Physical Sciences and Mathematics Commons^™

A Source-To-Sink Analysis Of The Pantanal Basin (Brazil): Implications For Weathering, Erosion, And Landscape Evolution In The World's Largest Wetland, Edward L. Lo

Theses and Dissertations--Earth and Environmental Sciences

Large back-bulge retro-arc basins have limited information about the sediment composition, yet they comprise important parts of the stratigraphic rock record. The exorheic Pantanal Basin is the world's largest continental wetland that regulates many valuable ecosystem services (water storage, nutrient cycling, agriculture, ranching, tourism, and transportation). This dissertation is composed of three studies that utilize a suite of tools to examine the most fundamental basin-wide source-to-sink sediment processes and controls that affect the characteristics and distribution of modern sediments.

The first paper consists of a metadata analysis of 76 shallow tropical floodplain lakes in the literature with bathymetric data and …

Distribution Of Particulate Organic Carbon – Fluxes And Inventories – In Growth-Faulted Coastal Wetlands, Samuel Joel Whitehead

Theses and Dissertations--Earth and Environmental Sciences

Coastal wetlands along the Northern Gulf of Mexico (NGOMx) are critically important but threatened environments which provide significant and diverse economic, social, and environmental value. These environments are essential components to the global carbon cycle, serving as one of the most efficient terrestrial carbon sinks. Since onset of the Industrial Revolution increasing rates of coastal wetland loss have been documented due to a variety of anthropogenic activities, neotectonic processes, subsidence, and rising sea-levels. This research utilized an array of methods and sedimentological analyses to test the hypothesis that growth-fault induced changes at Earth’s surface affects the delivery to, and storage …

Timing Of Regional Metamorphism In The Inner Piedmont And Blue Ridge Of North Carolina: Evidence From Monazite U-Pb Geochronology, Nicholas Edwin Powell

Theses and Dissertations--Earth and Environmental Sciences

Channel and escape flow, or lower crustal ductile flow and redirection from orogen-normal to orogen-parallel flow, are among the most impactful concepts introduced to explain shortening accommodation in large, hot orogens. In the Inner Piedmont (IP), southern Appalachians, channel and escape flow were proposed to have occurred during the Neo-Acadian (376–340 Ma) orogeny. However, the polymetamorphic history of the southern Appalachians makes it difficult to isolate thermal and deformational events for process-focused studies necessary to test these ideas in the IP. To address this, we used in situ laser ablation split stream (LASS) monazite U-Pb geochronology alongside new garnet chemical …

“The Tale Of 3,000 Zircons”: An Investigation Of Grenville Sedimentation In Amazonia Using U/Pb Detrital Zircon Geochronology, Felicia R. Harris

Theses and Dissertations--Earth and Environmental Sciences

The continental collision between Laurentia and Amazonia that generated Rodinia and the Grenville Orogen is proposed to be one of the largest, hottest and longest-lived orogens in Earth history. Subsequent erosion and weathering led to a mountain range’s worth of sediment recycled into clastic systems across North America, otherwise known as the “Great Grenville Sedimentation Event”. The Sunsas orogeny in Amazonia is correlative to the Grenville in North America and is proposed to be the result of final Rodinian collision at 1200-1000 Ma. Despite the connection between the two ranges and the robust sedimentary record in North America, little work …

Characterization Of Rare Earth Elements In The Illinois Basin Coals, Alireza Valian

Theses and Dissertations--Mining Engineering

The purpose of this study is to characterize the distribution and occurrence of rare earth elements (REEs) in the coal and coal-related material from the Illinois Basin. For characterizing the distribution of REEs, 17 core samples were investigated from various parts in the basin. Also, several individual samples from coal preparation plants and isolated geological occurrences were included in the study. In result, the average REE concentrations were calculated on a bed-to-bed basis, although the distribution of REEs in the coal beds was found laterally and vertically heterogeneous. A number of trends were found that describe the variations. Most importantly, …

A Multi-Method Investigation Of The Modern Sedimentation And Late Holocene Paleolimnology Of June Lake (Mono County, Ca), And A Survey-Based Analysis Of Ninth Graders’ Attitudes Towards Geology, Eva Lyon

Theses and Dissertations--Earth and Environmental Sciences

Three distinct manuscripts comprise this dissertation. The first analyzes the modern sedimentary basin of June Lake, a small glacial lake in the eastern Sierra Nevada of California (USA) using a number of data sets, including bathymetry, surface sediment composition, and seismic stratigraphy. The seismic survey revealed sublacustrine morphological features that suggest the basin originated due to ice scour, as well as four acoustically distinct stratigraphic units that reflect the history of sedimentation following glacial scouring. Corroborating the seismic record, sediment cores from the youngest unit are composed of hemipelagically deposited, organic-rich, laminated diatomaceous oozes alternating with coarse tephra beds. The …

Identification Of The Causes And Extent Of Elevated Methane Concentrations In The Groundwater Of Eastern Kentucky, Cristopher Alvarez Villa

Theses and Dissertations--Earth and Environmental Sciences

Recent development of unconventional oil and gas (UOG) resources has prompted concerns about its potential impact on public health and the quality of water and air resources. Elevated dissolved methane concentrations (> 1 mg/L) have been associated with proximity to UOG development and stray gas, but also with natural microbial activity. Baseline gas data, local hydrogeology and geochemistry context can aid assessment of methane sources and interactions. Methane concentrations in eastern Kentucky groundwater are above the “immediate action” level in some private/domestic water wells, show wide variations over small distances, and have been hypothesized to have different relationships to mining. …

Isotopic And Geochemical Tracers Of Groundwater Flow In The Shivwits Plateau, Grand Canyon National Park, Jonathan W. Wilson

Theses and Dissertations--Earth and Environmental Sciences

As the impacts of global climate change on water resources continue to become more apparent, proper understanding and management of groundwater resources will be needed as supplies become more strained. Traditional methods of characterizing groundwater systems are time-intensive, costly, and can be difficult to complete in remote areas. Using ambient geochemical tracers from discrete sampling could aid in characterizing spring systems through determining flow paths, recharge areas, and carbon cycling. However, using discrete seasonal samples to understand the hydrogeology of complex, mixed-lithology aquifers has not been extensively examined. Here we explore using δ¹³C of dissolved organic carbon (DOC), …

The Forestry Reclamation Approach: Measuring Sediment Mass Accumulation Rates In Reclaimed Mine Lands And Naturally Regenerated Logged Forests Of Eastern Kentucky, William E. Bond

Theses and Dissertations--Earth and Environmental Sciences

The spread of surface coal mining has resulted in loss of forests in the Appalachian region. The Forestry Reclamation Approach (FRA) was developed to provide guidance for restoring forests on reclaimed mined land. This study hypothesizes that the FRA will result in larger magnitude of sediment accumulation rates in reclaimed mine sites compared to those reclaimed using grassland reclamation. Three sediment cores and six trenches were sampled within four reclaimed mined and three previously logged sites in eastern Kentucky. Samples were processed for radionuclides, grain-size, stable isotopes (δ¹³C), and POC. LIDAR data were used to identify valley …

Temporal And Spatial Variability In Groundwater Flow And Chemistry Along The Cumberland River, Artemus, Kentucky, Amanda Rachelle Sherman

Theses and Dissertations--Earth and Environmental Sciences

Groundwater in the Kentucky Appalachian region is constrained by physiography and lithology. Lithostratigraphy, groundwater flow, and chemistry were delineated in the alluvial aquifer along the Cumberland River at H.L. Disney Training Center. To assess groundwater-river interactions and water quality, 11 monitoring wells were installed and sampled quarterly, plus the river and an existing bedrock well. Analytical results were evaluated for temporal and spatial trends. Collected soil cores were analyzed for bulk chemistry and grain size. Solute speciation and saturation indices were calculated and hydraulic conductivity estimated from grain-size analyses. Pumping and slug tests were performed to estimate hydraulic conductivity and …

A Joint Xrf-Δ13CCarb Chemostratigraphic Approach For Characterizing Paleo-Environmental Processes In The Mudstone-Dominated Wolfcamp Formation Of West Texas, Frank Tamakloe

Theses and Dissertations--Earth and Environmental Sciences

The Late Paleozoic Ice Age represents a dynamic period in Earth system history recording a shift from icehouse to greenhouse conditions. Concomitant with this change was a series high-frequency, high-amplitude sea level fluctuations leading to the deposition of “Kansas type” cyclothems in the Mid-Continent, and a similar rhythmic expression of interbedded shales and carbonates in the Midland Basin. Stable isotope geochemistry is a particularly powerful tool when examining these mud-rich successions because changes in organic matter partitioning may be recorded first in δ¹³C_DIC of sea-water and consequently in δ¹³C_carb of marine rocks. The δ …

Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna

Theses and Dissertations--Earth and Environmental Sciences

Understanding how karst aquifers store and transmit water and contaminants is an ongoing problem in hydrogeology. Flowpath and recharge heterogeneity contribute to the complexity of these systems. This thesis explores karst-conduit connectivity and water chemistry variability in the Houzhai catchment in Guizhou province, China. Artificial tracer tests were conducted during both the monsoon and dry seasons to understand temporal variability in connectivity and water velocity between karst features. Multiple flowpaths through the catchment are activated during the monsoon season and partially abandoned during the dry season. Additionally, gradient reversals during monsoonal high-flow events and as a result of pumping can …

Stratigraphy And Organic Geochemistry Reveal Patterns Of Late Quaternary Paleo-Productivity At Mono Lake, California, Bailee Nicole Hodelka

Theses and Dissertations--Earth and Environmental Sciences

Mono Lake (CA) is a hydrologically closed lacustrine basin well-known for its paleo-shorelines, which record fluctuations in water level for the last deglacial and late Holocene. Mono Lake is a sentinel of California’s water supply, situated in the rain shadow of the Sierra Nevada, a mountain range whose snowpack is a vital source of freshwater for urban and agricultural districts to the west and south. Recent droughts, floods, and wildfires show that California is threatened by climate change, but how these changes impact and get recorded by Mono Lake sediments remains poorly known. Here, we use a new radiocarbon-dated deepwater …

A Multi-Indicator Approach To Understanding The Diagenesis Of Carbonates In Pennsylvanian Mudrocks Of The Midland Basin, Alex J. Reis

Theses and Dissertations--Earth and Environmental Sciences

The Late Pennsylvanian was a time of frequent, rapid glacioeustatic sea-level changes. These changes were recorded in the Wolfcamp D Formation of the Midland Basin as a series of cyclothems similar to those studied in the Midcontinent region (e.g., Algeo and Heckel, 2008). This study focuses on identifying the mechanisms and controls on carbonate deposition and diagenesis through the Upper Pennsylvanian Wolfcamp D Formation and evaluating the potential for these layers to be stratigraphically significant. A stepwise progression of diagenetic processes was identified through the use of δ¹³C_carb and δ¹⁸O_carb, bulk geochemical and …

Catalyzed Synthesis Of Zinc Clays By Prebiotic Central Metabolites, Marcelo I. Guzman, Ruixin Zhou, Kaustuv Basu, Hyman Hartman, Christopher J. Matocha, S. Kelly Sears, Hajatollah Vali

Chemistry Faculty Publications

How primordial metabolic networks such as the reverse tricarboxylic acid (rTCA) cycle and clay mineral catalysts coevolved remains a mystery in the puzzle to understand the origin of life. While prebiotic reactions from the rTCA cycle were accomplished via photochemistry on semiconductor minerals, the synthesis of clays was demonstrated at low temperature and ambient pressure catalyzed by oxalate. Herein, the crystallization of clay minerals is catalyzed by succinate, an example of a photoproduced intermediate from central metabolism. The experiments connect the synthesis of sauconite, a model for clay minerals, to prebiotic photochemistry. We report the temperature, pH, and concentration dependence …

Zircon As A Proxy For "Taking The Temperature" Of Granites: An Example Using Zircon Thermometry Applied To Grenvillian Mid-Crustal Magmas In The Blue Ridge Province, Virginia, Samantha Rae Burk

Theses and Dissertations--Earth and Environmental Sciences

The Grenville orogeny was a protracted (~200 m.y.) series of “hot” magmatic- metamorphic events that contributed to the growth of the Laurentian margin in the late Mesoproterozoic. The granites contain remarkably high Zr content, lack xenocrysts, and become zircon saturated at high temperatures, which are all unusual for felsic magmas. The “hot Grenville granite” hypothesis is tested and use of high-Zr granitoids as potential zones of crustal magma generation through: U-Pb geochronology and cathodoluminescence imaging to assess inherited zircon components; quantitative modeling of zircon crystallization history using rhyolite-MELTS; and Ti-in-zircon thermometry. U-Pb zircon ages for two samples from the Virginia …

Stratigraphic, Geochemical, And Geochronological Analysis Of The Wolfcamp-D Interval, Midland Basin, Texas, Zachary S. Perlman

Theses and Dissertations--Earth and Environmental Sciences

Subsurface data derived from ~388 ft of drill core from Martin County (TX) were used to understand the depositional setting of the Wolfcamp-D, a petroleum producing interval in the Midland Basin. Elemental geochemistry collected via x-ray fluorescence revealed a highly variable depositional history marked by the deposition of diverse siliciclastic and carbonate lithofacies. Integration of multiple datasets resulted in the interpretation of nine lithofacies, whose deposition appears cyclical. Correlations between molybdenum and total organic carbon indicate slow recharge of bottom waters and anoxic/euxinicconditions within the basin. The presence of phosphatic nodules coinciding with siliceous black mudrocks suggested high levels of …

Field, Geochronologic, And Geochemical Constraints On Late Precambrian To Early Paleozoic Terrane Accretion In The Southern Appalachian Blue Ridge Province, Emma A. Larkin

Theses and Dissertations--Earth and Environmental Sciences

Xenolith-bearing orthogneiss of Amazonian affinity discovered in the Dellwood quadrangle in the Blue Ridge basement complex represents the oldest crustal component of the southern Appalachians (1.33 – 1.37 Ga: Quinn, 2012). New U-Pb zircon ages for migmatitic paragneiss of the Cartoogechaye terrane exposed in the Dellwood quadrangle reveal two unique detrital zircon age signatures that indicate either a local eastern Laurentian margin source or an exotic source. Detailed mapping, whole rock geochemistry, and U-Pb zircon geochronology were conducted to determine whether this exotic crustal component extends farther south into the Hazelwood 7.5” quadrangle. Lithological similarities exist between paragneisses in the …

Lithostratigraphic And Geochemical Characterization Of The Upper Pennsylvanian ‘Wolfcamp D’ Shale, Midland Basin (Usa): Implications For Paleoenvironments And Unconventional Petroleum Reserviors, Patrick W. Baldwin

Theses and Dissertations--Earth and Environmental Sciences

An integrated stratigraphic analysis of a ~350 ft drill core from Upton County (Texas) has revealed pervasive variability of several key siliciclastic and carbonate lithofacies in vertical section, where organic-rich siliceous mudrock beds alternate with aluminum-rich mudrocks and calcareous gravity flow deposits. Sediment chemistry, especially major and trace elements derived from x-ray fluorescence, captures this variability with high sensitivity. The high frequency chemostratigraphic variability appears to be cyclic, and it is interpreted to represent the first example of deep-water Late Pennsylvanian cyclothems for the Midland Basin. Positive trace metal (Mo, Cr) correlations to total organic carbon and gamma ray response …

Spring Responses To Storms And Seasonal Variations In Recharge In The Middle Atlas Region Of Morocco, Brett Andrew Howell

Theses and Dissertations--Earth and Environmental Sciences

Springs in the Middle Atlas Mountains of Morocco are significant sources for public water supply. From March 2014 to May 2015, water temperatures were measured hourly at three springs (Ribaa, Sidi Rached, and Zerouka); water levels were measured hourly at Sidi Rached and Zerouka; and daily turbidity data were obtained from Ribaa. From March 2014 to March 2015, daily water samples were taken at Zerouka for analyses of the stable isotopes deuterium and oxygen-18. Hourly weather data (precipitation and air temperature) were available from March 2014 to May 2015 from Ifrane, near Zerouka. Temperature responses varied between the springs, showing …

The Environmental Effects Of Coal Fires, Trent Garrison

Theses and Dissertations--Earth and Environmental Sciences

There are thousands of subterranean coal fires in the world that, because of incomplete combustion, emit a wide variety of volatile and semivolatile organic compounds to the atmosphere, water, and soil at concentrations that could pose health risks to humans and wildlife. The main goals of this study were to (1) review methods that are used to characterize physical and chemical characteristics of coal-fire sites, (2) determine relationships between gas emissions and physical and chemical characteristics of coal-fire sites, using a combination of regression and multivariate statistical methods, and (3) determine the concentrations of volatile and semivolatile organic compounds in …

Fluvial Responses To Growth Faulting In The West Pearl River, Louisiana, Stephen A. Prosser

Theses and Dissertations--Earth and Environmental Sciences

The Pearl River Delta (PRD) in southeastern Louisiana is an actively deforming deltaic complex displaying surface and near-surface evidence of growth faulting. Active growth faults in these environments are rarely identified at the surface, in part because the downthrown blocks often experience increased rates of sediment deposition leading to an obscured and low-relief, or entirely absent, surface expression. Faulting can be expressed in fluvial systems as changes in channel gradient, which often result in coincident changes in channel sinuosity, migration rates, planform deflections, and/or ponding features within the deformed zone. The study area is focused on a meander bend of …

Temporal And Spatial Characterization Of Macondo 252 Signatures In Gulf Of Mexico Shelf And Slope Sediments, Olivia P. Woodruff

Theses and Dissertations--Earth and Environmental Sciences

The long-term fate of hydrocarbons in the Gulf of Mexico (GOMx) following the 2010 Deepwater Horizon oil spill has yet to be fully characterized. Elemental (% C and % N), stable isotopes (δ¹³C_organic), and polycyclic aromatic hydrocarbon (PAH) molecular signatures were investigated in shelf and slope sediments collected in October 2010 and 2011 to gain insight into processes affecting the distribution and fate of spilled Macondo oil. Particulate organic carbon (POC) ranged between 1.55 and 2.22 wt. % in 2010 and 0.55 and 2.06 % in 2011 while the corresponding δ¹³C_organic ranges were …

Distribution And Impacts Of Petroleum Hydrocarbons In Louisiana Tidal Marsh Sediments Following The Deepwater Horizon Oil Spill, Rachel S. Hatch

Theses and Dissertations--Earth and Environmental Sciences

Following the 2010 Deepwater Horizon (DWH) spill, sediment cores were analyzed from marshes at various levels of oiling to determine how deeply oil penetrated sediment in these marsh environments, and if at these sites it had quantifiably affected benthic ecosystems. Minimum mixing depths were determined from penetration of the lithogenic radionuclide ²³⁴Th, which ranged from 0.25 to 4.5 cm. Sediment accumulation rates were determined using ²¹⁰Pb, with verification from ¹³⁷Cs in selected cores. Lead-210 profiles revealed long-term (decadal) mixing. Bay Jimmy, Louisiana was significantly affected by the DWH oil spill, as indicated by total polycyclic aromatic hydrocarbon …

Modeling Of Co2-Water-Rock Interactions In A Mississippian Sandstone Reservoir Of Kentucky, Anne M. Schumacher

Theses and Dissertations--Earth and Environmental Sciences

This study examined CO₂-water-rock interactions occurring during a carbon sequestration pilot test into a Mississippian oil reservoir in western Kentucky. New samples (n=62) and archived data, both collected from oil wells, were used to characterize the chemistry of formation waters from the Sugar Creek field in Hopkins County. In addition, core and cuttings samples (n=17) from the reservoir and overlying cap-rocks in, or near, the field were analyzed for bulk and clay mineralogy using X-ray diffraction. Electric logs were used to select sample intervals within the overlying cap-rocks and the center of the producing zones in the Jackson …

Abiotic Nitrate And Nitrite Reactivity With Iron Oxide Minerals, Prakash Dhakal

Theses and Dissertations--Plant and Soil Sciences

Under iron (Fe³⁺)-reducing conditions where aqueous Fe²⁺ and unreduced solid Fe³⁺-oxides commonly coexist, soil Fe²⁺ oxidation has been shown to be coupled with nitrate (NO₃^-) reduction. One possible secondary reaction is the involvement of NO₃^- and nitrite (NO₂^-) with Fe-oxide minerals found in many natural environments. Yet, spectroscopic measurements and kinetic data on reactivity of NO₃^- and NO₂^- with Fe-containing oxide minerals such as goethite (a-FeOOH), and magnetite (Fe₃O­₄) are not found in the literature. The reactivity of …

The Evolution Of Grenville Basement In The Eastern Great Smoky Mountains; Constraints From U-Pb Zircon Geochronology, Whole Rock Sm-Nd, And Feldspar Pb Geochemistry, Ryan Joel Quinn

Theses and Dissertations--Earth and Environmental Sciences

Identifying the crustal affinity of Grenville basement rocks in the Dellwood quadrangle, western NC, provides insight into the tectonic evolution of eastern Laurentia during Grenville orogenesis. U-Pb zircon geochronology of orthogneiss, augen gneiss, and mafic xenoliths in orthogneiss reveal magmatic pulses at 1130, 1180, and 1330 Ma and metamorphic episodes at 450 and 1040 Ma. Xenoliths in 1330 Ma orthogneiss are as old as 1382 Ma and represent the oldest component of Blue Ridge basement identified to-date. Feldspar Pb isotope values span a range between juvenile-Laurentian and southern-central Appalachian basement/Amazonia. Most Pb isotope data define an array consistent with crustal …

Petrologic, Geochemical, And Geochronologic Constraints On The Tectonic Evolution Of The Southern Appalachian Orogen, Blue Ridge Province Of Western North Carolina, Eric Douglas Anderson

University of Kentucky Doctoral Dissertations

The Blue Ridge Province of western North Carolina contains a wide variety of metamorphosed igneous and sedimentary rocks that record the tectonic effects of Precambrian and Paleozoic orogenic cycles. Tectonic interpretations of the events that led to the present configuration are varied and often conflicting. This investigation examines metamorphosed mafic rocks that are widely interpreted to have formed during the closure of ocean basins. Metabasites, and specifically eclogites, have a tendency to mark tectonic sutures and frequently preserve pressure (P), temperature (T), and age data (t) that can be gleaned from mineral equilibria and U-Pb isotopic compositions. As such, the …

Paleogene Mirelands Of The Upper Mississippi Embayment, Western Kentucky, Jennifer Marie Klein O'Keefe

University of Kentucky Doctoral Dissertations

Detailed petrography, geochemistry, and palynology together describe the depositional environments and paleoecology of an abandoned meander-fill system in western Kentucky. Oriented block petrography reveals alternating clay-rich and attrinite-rich zones of variable thickness. Woody tissues, where present, do not show dessication features and deflation layers could not be identified. Overall, petrography is indicative of a topogenous mire. Mire palyno-assemblages are less diverse than assemblages reported from clays in the region. Castanea-Cupuliferoidaepollenites assemblages dominate the entire system and other tree pollen are common; fungal spores are relatively uncommon. Weighted statistical analyses reveal ecological groupings beyond this dominance and define botanical succession within …

Compositional Variations In The Fire Clay Coal Bed Of Eastern Kentucky: Geochemistry, Petrography, Palynology, And Paleoecology, Cortland F. Eble, James C. Hower, William Morton Andrews Jr.

Report of Investigations--KGS

Bench samples of the Fire Clay coal bed, collected from 28 localities in a study area of eight 7.5-minute quadrangles in the Eastern Kentucky Coal Field, were analyzed geochemically, petrographically, and palynologically to determine any spatial or temporal trends among the studied parameters.

At most sample sites the Fire Clay is split by a flint-clay parting of probable volcanic origin. The upper bench of the Fire Clay coal generally is thick, laterally continuous, low in ash yield and sulfur content, has a moderate to high calorific value, and is high in total vitrinite content. In contrast, the lower bench generally …