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Physical Sciences and Mathematics Commons

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Environmental Sciences

University of Kentucky

1978

Nuclear Double Resonance Spectrograph

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Development Of A New Technique For The Analysis Of Pesticides In Water, Prasad K. Kadaba, Pramode K. Bhagat, Radko Osredkar, V. R. K. Murthy Oct 1978

Development Of A New Technique For The Analysis Of Pesticides In Water, Prasad K. Kadaba, Pramode K. Bhagat, Radko Osredkar, V. R. K. Murthy

KWRRI Research Reports

A Nuclear Double Resonance Spectrograph has been designed and constructed with emphasis on quadrupolar nuclei of half-integral spins. The use of a data acquisition and processing system featuring the A/D converter, signal averager with built in fast Fourier transformation hardware greatly improves the S/N ratio. The spectrograph has been used to detect certain organochlorine, carbamate and symmetrical triazine pesticides. Concentration levels that can be detected range from 15 to 100 micrograms per liter. Since the measurements are done below ice temperatures, heat-labile compounds can be detected without conversion to more suitable derivatives as in gas chromatography. Fats and oils in …