Physical Sciences and Mathematics Commons^™

The Application Of Laser Intracavity Absorption Detector To Gas Chromatography Of Trace Organic Pollutants In Water, Robert B. Green

Technical Reports

A helium-neon (HeNe) laser operating simultaneously at 3.39 um (infrared) and 0.63 um (visible) has been used as a selective detector for hydrocarbons in the effluent of a gas chromatograph. The infrared and visible laser transitions originate at the same energy level and are competitive. When a hydrocarbon enters the laser's resonant cavity, the 3.39 um energy is absorbed due to the C-H stretching vibration and the visible emission is enhanced. The visible laser emission is monitored with a photodiode as a quantitative measure of the concentration of the absorbing molecule. The minimum detectable concentration for propane using the double-beam …