Physical Sciences and Mathematics Commons^™

Do Microplastics, Vibrio Bacteria, And Warming Water Temperatures Cause Disease In The Northern Star Coral, Astrangia Poculata?, Heather Leigh Sheffey

OES Theses and Dissertations

As marine plastic pollution increases, it becomes imperative to study the effects of microplastics on marine fauna. Marine plastic debris is a vector for disease to marine invertebrates (Lamb et al., 2018; Rotjan et al., 2019). In this context, studies have shown Astrangia poculata will consume microplastics as they do their normal food (Allen et al, 2017; Rotjan et al., 2019). Further, with temperatures increasing worldwide, there is a concern the virulence of disease-causing bacteria will increase (Vezzulli et al., 2015). In a series of manipulative laboratory experiments, this study quantified changes in respiration rates and visual health of Astrangia …

Global Energy Consumption: An Analysis Of Variables That Shape Per Capita Usage, Or How Pump Price, Urbanization, And Fossil Fuels Imports Impact Fossil Fuels Consumption Per Capita Across Oecd Countries, Mila Demchyk Savage

Graduate Program in International Studies Theses & Dissertations

Among reasons explaining the importance of studying fossil fuel consumption are: crude oil is a subject of the international commodities market, thus, any fluctuation related to its' availability or price would impact the rest of the World; natural resources like oil, gas, and coal are limited; the extensive use of fossil fuels harms our surroundings, creating many environmental concerns; every human (on average) has been using more energy since 1971 and the trend is expected to continue. The upward trend is not consistent among individual countries. Therefore, the core question of my research is, `Why do some countries consume less …

Biocrude Production From Lignin In Hydrothermal Medium: Effect Of Rapid Heating And Short Residence Time, Kyoko Hirayama

Civil & Environmental Engineering Theses & Dissertations

This study aims to address knowledge gaps in the production of valuable products from waste streams generated during lignocellulosic biofuel production. The primary objective is to develop a process that converts lignin, a byproduct of bioethanol refineries, into a sustainable biolubricant.

The first chapter examines recent advancements in synthesizing biolubricants and investigates their scalability. It explores innovative materials, catalysts, chemical modification approaches, and additives that have emerged in the field. A particular hurdle is the oxidative stability of biolubricants derived from plant oils, which are prone to autooxidation due to their C=C bonds. To overcome this, the study aims to …

Evaluating Direct Filtration As An Alternative To Conventional Carbon-Based Advanced Treatment For Indirect Potable Reuse, Savannah M. Flemmer

Civil & Environmental Engineering Theses & Dissertations

Hampton Roads Sanitation District (HRSD) is recharging purified wastewater into the Potomac Aquifer via the Sustainable Water Initiative for Tomorrow (SWIFT) project. Conventional SWIFT treatment applies coagulation, flocculation, sedimentation, ozonation, biofiltration, granular activated carbon (GAC) adsorption, and ultraviolet disinfection to secondary effluent to produce water that meets drinking water standards for managed aquifer recharge. HRSD is considering implementing direct filtration as an alternative to conventional treatment for two additional SWIFT facilities. Direct filtration presents an opportunity for significant cost savings by eliminating sedimentation, shortening flocculation detention time, and reducing coagulant usage. Without upstream removal of solids and organics, however, biofilters …

Tidal Flooding In The Mid-Atlantic Region Of The Us: Water Quality Effects In The Lower Chesapeake Bay, Alfonso Macias Tapia

OES Theses and Dissertations

Many coastal areas around the globe suffer from nutrient pollution and its environmental, social, and economic consequences. Nutrient inputs can come from point (e.g., the end of a pipe) and nonpoint sources, from which the former are better constrained as sampling need only be conducted at a discharge point. Given the temporal and spatially extensive nature of tidal flooding events, they can represent another type of nonpoint source of nutrients to adjacent water bodies heretofore, unexamined and quantified. Most studies examining impacts of tidal flooding have focused on threats to resources on land, such as urban infrastructure and human health …

The Solidarity Manifesto: A New Network For Future Change, Sofia Calicchio

Graduate Program in International Studies Theses & Dissertations

Colonialism is a scheme of standpoint; colonizer versus colonized, West versus East, good versus bad. When put in the foreground, the value of what we see heavily relies on our perspective and knowledge. When learning to dissect, deconstruct, and decolonize spaces, we need to start utilizing decolonial thought as an historical tool rather than a true depiction of reality. Decolonizing spaces and recognizing Western colonization practices means challenging the normative structures in colonial history, thus breaking the cycle of oppression through building community and fostering solidarity. Drawing on theories exploring access to public spheres, representation, protection, permanence, cultural displacement and …

Molecular Evidence For The Export Of Terrigenous Organic Matter To The North Gulf Of Mexico By Solid-State 13C Nmr And Fourier Transform Ion Cyclotron Resonance Mass Spectrometry Of Humic Acids, Sarah Ann Ware

Chemistry & Biochemistry Theses & Dissertations

Marine organic matter is mainly believed to originate from autochthonous organic matter, while terrigenous organic matter is assumed to be largely degraded prior to reaching the open ocean or more recently replaced by marine organic matter via a stripping process. Sediment samples along a transect extending from the Mississippi River Birdsfoot Delta to the Mississippi Canyon on the Louisiana continental shelf were examined by advanced analytical techniques, electrospray ionization coupled to a 12T Fourier transform ion cyclotron resonance mass spectrometer (ESI-FTICR-MS) and quantitative solid-state multiple cross polarization magic angle spinning (multi-CPMAS) ¹³C NMR in an effort to understand the …

Fabrication Of Solid Oxide Fuel Cell Components Using Stereolithography 3d Printing, Hannah Dyer

Mechanical & Aerospace Engineering Theses & Dissertations

Transitioning from fossil fuel supplied energy to renewable technology must meet cost efficient parameters throughout the manufacturing process while possessing the characteristics of a functioning and reliable power source. With a significant demand in renewable energy products, developmental techniques require adaptive approaches and procedures for novel materials in the manufacturing phase. This report proposes how a solid oxide fuel cell (SOFC), a renewable energy system, can employ additive manufacturing for directly 3D printing its components by utilizing stereolithography (SLA) 3D printing techniques. Fabrication of the printed components from the mixtures were first mixed with varying concentrations of ceramic powder and …

Margalefidinium Polykrikoides Cyst Resuspension In The Lafayette River, A Sub-Tributary Of The Chesapeake Bay, Gabrielle Greaney, Eduardo Perez Vega, Katherine Crider, Dreux Chappell, Kimberly Powell, Richard Hale, Peter Bernhardt, Margaret Mulholland

Undergraduate Research Symposium

Harmful Algal Blooms are a collection of algae in a body of water that can cause serious environmental issues and health problems in both people and aquatic organisms. Dinoflagellates are microscopic, unicellular, and eukaryotic organisms that are well known for forming harmful algal blooms because of eutrophication. Coastal Virginia suffers from HABs in the Chesapeake Bay and its tributaries. A common species of dinoflagellate, known as Margalefidinium polykrikoides exists in the Chesapeake Bay. The purpose of this study is to determine if sediment resuspension produced by wind generated surface gravity waves cause cysts (dinoflagellate resting stages) to be suspended into …

Potential Repercussions Of Offshore Wind Energy Development In The Northeast United States For The Atlantic Surfclam Survey And Population Assessment, Sarah Borsetti, Daphne M. Munroe, Andrew M. Scheld, Eric N. Powell, John M. Klinck, Eileen E. Hofmann

CCPO Publications

The Atlantic surfclam Spisula solidissima fishery, which spans the U.S. Northeast continental shelf, is among the most exposed to offshore wind energy development impacts because of the overlap of fishing grounds with wind energy lease areas, the hydraulic dredges used by the fishing vessels, and the location of vessel home ports relative to the fishing grounds. The Atlantic surfclam federal assessment survey is conducted using a commercial fishing vessel in locations that overlap with the offshore wind energy development. Once wind energy turbines, cables, and scour protection are installed, survey operations within wind energy lease areas may be curtailed or …

A Multi-Taxon Analysis Of European Red Lists Reveal Major Threats To Biodiversity, Axel Hochkirch, Melanie Bilz, Catarina C. Ferreira, Anja Danielczak, David Allen, Ana Nieto, Carlo Rondinini, Kate Harding, Craig Hilton-Taylor, Caroline M. Pollock, Mary Seddon, Jean-Christophe Vié, Keith N. A. Alexander, Emily Beech, Manuel Biscoito, Yoan Braud, Ian J. Burfield, Filippo Maria Buzzetti, Marta Cálix, Kent E. Carpenter, Ning Labbish Chao, Dragan Chobanov, Maarten J. M. Christenhusz, Bruce B. Collette, Mia T. Comeros-Raynal, Neil Cox, Matthew Craig, Annabelle Cuttelod, William R. T. Darwall, Benoit Dodelin, Nicholas K. Dulvy, Eve Englefield, Michael F. Fay, Nicholas Fettes, Jörg Freyhof, Silvia García, Mariana García Criado, Michael Harvey, Nick Hodgetts, Christina Ieronymidou, Vincent J. Kalkman, Shelagh P. Kell, James Kemp, Sonia Khela, Richard V. Lansdown, Julia M. Lawson, Danna J. Leaman, Joana Magos Brehm, Nigel Maxted, Rebecca M. Miller, Eike Neubert, Baudewijn Odé, David Pollard, Riley Pollom, Rob Pople, Juan José Presa Asensio, Gina M. Ralph, Hassan Rankou, Malin Rivers, Stuart P. M. Roberts, Barry Russell, Alexander Sennikov, Fabien Soldati, Anna Staneva, Emilie Stump, Andy Symes, Dmitry Telnov, Helen Temple, Andrew Terry, Anastasiya Timoshyna, Chris Van Swaay, Henry Väre, Rachel H. L. Walls, Luc Willemse, Brett Wilson, Jemma Window, Emma G. E. Wright, Thomas Zuna-Kratky

Biological Sciences Faculty Publications

Biodiversity loss is a major global challenge and minimizing extinction rates is the goal of several multilateral environmental agreements. Policy decisions require comprehensive, spatially explicit information on species’ distributions and threats. We present an analysis of the conservation status of 14,669 European terrestrial, freshwater and marine species (ca. 10% of the continental fauna and flora), including all vertebrates and selected groups of invertebrates and plants. Our results reveal that 19% of European species are threatened with extinction, with higher extinction risks for plants (27%) and invertebrates (24%) compared to vertebrates (18%). These numbers exceed recent IPBES (Intergovernmental Platform on Biodiversity …

A Hybrid Deep Learning Approach For Crude Oil Price Prediction, Hind Aldabagh, Xianrong Zheng, Ravi Mukkamala

Computer Science Faculty Publications

Crude oil is one of the world’s most important commodities. Its price can affect the global economy, as well as the economies of importing and exporting countries. As a result, forecasting the price of crude oil is essential for investors. However, crude oil price tends to fluctuate considerably during significant world events, such as the COVID-19 pandemic and geopolitical conflicts. In this paper, we propose a deep learning model for forecasting the crude oil price of one-step and multi-step ahead. The model extracts important features that impact crude oil prices and uses them to predict future prices. The prediction model …

An Integrative Salt Marsh Conceptual Framework For Global Comparisons, Erik S. Yando, Scott F. Jones, W. Ryan James, Denise D. Colombano, Diana I. Montemayor, Stefanie Nolte, Jacqueline L. Raw, Shelby L. Ziegler, Luzhen Chen, Daniele Daffonchio, Marco Fusi, Kerrylee Rogers, Liudmila Sergienko

Biological Sciences Faculty Publications

Salt marshes occur globally across climatic and coastal settings, providing key linkages between terrestrial and marine ecosystems. However, salt marsh science lacks a unifying conceptual framework; consequently, historically well-studied locations have been used as normative benchmarks. To allow for more effective comparisons across the diversity of salt marshes, we developed an integrative salt marsh conceptual framework. We review ecosystem-relevant drivers from global to local spatial scales, integrate these multi-scale settings into a framework, and provide guidance on applying the framework using specific variables on 11 global examples. Overall, this framework allows for appropriate comparison of study sites by accounting for …

Coastal Science For Resilience And Management At The Cape Hatteras National Seashore, Nc, Usa, Michael J. Flynn, Thomas R. Allen, Meaghan E. Johnson, David E. Hallac

Political Science & Geography Faculty Publications

National seashores are cherished public lands with rich environmental, cultural, and historic resources. The Cape Hatteras National Seashore is one such coastal asset that is both bountiful yet vulnerable, with historic lighthouses, critical habitats, and recreational amenities alike facing threats of sea-level rise and continual storm and climate change impacts. Over 3 million visitors to the Seashore in 2021 set an annual visitation record. Historic resources such as the Bodie Island Lighthouse and Ocracoke Lighthouse are among the most visited sites, yet these assets are also among those most vulnerable to flooding, compromised structural integrity, and reduced accessibility. Future challenges …

Blue Carbon Science, Management And Policy Across A Tropical Urban Landscape, Daniel A. Friess, Yasmine M. Gatt, Tze Kwan Fung, Jahson B. Alemu I, Natasha Bhatia, Rebecca Case, Siew Chin Chua, Danwei Huang, Valerie Kwan, Kiah Eng Lim, Yudhishthra Nathan, Yan Xiang Ow, Daniel Saavedra-Hortua, Taylor M. Sloey, Erik S. Yando, Hassan Ibrahim, Lian Pin Koh, Jun Yu Puah, Serena Lay-Ming Teo, Karenne Tun, Lynn Wei Wong, Siti Maryam Yaakub

Biological Sciences Faculty Publications

The ability of vegetated coastal ecosystems to sequester high rates of “blue” carbon over millennial time scales has attracted the interest of national and international policy makers as a tool for climate change mitigation. Whereas focus on blue carbon conservation has been mostly on threatened rural seascapes, there is scope to consider blue carbon dynamics along highly fragmented and developed urban coastlines. The tropical city state of Singapore is used as a case study of urban blue carbon knowledge generation, how blue carbon changes over time with urban development, and how such knowledge can be integrated into urban planning alongside …

Anticipating And Adapting To The Impacts Of Climate Change On Low Elevation Coastal Zone (Lecz) Communities, Lynn Donelson Wright, Thomas Allen, Kiki Caruson, Alain Hénaff, Jaia Syvitski

Political Science & Geography Faculty Publications

[Scholarcy Abstract] The rates of sea level rise in coastal Virginia and the Chesapeake Bay significantly exceed the global rate and weakening of the Atlantic Meridional Overturning Circulation adds to the annual rates.

The original vision was to enhance future resilience of Low-Elevation Coastal Zone communities by advancing understandings and approaches to better anticipate and mitigate hazards to human health, safety and welfare and reduce deleterious impacts to coastal residents and industries. The goal of the thematic Research Topic has been to assemble interdisciplinary papers that contribute to better understanding of the couplings among physical, ecological, socioeconomic, management and policy …

Five Years Measuring The Muck: Evaluating Interannual Variability Of Nutrient Loads From Tidal Flooding, Alfonso Macías-Tapia, Margaret R. Mulholland, Corday R. Selden, J. Derek Loftis, Peter W. Bernhardt

OES Faculty Publications

Due to sea level rise, tidal flooding is now common in low-lying coastal systems around the world. Yet, the contribution of tidal flooding to non-point source nutrient loads and their impact on the quality of adjacent waters remains poorly constrained. Here, we quantified dissolved nutrient loading and Enterococcus abundance during annual autumnal king tides (i.e., perigean spring tides), between 2017 and 2021, in a sub-watershed of the lower Chesapeake Bay. To calculate nutrient loading from tidal flooding, we used geospatial inundation depths from a street-level hydrodynamic model to estimate floodwater volumes during each of the five sampling events and the …

Acidification Of Northeastern Usa Lakes From Rising Anthropogenic-Sourced Atmospheric Carbon Dioxide And Its Effects On Aluminum Speciation, Karen H. Johannesson, Jaxon Dii Horne, Anant Misra, Catherine Aliperta, Orpheus V. Meletis, Robert C. Santore, Christopher D. White, Georgia Mavrommati, David J. Burdige

OES Faculty Publications

The impact of rising atmospheric CO₂ (pCO₂^atm) from anthropogenic activities on pH, dissolved inorganic carbon, carbonate mineral saturation, and aluminum (Al) speciation is evaluated for 18 northeastern USA lakes using polythermal, sliding activity reaction path models. pCO₂^atm was forced using two scenarios from the IPCC's Sixth Assessment Report in which pCO₂^atm attains either 600 or 1,100 ppm in 2,100. Results suggest pH will decrease 0.15 and 0.32 pH units, _aCO^2-₃ will decrease 24% and 49%, and Ω_aragonite will decrease 21% and 45%, respectively. These changes are of the same …

Carbonate Chemistry And Carbon Sequestation Driven By Inorganic Carbon Outwelling From Mangroves And Saltmarshes, Gloria M. S. Reithmaier, Alex Cabral, Anirban Akhand, Matthew J. Bogard, Alberto V. Borges, Steven Bouillon, David J. Burdige, Mitchell Call, Nengwang Chen, Xiaogang Chen, Luiz C. Cotovicz Jr., Meagan J. Eagle, Erik Kristensen, Kevin D. Kroeger, Zeyang Lu, Damien T. Maher, J. Lucas Pérez-Lloréns, Raghab Ray, Pierre Taillardat, Joseph J. Tamborski, Rob C. Upstill-Goddard, Faming Wang, Zhaohui Aleck Wang, Kai Xiao, Yvonne Y.Y. Yau, Isaac R. Santos

OES Faculty Publications

Mangroves and saltmarshes are biogeochemical hotspots storing carbon in sediments and in the ocean following lateral carbon export (outwelling). Coastal seawater pH is modified by both uptake of anthropogenic carbon dioxide and natural biogeochemical processes, e.g., wetland inputs. Here, we investigate how mangroves and saltmarshes influence coastal carbonate chemistry and quantify the contribution of alkalinity and dissolved inorganic carbon (DIC) outwelling to blue carbon budgets. Observations from 45 mangroves and 16 saltmarshes worldwide revealed that >70% of intertidal wetlands export more DIC than alkalinity, potentially decreasing the pH of coastal waters. Porewater-derived DIC outwelling (81 ± 47 mmol m^{−2 …}

Rainwater Catchment System In Public Sector Housing, Araceli Peña, Muhammad Yanzar Sarin

2023 REYES Proceedings

Water is a universal right for all living beings on the planet, but today it has become a commercial good. It costs significantly to extract water from increasingly distant storage sources. For these reasons and many more the fight for water has become increasingly intense. Precisely, an alternative to avoid more dam construction is the implementation of public politic with actions focused on the integral solution of water, that is to say, that it be distributed fairly and equitably to all users, avoiding more concessions to great industries like as soft drinks and breweries, which are the main consumers and …

Computational Decision Support For Socio-Technical Awareness Of Land-Use Planning Under Complexity—A Dam Resilience Planning Case Study, Andreas Tolk, Jennifer A. Richkus, F. Leron Shults, Wesley J. Wildman

VMASC Publications

Land-use planning for modern societies requires technical competence as well as social competence. We therefore propose an integrative solution enabling better land-use planning and management through better-informed decision-making. We adapt a method developed for cross-disciplinary team building to identify the stakeholders and their various objectives and value systems. We use these results to populate artificial societies embedded into a dynamic data analytics framework as a tool to identify, explore, and visualize the challenges resulting from the different objectives and value systems in land-use planning and management. To prove the feasibility of the proposed solution, we present two use cases from …

Sea Ice Formation, Glacial Melt And The Solubility Pump Boundary Conditions In The Ross Sea, Brice Loose, Sharon Stammerjohn, Peter Sedwick, Stephen Ackley

OES Faculty Publications

Seasonal formation of Dense Shelf Water (DSW) in the Ross Sea is a direct precursor to Antarctic Bottom Water, which fills the deep ocean with atmospheric gases in what composes the southern limb of the solubility pump. Measurements of seawater noble gas concentrations during katabatic wind events in two Ross Sea polynyas reveal the physical processes that determine the boundary value properties for DSW. This decomposition reveals 5–6 g kg⁻¹ of glacial meltwater in DSW and sea-ice production rates of up to 14 m yr⁻¹ within the Terra Nova Bay polynya. Despite winds upwards of 35 m s …

The Importance Of Winter Dinoflagellate Blooms In Chesapeake Bay— A Missing Link In Bay Productivity, Nicole C. Millette, Sophie Clayton, Margaret R. Mulholland, Leah Gibala-Smith, Michael Lane

OES Faculty Publications

It is widely assumed that phytoplankton abundance and productivity decline during temperate winters because of low irradiance and temperatures. However, winter phytoplankton blooms commonly occur in temperate estuaries, but they are often undocumented because of reduced water quality monitoring in winter. The small body of in situ work that has been done on winter blooms suggests they can be of enormous consequence to ecosystems. However, because monitoring is often reduced or stopped altogether during winter, it is unclear how widespread these blooms are or how long they can last. We analyzed an over 30-year record of monthly phytoplankton monitoring samples …

Electron Beam Treatment For The Removal Of 1,4-Dioxane In Water And Wastewater, Robert Pearce, Xi Li, John Vennekate, Gianluigi Ciovati, Charles Bott

Electrical & Computer Engineering Faculty Publications

Electron beam (e-beam) treatment uses accelerated electrons to form oxidizing and reducing radicals when applied to water without the use of external chemicals. In this study, electron beam treatment was used to degrade 1,4-dioxane in several water matrices. Removal improved in the progressively cleaner water matrices and removals as high as 94% to 99% were observed at a dose of 2.3 kGy in secondary effluent. 1,4-dioxane removal was confirmed to be primarily through hydroxyl radical oxidation. The calculated electrical energy per order was found to be 0.53, 0.26, and 0.08 kWh/m³/order for secondary effluent (Avg. total organic carbon …

Elevation-Distributed Multistage Reverse Osmosis Desalination With Seawater Pumped Storage, Hani E. Elsayed-Ali

Electrical & Computer Engineering Faculty Publications

A seawater reverse osmosis (RO) plant layout based on multistage RO with stages located at different elevations above sea level is described. The plant uses the weight of a seawater column from pumped storage as head pressure for RO (gravity-driven multistage RO) or to supplement high-pressure pumps used in RO (gravity-assisted multistage RO). The use of gravitational force reduces the specific energy for RO compared to using high-pressure pumps. By locating the RO stages at different elevations based on demand sites, the total specific energy consumption for RO and permeate transport to different elevations above sea level is reduced from …

Tenvr: Matlab-Based Toolbox For Environmental Research, Aleksandar I. Goranov, Rachel L. Sleighter, Dobromir A. Yordanov, Patrick G. Hatcher

Chemistry & Biochemistry Faculty Publications

With the advancements in science and technology, datasets become larger and more multivariate, which warrants the need for programming tools for fast data processing and multivariate statistical analysis. Here, the MATLAB-based Toolbox for Environmental Research "TEnvR" (pronounced "ten-ver") is introduced. This novel toolbox includes 44 open-source codes for automated data analysis from a multitude of techniques, such as ultraviolet-visible, fluorescence, and nuclear magnetic resonance spectroscopies, as well as from ultrahigh resolution mass spectrometry. Provided are codes for processing data (e.g., spectral corrections, formula assignment), visualization of figures, calculation of metrics, multivariate statistics, and automated work-up of large datasets. TEnvR allows …