Physical Sciences and Mathematics Commons^™

A Period Examination Through Contemporary Energy Analysis Of Kevin Roche’S Fine Arts Center At University Of Massachusetts-Amherst, L Carl Fiocchi Jr

Doctoral Dissertations

Studies of buildings belonging to a subset of Modernist architecture, Brutalism, have included discussions pertaining to social and architectural history, critical reception, tectonic form and geometry inspirations, material property selections, period technology limitations, and migration of public perceptions. Evaluations of Brutalist buildings’ energy related performances have been restricted to anecdotal observations with particular focus on the building type’s poor thermal performance, a result of the preferred construction method, i.e. monolithic reinforced concrete used as structure, interior finish and exterior finish. A valid criticism, but one that served to dismiss discussion that the possibility of other positive design strategies limiting energy …

Stochastic Network Design: Models And Scalable Algorithms, Xiaojian Wu

Doctoral Dissertations

Many natural and social phenomena occur in networks. Examples include the spread of information, ideas, and opinions through a social network, the propagation of an infectious disease among people, and the spread of species within an interconnected habitat network. The ability to modify a phenomenon towards some desired outcomes has widely recognized benefits to our society and the economy. The outcome of a phenomenon is largely determined by the topology or properties of its underlying network. A decision maker can take management actions to modify a network and, therefore, change the outcome of the phenomenon. A management action is an …

Uptake And Accumulation Of Engineered Nanomaterials By Agricultural Crops And Associated Risks In The Environment And Food Safety, Yingqing Deng

Doctoral Dissertations

Engineered nanomaterials (ENMs) are being discharged into the environment and to agricultural fields, with unknown impacts on crop species. This study focused on the bioaccumulation of engineered nanomaterials into crops and the associated impact on plant growth and plant uptake of secondary contaminant. Investigations into the interactions between nanomaterials and agricultural plants will provide a more developed understanding of nanomaterials implications in the environment; in addition, evaluations of the risks associated with plant-nanomaterials interactions will provide guidelines for safe use of nanomaterials in agriculture. In the screening study on phytotoxicity, carbon-based nanoparticles (NPs) including C₆₀, MWCNTs, NH_{2 …}

Specific Phosphate Sorption Mechanisms Of Unaltered And Altered Biochar, Kathryn D. Szerlag

Masters Theses

Biochar has been shown to act as an effective sorbent for many organic and inorganic contaminants (including phosphate) and can help to improve the quality of our fresh water resources by preventing eutrophication. Most of the high efficiency biochar phosphate-adsorbent feedstocks are modified with chemical pretreatment, phytoremediation or anaerobic digestion to accumulate desired elements. The main objectives of this project were to first engineer magnesium (Mg) and calcium (Ca) altered biochar by chemical pretreatment followed by pyrolysis at either 350 or 550°C and evaluate their phosphate adsorption rate and potential as compared to their unaltered counterparts. Determination of surface physiochemical …

Ecological Consequences Of Lost Anadromous Forage Fish In Freshwater Ecosystems, Steven R. Mattocks

Masters Theses

Beginning in the early 1600s, dam construction in New England obstructed anadromous fish access to spawning grounds during migration. As a result, anadromous forage fish populations have declined, which has impacted freshwater, marine, and terrestrial ecosystems. To determine the impacts of dams on anadromous forage fish and freshwater ecosystems, I used historical and current data to estimate population changes in alewives (Alosa pseudoharengus) from 1600-1900. A significant reduction in spawning habitat occurred in New England as a result of 1,642 dams constructed between 1600 and 1900, resulting in 14.8% and 16.6% lake and stream habitat remaining by 1900, …

Factors Affecting Habitat Quality For Wintering Wood Thrushes In A Coffee Growing Region In Honduras, Brett A. Bailey

Masters Theses

Amongst the diversity of taxa that occur in the Neotropics, 200 migratory bird species that breed in temperate North America can be found. Many of these populations have seen significant declines since the 1960s. The Wood Thrush, Hylocichla mustelina, is one such species. Shade coffee and other agroforestry practices show potential for benefiting migratory species, but the quality of coffee habitat and optimal habitat characteristics for Wood Thrushes remain unknown.

I surveyed a spatially complex, agricultural landscape in Honduras outside the recognized winter range of the Wood Thrush and radio-tagged 46 individuals within rustic coffee farms during the winters …

Restoration: Bridging The Gaps A Graphic Translation Of Ecological Restoration, Alyssandra Black

Masters Theses

The terms restoration ecology and ecological restoration are used interchangeably confusing the definition and work of ecological restoration and its many components. Restoration ecology is a type of scientific practice whose work will be a component of a restoration project while ecological restoration is the sum of practices, social, historical and ecological that constitute the field of restoration (Higgs, 2005). Within our rapidly urbanizing society the role of ecological restoration and restoring ecosystem services is increasingly important, especially within our coastal cities. The goals of restoration differ when the classification of restoration techniques is by ecosystem service, not ecological function, …

A Comparative Sustainability Study For Treatment Of Domestic Wastewater: Conventional Concrete And Steel Technology Vs. Vegetated Sand Beds (Vsb’S) And Their Relative Differences In Co2 Production, Alicia M. Milch

Masters Theses

Conventional wastewater treatment in the U.S. is an energy dependent and carbon dioxide emitting process. Typical mechanical systems consume copious amounts of energy, which is most commonly produced from fossil fuel combustion that results in the production of CO₂. The associated organic load is also metabolized by microorganisms into CO₂ and H₂O. As the desire to reduce CO₂ output becomes more prominent, it is logical to assess the costs of conventional treatment methods and to compare them to alternative, more sustainable technology. Vegetated Sand Bed (VSB) and Reed Bed (RB) systems are green technologies …

Invasive Species Occurrence Frequency Is Not A Suitable Proxy For Abundance In The Northeast, Tyler J. Cross

Masters Theses

Spatial information about invasive species abundance is critical for estimating impact and understanding risk to ecosystems and economies. Unfortunately, at landscape and regional scales, most distribution datasets provide limited information about abundance. However, national and regional invasive plant occurrence datasets are increasingly available and spatially extensive. We aim to test whether the frequency of these point occurrences can be used as a proxy for abundance of invasive plants. We compiled both occurrence and abundance data for nine regionally important invasive plants in the northeast US using a combination of herbarium records, surveys of expert knowledge, and various invasive species spatial …

Sources Of Water And Solutes To The Salar De Atacama, Chile: A Coupled Hydrologic, Geochemical, And Groundwater Modeling Study, Lilly G. Corenthal

Masters Theses

Focused groundwater discharge in endorheic basins provides opportunities to investigate mechanisms for closing hydrologic budgets in arid regions. The Salar de Atacama (SdA), a closed basin in northern Chile, has accumulated over 1800 km³ of halite and a lithium-rich brine since the late Miocene primarily through evapotranspiration of groundwater. The hydrologic balance of SdA and sources of water and solutes required to explain this deposit are not well constrained. An adapted chloride mass balance method drawing on a database of over 200 water sample sites is applied to a remotely-sensed precipitation dataset to estimate spatially-distributed modern groundwater recharge. Comparing …