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Full-Text Articles in Physical Sciences and Mathematics

Predicting The Past, Recounting The Future: Human Ecology And A Prehistory Of Consciousness, Paul Faulstich Jan 1994

Predicting The Past, Recounting The Future: Human Ecology And A Prehistory Of Consciousness, Paul Faulstich

Pitzer Faculty Publications and Research

This paper is concerned with the organic derivation and primary meaning of Pleistocene finger flutings; I propose that in order to gain insight into the significance of the flutings, we must attempt an understanding of the physical and mental contexts in which they emerged. I suggest that finger flutings provided a cultural record in the Pleistocene which documented thought and action, and made it ready for reflection. Through the process of finger fluting, the human 'self' was objected and reality was modified in the experience of self-consciuosness. I argue that finger flutings, like language, were employed to discover and convey …


Resonance Raman Investigation Of The Radical Cation Of 1,3,5-Hexatriene, Tamas Keszthelyi, Robert Wilbrandt, Robert J. Cave, Jenifer L. Johnson Jan 1994

Resonance Raman Investigation Of The Radical Cation Of 1,3,5-Hexatriene, Tamas Keszthelyi, Robert Wilbrandt, Robert J. Cave, Jenifer L. Johnson

All HMC Faculty Publications and Research

The resonance Raman spectrum of the 1,3,5-hexatriene radical cation generated by v-irradiation in a Freon glass is reported. The spectrum is excited at 395 nm in resonance with the second absorption band. Identical spectra are obtained from ionized (E)- and (Z)-1,3,5-hexatriene. The presence of more than one rotamer has to be assumed to account for all the observed resonance Raman bands. The bands are assigned to a mixture of the two rotamers, calculated at lowest energy, the ttt an tct rotamers, on the basis of ab initio ROHF/6-31G calculated harmonic frequencies. The spectrum indicates that …