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Environmental Sciences

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2013

Abiotic Degradation

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Abiotic Degradation Of Chlorinated Hydrocarbons (Chcs) With Zero-Valent Magnesium (Zvm) And Zero-Valent Palladium/Magnesium Bimetallic (Pd/Mg)-Reductant, Fang Yu Jan 2013

Abiotic Degradation Of Chlorinated Hydrocarbons (Chcs) With Zero-Valent Magnesium (Zvm) And Zero-Valent Palladium/Magnesium Bimetallic (Pd/Mg)-Reductant, Fang Yu

Browse all Theses and Dissertations

Chlorinated hydrocarbons (CHCs) in groundwater can be treated by monometallic and bimetallic metal reductants through abiotic degradation. The breakdown of CHC is achieved by gaining electrons from those reductants and removing chlorines from CHC molecules to transform the CHCs into less chlorinated compounds. As a proven technology in groundwater treatment, permeable reactive barriers (PRBs) have been used to passively treat contaminated groundwater, in which granular metals can be used as reactive materials. This study explored the abiotic degradation of CHCs by zero-valent magnesium (ZVM) and bimetallic palladium/magnesium (Pd/Mg) reductants. Different CHCs (carbon tetrachloride, chloroform, dichloromethane (DCM), 1,2-dichloroethane (1,2-DCA), 1,1,2-trichloroethane (1,1,2-TCA), …