geology As Seen By Geologists: Manhattan, New York City, Nazrul I. Khandaker, Stanley Schleifer, Masud Ahmed, Alan R. Slaughter, Belal A. Sayeed, Dorean J. Flores, Mario Jo-Ramirez

Publications and Research

Current exploratory boring operations in and around Manhattan, New York City are providing geologists and geotechnical engineers with a plethora of new and interesting geological information, which has not been previously reported. The rocks encountered, mostly medium to high-grade metamorphic rocks, with both mafic and felsic intrusives, are highly variable in competency and mechanical durability. One of the most frequently encountered rock types is a garnetiferous-muscovite-biotite schist which grades into schistose gneiss and displays a wide variety of structural, compositional, and textural attributes. Metamorphic minerals showing the variable degree of metamorphism include graphite, talc, garnet, kyanite, tourmaline, emory, and occasionally …

Geogram 2005, David J. Keeling Editor, Wku Department Of Geography And Geology

Earth, Environmental, and Atmospheric Sciences Publications

No abstract provided.

Regional-Scale Mid-Jurassic To Late Cretaceous Unroofing From The Adirondack Mountains Through Central New England Based On Apatite Fission-Track And (U-Th)/He Thermochronology, Mary K. Roden-Tice, Steven J. Tice

Mary K. Roden-Tice

Apatite fission-track (AFT) ages of 178 to 70 Ma for 108 samples from the Adirondack Mountains and eastern New York State, Vermont, western Massachusetts and Connecticut, and western New Hampshire indicate that widespread unroofing occurred throughout the region during the Middle Jurassic to Late Cretaceous. Additionally, (U-Th)/He ages of 167 to 85 Ma were determined on nine of those samples and support cooling rates of 1.8°-2.2°C/m.yr. from 100° to 65°C during the Middle Jurassic to Late Cretaceous. Assuming a geothermal gradient of 25°C/km, unroofing rates for the region were estimated to be, on average, ∼0.07-0.08 km/m.yr. The AFT age discontinuities …

Modeling Tephra Sedimentation From A Ruapehu Weak Plume Eruption, Costanza Bonadonna, J. C. Phillips, B. F. Houghton

Geology Faculty Publications

We present a two-dimensional model for sedimentation of well-mixed weak plumes, accounting for lateral spreading of the cloud, downwind advection, increase of volumetric flux in the rising stage, and particle transport during fallout. The 17 June 1996 subplinian eruption of Ruapehu produced a bent-over plume that rose to a height of 8.5 km in a wind field with an average velocity of 24 m s⁻¹ and generated a narrow deposit on land extending up to 200 km from vent. The sedimentation from the Ruapehu plume was dominated by coarse ash, with all the blocks and most of the lapilli …

Andrill Mcmurdo Ice Shelf Project Scientific Prospectus, Timothy R. Naish, Ross D. Powell, Peter J. Barrett, Huw Horgan, Gavin B. Dunbar, Gary S. Wilson, Richard Levy, Natalie Robinson, L. Carter, Alex R. Pyne, Frank Niessen, Stephen Bannister, Natalie Balfour, Detlef Damaske, Stuart Henrys, Phil Kyke, Terry Wilson

ANDRILL Project Information

Response of Antarctic ice sheets to projected greenhouse warming of up to 5.8!C by the end of the century is not known. Models on which predictions are based need to be constrained by geological data of the ancient ice sheets during times when Earth is known to have been warmer than today. The marine-based West Antarctic Ice Sheet (WAIS) and its fringing ice shelves are hypothesized (Clark et al., 2002; Weaver et al., 2003; Stocker, 2003) and documented (Scherer et al., 1998) to have collapsed during past “super-interglacial” warm extremes when global sea-level was more than 5m higher than today. …

Andrill Southern Mcmurdo Sound Project Scientific Prospectus, David M. Harwood, Fabio Florindo, Richard H. Levy, Christopher R. Fielding, Stephen F. Pekar, M. A. Speece, Sms Science Team, Andrill Science Management Office

ANDRILL Project Information

During the austral summer of 2007 the ANtarctic DRILLing program (ANDRILL) will drill from a sea-ice platform in southern McMurdo Sound to obtain new information about the Neogene Antarctic cryosphere and evolution of Antarctic rift basins.

Geochemistry Of Serpentinized Peridotites From The Mariana Forearc Conical Seamount, Odp Leg 125: Implications For The Elemental Recycling At Subduction Zones, Ivan P. Savov, Jeffrey G. Ryan, Massimo D'Antonio, Katherine Kelley, Patrick Mattie

Geology Faculty Publications

Recent examinations of the chemical fluxes through convergent plate margins suggest the existence of significant mass imbalances for many key species: only 20–30% of the to-the-trench inventory of large-ion lithophile elements (LILE) can be accounted for by the magmatic outputs of volcanic arcs. Active serpentinite mud volcanism in the shallow forearc region of the Mariana convergent margin presents a unique opportunity to study a new outflux: the products of shallow-level exchanges between the upper mantle and slab-derived fluids. ODP Leg 125 recovered serpentinized harzburgites and dunites from three sites on the crests and flanks of the active Conical Seamount. These …

Sulfide Mineralization In Deep-Water Marine Sediments Related To Methane Transport, Methane Consumption, And Methane Gas Hydrates, Matthew K. Thompson, Walter S. Borowski, Charles K. Paull, William Ussler Iii

EKU Faculty and Staff Scholarship

Patterns of sulfide sulfur concentration and sulfur isotopic composition (d³⁴ S) are perhaps related to upward methane transport, especially in sediments underlain by methane gas hydrate deposits. Increased methane delivery augments the effect of anaerobic methane oxidation (AMO) occurring at the sulfate-methane interface (SMI). Sulfate and methane co-consumption results in production of dissolved sulfide at the interface that is eventually sequestered within sulfide minerals (elemental sulfur, iron monosulfide, pyrite).

We examine the sediments of two piston cores collected over the Blake Ridge gas hydrate deposits (offshore southeastern United States) by extracting total sedimentary sulfide using chromium reduction. We use …

Probabilistic Modeling Of Tephra Dispersal: Hazard Assessment Of A Multiphase Rhyolitic Eruption At Tarawera, New Zealand, Costanza Bonadonna, Charles B. Connor, B. F. Houghton, Laura Connor, Marc A. Byrne, A. Laing, T. K. Hincks

Geology Faculty Publications

The Tarawera Volcanic Complex comprises 11 rhyolite domes formed during five major eruptions between 17,000 B.C. and A.D. 1886, the first four of which were predominantly rhyolitic. The only historical event erupted about 2 km³ of basaltic tephra fall (A.D. 1886). The youngest rhyolitic event erupted a tephra fall volume more than 2 times larger and covered a wider area northwest and southeast of the volcano (∼A.D. 1315 Kaharoa eruption). We have used the Kaharoa scenario to assess the tephra fall hazard from a future rhyolitic eruption at Tarawera of a similar scale. The Plinian phase of this eruption …

Evidence For Static Stress Changes Triggering The 1999 Eruption Of Cerro Negro Volcano, Nicaragua And Regional Aftershock Sequences, M. Diez, P. C. La Femina, Charles B. Connor, W. Strauch, Tenorio V. Tenorio

Geology Faculty Publications

Remarkable evidence of coupling between tectonic and magmatic events emerges from investigation of three tectonic earthquakes, aftershock sequences and eruption of Cerro Negro volcano, Nicaragua in 1999. Here, we explain this coupling through static stress changes following three Mw 5.2 earthquakes. We use focal mechanism solutions to estimate fault system geometry and magnitude of slip from these events, which are then used to calculate the change in minimum horizontal principal stress (σ₃) for the region and the change in Coulomb failure stress on optimally oriented fault planes. Results of these simulations indicate that σ₃ was reduced by …

Sulfide Mineralization Within Modern, Deep-Sea Marine Sediments And Oxygenation Of The Early Earth, Matthew K. Thompson, Walter S. Borowski

EKU Faculty and Staff Scholarship

The Earth’s atmosphere and oceans have not always been oxygenated. The exact pathway and timing of the oxygenation of the Earth’s early oceans is poorly constrained, although it appears that oxygenation was essentially complete by the beginning of the Cambrian (545 million years ago). Indeed, the appearance and diversification of the first animals may have been dependent on threshold levels of oxygen. Eventually we intend to use the sulfur isotopic composition of sulfide minerals (iron monosulfides and pyrite) present in sedimentary rocks to reconstruct the oxygenation of Proterozoic oceans, but first must strive to understand sulfide mineral formation in the …

Origin Of Secondary Sulfate Minerals On Active Andesitic Stratovolcanoes, D.R. Zimbelman, Robert O. Rye, G.N. Breit

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Sulfate minerals in altered rocks on the upper flanks and summits of active andesitic stratovolcanoes result from multiple processes. The origin of these sulfates at five active volcanoes, Citlalte´petl (Mexico), and Mount Adams, Hood, Rainier, and Shasta (Cascade Range, USA), was investigated using field observations, petrography, mineralogy, chemical modeling, and stable-isotope data. The four general groups of sulfate minerals identified are: (1) alunite group, (2) jarosite group, (3) readily soluble Fe- and Al-hydroxysulfates, and (4) simple alkaline-earth sulfates such as anhydrite, gypsum, and barite. Generalized assemblages of spatially associated secondary minerals were recognized: (1) alunite+silica±pyrite±kaolinite±gypsum±sulfur, (2) jarosite+alunite+silica; (3) jarosite+smectite+silica±pyrite, (4) …

Characterization Of Gas Chemistry And Noble-Gas Isotope Ratios Of Inclusion Fluids In Magmatic-Hydrothermal And Magmatic-Steam Alunite, Robert O. Rye, G.P. Landis

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Chemical and isotope data were obtained for the active gas and noble gas of inclusion fluids in coarse-grained samples of magmatic-hydrothermal and magmatic-steam alunite from well-studied deposits (Marysvale, Utah; Tambo, Chile; Tapajo´s, Brazil; Cactus, California; Pierina, Peru), most of which are discussed in this Volume. Primary fluid inclusions in the alunite typically are less than 0.2 µm but range up to several micrometers. Analyses of the active-gas composition of these alunitehosted inclusion fluids released in vacuo by both crushing and heating indicate consistent differences in the compositions of magmatic-hydrothermal and magmatic-steam fluids. The compositions of fluids released by crushing were …

Evolution Of The Magmatic-Hydrothermal Acid-Sulfate System At Summitville, Colorado: Integration Of Geological, Stable-Isotope, And Fluid-Inclusion Evidence, Philip M. Bethke, Robert O. Rye, Roger E. Stoffregen, Peter G. Vikre

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

The Summitville Au–Ag–Cu deposit is a classic volcanic dome-hosted high-sulfidation deposit. It occurs in the Quartz Latite of South Mountain, a composite volcanic dome that was emplaced along the coincident margins of the Platoro and Summitville calderas at 22.5±0.5 Ma, penecontemporaneous with alteration and mineralization. A penecontemporaneous quartz monzonite porphyry intrusion underlies the district and is cut and overlain by pyrite–quartz stockwork veins with traces of chalcopyrite and molybdenite. Alteration and mineralization proceeded through three hypogene stages and a supergene stage, punctuated by at least three periods of hydrothermal brecciation. Intense acid leaching along fractures in the quartz latite produced …

A Review Of The Stable-Isotope Geochemistry Of Sulfate Minerals In Selected Igneous Environments And Related Hydrothermal Systems, Robert O. Rye

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

The stable-isotope geochemistry of sulfate minerals that form principally in I-type igneous rocks and in the various related hydrothermal systems that develop from their magmas and evolved fluids is reviewed with respect to the degree of approach to isotope equilibrium between minerals and their parental aqueous species. Examples illustrate classical stable-isotope systematics and principles of interpretation in terms of fundamental processes that occur in these systems to produce (1) sulfate in igneous apatite, (2) igneous anhydrite, (3) anhydrite in porphyry-type deposits, (4) magmatic-hydrothermal alunite and closely related barites in high-sulfidation mineral deposits, (5) coarse-banded alunite in magmatic-steam systems, (6) …

Sulfur And Oxygen Isotopic Record In Sulfate And Sulfide Minerals Of Early, Deep, Pre-Main Stage Porphyry Cu–Mo And Late Main Stage Base-Metal Mineral Deposits, Butte District, Montana, C.W. Field, L. Zhang, J.H. Dilles, Robert O. Rye, M.H. Reed

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Typical porphyry-type Cu–Mo mineralization occupies two connected domal centers, the eastern Pittsmont and western Anaconda domes, that predate and largely underlie the well-known, throughgoing, Main Stage polymetallic veins of Butte. Among the sulfur-bearing minerals recovered from deep drill core of this early pre-Main Stage hydrothermal assemblage are anhydrite, chalcopyrite, pyrite, and molybdenite in veinlets bordered by K-silicate alteration, and pyrite from slightly younger quartz–pyrite veinlets with dgray-sericiticT alteration selvages. The ranges of δ³⁴S values for minerals of the K-silicate assemblage are 9.8–18.2%◦ for anhydrite (n=23 samples), 3.0%◦ to 4.7%◦ for molybdenite (n=6), 0.4%◦ to 3.4%◦ for pyrite (n=19), …

Snow Chemistry Across Antarctica, Nancy Bertler, Paul Andrew Mayewski, Alberto Aristarain, P. Barrett, S. Becagli, Ronaldo Torma Bernardo, Xiao Cunde, M. Curran, Qin Dahe, Daniel Dixon, Francisco Adolfo Ferron, H. Fischer, Markus Frey, M. Frezzotti, F. Fundel, Christophe Genthon, R. Gragani, Gordon Hamilton, M. Handley, Sungmin Hong, E. Isaksson, Ren Jiawen, Kokichi Kamiyama, Satoru Kanamori, Eija Karkas, L. Karlöf, S. Kaspari, K. Kreutz, A. Kurbatov, E. Meyerson, Hideaki Motoyama, R. Mulvaney, Zhang Mingjun, H. Oerter, E. Osterberg, M. Proposito, A. Pyne, U. Ruth, Jefferson Cardia Simoes, B. Smith, S. Sneed, Kimmo Teinila, F. Traufetter, R. Udisti, Aki Virkkula, Okitsugu Watanabe, B. Williamson, E. Wolff, Li Zhongqin

Earth Science Faculty Scholarship

An updated compilation of published and new data of major-ion (Ca, Cl, K, Mg, Na, NO₃, SO₄) and methylsulfonate (MS) concentrations in snow from 520 Antarctic sites is provided by the national ITASE (International Trans-Antarctic Scientific Expedition) programmes of Australia, Brazil, China, Germany, Italy, Japan, Korea, New Zealand, Norway, the United Kingdom, the United States and the national Antarctic programme of Finland. The comparison shows that snow chemistry concentrations vary by up to four orders of magnitude across Antarctica and exhibit distinct geographical patterns. The Antarctic-wide comparison of glaciochemical records provides a unique opportunity to improve …

Major And Trace Element Composition Of Copiapite-Group Minerals And Coexisting Water From The Richmond Mine, Iron Mountain, California, Heather E. Jamieson, Clare Robinson, Charles N. Alpers, R. Blaine Mccleskey, D. Kirk Nordstrom, Ronald C. Peterson

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Copiapite-group minerals of the general formula AR₄(SO₄)₆(OH)₂• nH₂O, where A is predominantly Mg, Fe²⁺, or 0.67Al³⁺, R is predominantly Fe³⁺, and n is typically 20, are among several secondary hydrous Fe sulfates occurring in the inactive mine workings of the massive sulfide deposit at Iron Mountain, CA, a USEPA Superfund site that produces extremely acidic drainage. Samples of copiapite-group minerals, some with coexisting water, were collected from the Richmond mine. Approximately 200 mL of brownish pore water with a pH of ‒0.9 were …

Secondary Sulfate Minerals Associated With Acid Drainage In The Eastern Us: Recycling Of Metals And Acidity In Surficial Environments, J.M. Hammarstrom, R.R. Seal Ii, A.L. Meier, J.M. Kornfeld

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Weathering of metal-sulfide minerals produces suites of variably soluble efflorescent sulfate salts at a number of localities in the eastern United States. The salts, which are present on mine wastes, tailings piles, and outcrops, include minerals that incorporate heavy metals in solid solution, primarily the highly soluble members of the melanterite, rozenite, epsomite, halotrichite, and copiapite groups. The minerals were identified by a combination of powder X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron-microprobe. Base-metal salts are rare at these localities, and Cu, Zn, and Co are commonly sequestered as solid solutions within Fe- and Fe–Al sulfate minerals. Salt …

Evaluation Of Argon Ages And Integrity Of Fluid-Inclusion Compositions: Stepwise Noble Gas Heating Experiments On 1.87 Ga Alunite From Tapajo´ S Province, Brazil, G.P. Landis, L.W. Snee, C. Juliani

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Quantitative analyses are reported for active (N₂, CH₄, CO, CO₂, H₂, O₂, HF, HCl, H₂S, SO₂) and noble (He, Ar, Ne) gases released by crushing and step heating of magmatic-hydrothermal alunite from the Tapajo´ s gold province in Brazil. This is the oldest known alunite (⁴⁰Ar/³⁹Ar age of 1.87 Ga), and because it has undergone minimal postdepositional thermal or tectonic strain, it is excellent material to test the retention of gas species in fluid inclusions and within the crystal structure over geological …

Alunite And The Role Of Magmatic Fluids In The Tambo High-Sulfidation Deposit, El Indio–Pascua Belt, Chile, C.L. Deyell, R.O. Rye, G.P. Landis, T. Bissig

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

The Tambo high-sulfidation deposit, located within the El Indio–Pascua belt in Chile, produced almost 25 t (0.8 M oz) of gold from altered Tertiary rhyodacitic volcanic rocks. Episodic magmatic-hydrothermal activity in the district occurred over at least 4 my and is characterized by several stages of acid-sulfate alteration, including magmatic-hydrothermal, magmatic steam, steam-heated, and apparent supergene assemblages. Two stages of Au±Ag mineralization are recognized and are hosted in barite and alunite within hydrothermal breccias and veins. Isotopic compositions of fluid in alunite show a dominant magmatic signature, with only a variable ¹⁸O-enriched meteoric water component throughout the entire hydrothermal …

Paleoproterozoic High-Sulfidation Mineralization In The Tapajo´S Gold Province, Amazonian Craton, Brazil: Geology, Mineralogy, Alunite Argon Age, And Stable-Isotope Constraints, Caetano Juliani, Robert O. Rye, Carmen M.D. Nunes, Lawrence W. Snee, Rafael H. Corrêa Silva, Lena V.S. Monteiro, Jorge S. Bettencourt, Rainer Neumann, Arnaldo Alcover Neto

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

The Brazilian Tapajós gold province contains the first evidence of high-sulfidation gold mineralization in the Amazonian Craton. The mineralization appears to be in large nested calderas. The Tapajós–Parima (or Ventuari–Tapajo´ s) geological province consists of a metamorphic, igneous, and sedimentary sequence formed during a 2.10 to 1.87 Ga ocean ̶ continent orogeny. The high-sulfidation mineralization with magmatic-hydrothermal alunite is related to hydrothermal breccias hosted in a rhyolitic volcanic ring complex that contains granitic stocks ranging in age from 1.89 to 1.87 Ga. Cone-shaped hydrothermal breccias, which flare upward, contain vuggy silica and have an overlying brecciated cap of massive silica; …

"Sour Gas" Hydrothermal Jarosite: Ancient To Modern Acid-Sulfate Mineralization In The Southern Rio Grande Rift, Virgil W. Lueth, Robert O. Rye, Lisa Peters

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

As many as 29 mining districts along the Rio Grande Rift in southern New Mexico contain Rio Grande Rift-type (RGR) deposits consisting of fluorite–barite±sulfide–jarosite, and additional RGR deposits occur to the south in the Basin and Range province near Chihuahua, Mexico. Jarosite occurs in many of these deposits as a late-stage hydrothermal mineral coprecipitated with fluorite, or in veinlets that crosscut barite. In these deposits, many of which are limestone-hosted, jarosite is followed by natrojarosite and is nested within silicified or argillized wallrock and a sequence of fluorite–bariteFsulfide and late hematite– gypsum. These deposits range in age from ~10 to …

Stable-Isotope Geochemistry Of The Pierina High-Sulfidation Au–Ag Deposit, Peru: Influence Of Hydrodynamics On So42-–H2S Sulfur Isotopic Exchange In Magmatic-Steam And Steam-Heated Environments, Richard H. Fifarek, Robert O. Rye

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

The Pierina high-sulfidation Au–Ag deposit formed 14.5 my ago in rhyolite ash flow tuffs that overlie porphyritic andesite and dacite lavas and are adjacent to a crosscutting and interfingering dacite flow dome complex. The distribution of alteration zones indicates that fluid flow in the lavas was largely confined to structures but was dispersed laterally in the tuffs because of a high primary and alteration-induced permeability. The lithologically controlled hydrodynamics created unusual fluid, temperature, and pH conditions that led to complete SO₄ ^2‒–H₂S isotopic equilibration during the formation of some magmatic-steam and steam-heated alunite, a phenomenon not …

Supergene Destruction Of A Hydrothermal Replacement Alunite Deposit At Big Rock Candy Mountain, Utah: Mineralogy, Spectroscopic Remote Sensing, Stable-Isotope, And Argon-Age Evidences, Charles G. Cunningham, Robert O. Rye, Barnaby W. Rockwell, Michael J. Kunk, Terry B. Councell

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Big Rock Candy Mountain is a prominent center of variegated altered volcanic rocks in west-central Utah. It consists of the eroded remnants of a hypogene alunite deposit that, at ~21 Ma, replaced intermediate-composition lava flows. The alunite formed in steam-heated conditions above the upwelling limb of a convection cell that was one of at least six spaced at 3- to 4- km intervals around the margin of a monzonite stock. Big Rock Candy Mountain is horizontally zoned outward from an alunite core to respective kaolinite, dickite, and propylite envelopes. The altered rocks are also vertically zoned from a lower pyrite– …

Chemical Openness And Potential For Misinterpretation Of The Solute Environment Of Coastal Sabkhat, Warren W. Wood, Ward E. Sanford, Shaun K. Frape

Geochemistry of Sulfate Minerals: A Tribute to Robert O. Rye

Sabkha deposits in the geologic record are commonly used to interpret the environmental conditions of deposition. Implicit in this use is the assumption that the solute system is chemically closed, that is, the authigenic minerals represent the composition of the fluids in their environment of origin. Thermodynamic and mass-balance calculations based on measurements of water and solute flux of contemporary Abu Dhabi coastal sabkha system, however, demonstrate that the system is open for sodium and chloride, where nearly half of the input is lost, but closed for sulfur, where nearly 100% is retained. Sulfur and chloride isotopes were consistent with …

Variations In Mineralogy, Temperature, And Oxygen Fugacity In A Suite Of Strongly Peralkaline Lavas And Tuffs, Pantelleria, Italy., John C. White, Minghua Ren, Don Parker

EKU Faculty and Staff Scholarship

Eight samples of pantelleritic lava and tuff and a lithic inclusion of trachyte from Pantelleria, Italy, have been thoroughly analyzed with an electron microprobe. These samples reveal five different mineral assemblages if classified by the presence of fayalite, aenigmatite, ilmenite, and magnetite: (1) augite + fayalite + ilmenite + magnetite, (2) augite + fayalite + ilmenite, (3) hedenbergite or sodian hedenbergite + fayalite + ilmenite + aenigmatite + quartz, (4) sodian hedenbergite or aegirine-augite + ilmenite + aenigmatite + quartz ± ferrorichterite, and (5) aegirine-augite + aenigmatite + quartz. Alkali feldspar (Or35–37) is present as the dominant phyric phase in …

2005- 2008 Unlv Mcnair Journal, Valerie Avery, Shana Bachus, Karmen K. Boehlke, Andrea Flores, Alden Kelly, Erick Lopez, Carol Preussler, Heather Shay, Ava Bookatz, Shaun Elsasser, Veronica Hicks, Shaida A. Jetha, Anthony Quinn, Thurithabhani Seneviratne, Teddy Boado Sim Jr., Liza Ward, Amris Henry-Rodgers, Jacquelynn Kaaa-Logan, Jason Orozco, Juan C. Plata, Bonnie Bartlett, Kathleen Bell, Vacheral M. Carter, Nydia Diaz, Kimberly Hackstock, Julio A. Luna, Charles Mao, Sandra Ramos, Precious Rideout, Benjamin Lee Watrous, Chet R. Whitley

McNair Journal

Journal articles based on research conducted by undergraduate students in the McNair Scholars Program

Table of Contents

Biography of Dr. Ronald E. McNair

Statements:

Dr. Neal J. Smatresk, UNLV President

Dr. Juanita P. Fain, Vice President of Student Affairs

Dr. William W. Sullivan, Associate Vice President for Retention and Outreach

Mr. Keith Rogers, Deputy Executive Director of the Center for Academic Enrichment and Outreach

McNair Scholars Institute Staff

Planar Oxides As A Novel Approach To Metal Ion Sorption Studies: From The Lab To The Field, Christine F. Conrad

Dissertations, Theses, and Masters Projects

The purpose of this work is to investigate the use of planar oxides as tools for metal ion sorption studies that can be used in both laboratory and field settings. to do this, a three-step approach was used. In the first step, the reactivities of the planar gamma-Al2O3 surfaces relative to pure phase gamma alumina was investigated through Pb(II) sorption studies. The relative quantitative uptake of Pb(II) on the planar gamma alumina was found to be comparable to that on the bulk. XAS analysis showed that the coordination geometry and local binding environment of the Pb(II) complexes were similar on …