Physical Sciences and Mathematics Commons^™

Aspergillus Niger Decreases Bioavailability Of Arsenic(V) Via Biotransformation Of Manganese Oxide Into Biogenic Oxalate Minerals, Bence Farkas, Marek Kolenčík, Miroslav Hain, Edmund Dobročka, Gabriela Kratošová, Marek Bujdoš, Huan Feng, Yang Deng, Qian Yu, Ramakanth Illa, B. Ratna Sunil, Hyunjung Kim, Peter Matúš, Martin Urík

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The aim of this work was to evaluate the transformation of manganese oxide (hausmannite) by microscopic filamentous fungus Aspergillus niger and the effects of the transformation on mobility and bioavailability of arsenic. Our results showed that the A. niger strain CBS 140837 greatly affected the stability of hausmannite and induced its transformation into biogenic crystals of manganese oxalates—falottaite and lindbergite. The transformation was enabled by fungal acidolysis of hausmannite and subsequent release of manganese ions into the culture medium. While almost 45% of manganese was bioextracted, the arsenic content in manganese precipitates increased throughout the 25-day static cultivation of fungus. …

Assessment Of Switchgrass-Based Bioenergy Supply Using Gis-Based Fuzzy Logic And Network Optimization In Missouri (U.S.A.), Gia Nguyen, Erik Lyttek, Pankaj Lal, Taylor Wieczerak, Pralhad Burli

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Bioenergy has been globally recognized as one of the sustainable alternatives to fossil fuels. An assured supply of biomass feedstocks is a crucial bottleneck for the bioenergy industry emanating from uncertainties in land-use changes and future prices. Analytical approaches deriving from geographical information systems (GIS)-based analysis, mathematical modeling, optimization analyses, and empirical techniques have been widely used to evaluate the potential for bioenergy feedstock. In this study, we propose a three-phase methodology integrating fuzzy logic, network optimization, and ecosystem services assessment to estimate potential bioenergy supply. The fuzzy logic analysis uses multiple spatial criteria to identify suitable biomass cultivating regions. …

Storm Surges In The Bohai Sea: The Role Of Waves And Tides, Yuanyi Li, Huan Feng, Guillaume Vigouroux, Dekui Yuan, Guangyu Zhang, Xiaodi Ma, Kun Lei

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

A storm surge is a complex phenomenon in which waves, tide and current interact. Even though wind is the predominant force driving the surge, waves and tidal phase are also important factors that influence the mass and momentum transport during the surge. Devastating storm surges often occur in the Bohai Sea, a semi-enclosed shallow sea in North China, due to extreme storms. However, the effects of waves on storm surges in the Bohai Sea have not been quantified and the mechanisms responsible for the higher surges that affect part of the Bohai Sea have not been thoroughly studied. In this …

Statistical Analysis Of Nutrient Loads From The Mississippi-Atchafalaya River Basin (Marb) To The Gulf Of Mexico, Phyllis Okwan, Yi Zhen, Huan Feng, Shinjae Yoo, Murty S. Kambhampati, Abreione Walker, Shayne Boykin, Joe Omojola, Noel Blackburn

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

This study investigated the annual and seasonal variations in nutrient loads (NO₂⁻ + NO₃⁻ and orthophosphate) delivered to the Gulf of Mexico from the Mississippi-Atchafalaya River Basin (MARB) and examined the water quality variations. The results indicate that (1) annually, the mean NO₂⁻ + NO₃⁻ and orthophosphate loads showed a steady increase during 1996–1999, a persistent level during 2000–2007, and a moderate increase during 2008–2016; (2) seasonally, NO₂⁻ + NO₃⁻ and orthophosphate in MARB in spring and summer were higher than those in autumn and winter. Analysis of …

Green Strategic Planning Approach For International Shipping Activities, Xiaofang Wu, Luoping Zhang, Huan Feng

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Sustainability is a long-term and ultimate goal for international shipping, although it is slowly making progress. The shipping perspective that moves away from “port-to-port” operations to “door-to-door” services also requires international shipping to take a long-term and holistic view instead of fragmented efforts. How to achieve the long-term sustainability goal becomes a key issue for door-to-door international shipping. Hence, green strategic planning for door-to-door international shipping was proposed with green development that puts forward the eco-centric point of view as its basic theory for sustainability. This study used a strategic decision-making approach, a so-called multi-dimensional decision-making (MDDM), coupled with the …

Effect Of Foliar Spray Application Of Zinc Oxide Nanoparticles On Quantitative, Nutritional, And Physiological Parameters Of Foxtail Millet (Setaria Italica L.) Under Field Conditions, Marek Kolenčík, Dávid Ernst, Matej Komár, Martin Šebesta, Martin Urík, Edmund Dobročka, Ivan Černý, Ramakanth Illa, Raghavendra Kanike, Qian Yu, Huan Feng, Denisa Orlová, Gabriela Kratošová

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

It has been shown that the foliar application of inorganic nano-materials on cereal plants during their growth cycle enhances the rate of plant productivity by providing a micro-nutrient source. We therefore studied the effects of foliarly applied ZnO nanoparticles (ZnO NPs) on Setaria italica L. foxtail millet’s quantitative, nutritional, and physiological parameters. Scanning electron microscopy showed that the ZnO NPs have an average particle size under 20 nm and dominant spherically shaped morphology. Energy dispersive X-ray spectrometry then confirmed ZnO NP homogeneity, and X-ray diffraction verified their high crystalline and wurtzite-structure symmetry. Although plant height, thousand grain weight, and grain …

Stakeholders’ Perceptions Of Geographical Criteria For Loblolly Pine Management For Bioenergy Production In Virginia, Meghann Smith, Gia Nguyen, Taylor Wieczerak, Bernabas Wolde, Pankaj Lal, John Munsell

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

This study analyzed the perceptions of four stakeholder groups (forest landowners, private forest consultants, forest management researchers or educators, and federal or state agency foresters), regarding their management practices and preferred geographic growing conditions of loblolly pine in Virginia by combining AHP (analytical hierarchy process) and regression modeling. By ranking the importance of different geographical conditions for managing loblolly pine, we aimed to identify ways to support loblolly growth as a potential feedstock for biofuel generation. We achieved this through collecting survey responses from 43 stakeholders during the 2019 Virginia Forestry Summit. The results showed that the landowner, researcher/educator, and …

Potential Economic Impacts Of Allocating More Land For Bioenergy Biomass Production In Virginia, Thomas O. Ochuodho, Janaki Alavalapati, Pankaj Lal, Domena A. Agyeman, Bernabas Wolde, Pralhad Burli

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The growing attention to renewable energy and rural development has created greater demand for production of biomass feedstock for bioenergy. However, forest growth rates and the amount of land in most existing forests may not be sufficient to sustainably supply the forest biomass required to support existing forest products industries and the expanding bioenergy industry. Additionally, concerns about agricultural land use competition have dampened expansion of biomass production on agricultural land base. One of the ways to meet the growing forest biomass feedstock demand for bioenergy production is by allocating currently marginal non-forested land for growing bioenergy feedstocks. In Virginia, …

Environmental Forensic Characterization Of Former Rail Yard Soils Located Adjacent To The Statue Of Liberty In The New York/New Jersey Harbor, Diane Hagmann, Michael A. Kruge, Matthew Chi-Hymn Cheung, Maria Mastalerz, José Luis Gallego, Jay Prakash Singh, Jennifer Krumins, Xiaona N. Li, Nina M. Goodey

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Identifying inorganic and organic soil contaminants in urban brownfields can give insights into the adverse effects of industrial activities on soil function, ecological health, and environmental quality. Liberty State Park in Jersey City (N.J., USA) once supported a major rail yard that had dock facilities for both cargo and passenger service; a portion remains closed to the public, and a forest developed and spread in this area. The objectives of this study were to: 1) characterize the organic and inorganic compounds in Liberty State Park soils and compare the findings to an uncontaminated reference site (Hutcheson Memorial Forest); and 2) …

Impacts Of Climate Change And Bioenergy Markets On The Profitability Of Slash Pine Pulpwood Production In The Southeastern United States, Andrea Susaeta, Pankaj Lal

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

In this study, we assessed the impacts of climate change on the production of pulpwood and biomass for bioenergy, and the profitability of slash pine stands in the Southeastern United States. We employed the 3-PG (Physiological Processes Predicting Growth) model to determine the effects of future climates on forest growth and integrated it with a stand-level economic model to determine their impacts on optimal forest management. We found that the average production of pulpwood increased for all sites by 7.5 m³ ha⁻¹ for all climatic scenarios and productivity conditions. In the case of forest biomass for bioenergy, the …

Invasive-Plant-Removal Frequency—Its Impact On Species Spread And Implications For Further Integration Of Forest-Management Practices, Bernabas Wolde, Pankaj Lal

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

For a given invasive plant species and control method, effective invasive plant eradication requires regular monitoring and management. While most previous studies characterize invasive plant species, develop appropriate control methods, or prioritize species for management using aggressiveness and other considerations, few study why some forestland owners are less likely than others to regularly remove invasive plant species. Such information is useful in prioritizing and targeting forestland owners who are at greater risk for invasion, with the stands threatening adjacent forestlands. Towards this end, we surveyed 1800 forestland owners in Virginia and Texas. We use data on forestland owners’ socioeconomics and …

Morphometric Change Detection Of Lake Hawassa In The Ethiopian Rift Valley, Yonas Abebe, Menberu Bitew, Tenalem Ayenew, Clement Alo, Assegid Cherinet, Mulugeta Dadi

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The Ethiopian Rift Valley lakes have been subjected to environmental and ecological changes due to recent development endeavors and natural phenomena, which are visible in the alterations to the quality and quantity of the water resources. Monitoring lakes for temporal and spatial alterations has become a valuable indicator of environmental change. In this regard, hydrographic information has a paramount importance. The first extensive hydrographic survey of Lake Hawassa was conducted in 1999. In this study, a bathymetric map was prepared using advances in global positioning systems, portable sonar sounder technology, geostatistics, remote sensing and geographic information system (GIS) software analysis …

Spatio-Temporal Variability Of Processes Across Antarctic Ice-Bed–Ocean Interfaces, Florence Colloni, Laura De Santis, Christine S. Siddoway, Andrea Bergamasco, Nicholas R. Golledge, Gerrit Lohmann, Sandra Passchier, Martin J. Siegert

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Understanding how the Antarctic ice sheet will respond to global warming relies on knowledge of how it has behaved in the past. The use of numerical models, the only means to quantitatively predict the future, is hindered by limitations to topographic data both now and in the past, and in knowledge of how subsurface oceanic, glaciological and hydrological processes interact. Incorporating the variety and interplay of such processes, operating at multiple spatio-temporal scales, is critical to modeling the Antarctic’s system evolution and requires direct observations in challenging locations. As these processes do not observe disciplinary boundaries neither should our future …

Environmental Forensics Study Of Crude Oil And Petroleum Product Spills In Coastal And Oilfield Settings: Combined Insights From Conventional Gc-Ms, Thermodesorption-Gc-Ms And Pyrolysis-Gc-Ms, Michael A. Kruge, José Luis Gallego, Azucena Lara-Gonzalo, Noemi Esquinas

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

A representative set of five oil spill samples from four different regions displayed different product characteristics and different levels of weathering. Three of them were taken along shorelines affected by marine oil spill events, viz., Aboño and Prestige (Spain) and Deepwater Horizon (USA) and the other two were taken at inland oil spill sites (Angola and Kuwait). A multi-faceted environmental forensics approach revealed key molecular features. In addition to the conventional GC/MS analysis of saturated and aromatic fractions, the polar fractions also were analyzed, revealing a complex series of linear alkanones in those oil samples particularly enriched in aliphatics. Thermodesorption-GC-MS …

A Complex Legacy Of Contamination In Urban Estuarine Systems, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Industrialized urban waterways have typically suffered decades of contamination, varying in source and intensity as manufacturing and transportation practices evolved. The U.S. Environmental Protection Agency designates locales with particularly severe contamination as Superfund sites. Among these, the Gowanus Canal and lower Passaic River in the New York/New Jersey harbor estuary illustrate a complex range of contamination types.

The 2.2 km Gowanus Canal, with sluggish circulation driven mostly by tides, accumulated fine-grained sediments (average thickness of 3 m) highly enriched in organic carbon (OC, mean 11 % but up to 49 %) derived from hydrocarbons, sewage, coal, char, and biomass, along …

Analytical Pyrolysis Principles And Applications To Environmental Science, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Over the past half century, analytical pyrolysis has proven itself to be an effective means for the semiquantitative characterization of complex macromolecular organic substances. It has been demonstrated that instruments such as Py-FID, Py-MS, and in particular, Py-GC/MS can provide valuable geochemical insights when applied to a wide variety of problems in environmental science. The more widespread use of analytical pyrolysis methods in the evaluation of environmental pollution is recommended, because of their relatively low cost and information-rich results.

Pyrolysis is the heating of organic substances in an inert, oxygen-free atmosphere, thereby avoiding combustion. When performed on a large scale, …

Pyrolysis-Gc-Ms For The Rapid Environmental Forensic Screening Of Contaminated Brownfield Soil, Azucena Lara-Gonzalo, Michael A. Kruge, I Lores, B Gutiérrez, José Luis Gallego

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

An abandoned chemical plant in Asturias (Spain) was studied using a multi-faceted molecular fingerprinting approach, demonstrating that it is possible to: (1) carefully unravel tangled evidence resulting from multiple pollution sources, and (2) recognize major contaminants largely ignored by conventional analyses. This methodology employed a battery of GC-MS analyses of liquid chromatographic fractions of soil extracts, plus the pyrolysis products of the soil extract's asphaltene fraction and the whole soil itself. In this example, coal tar distillation and the subsequent production of naphthalene, phenols and polymer resins are responsible for most of the soil contamination. Styrene, naphthalene, indene, and their …

Oil Pollution In Water Bodies Of Restricted Circulation, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Coastal lagoons and embayments near urban centers around the world share many common characteristics and problems. Physical impediments to free water circulation (spits, barrier islands, internal islands, tombolos, submerged sills) often lead to water stagnation and, in the presence of excess nutrients, eutrophication. Urban and industrial activities provoke (usually accidental) spills of hazardous materials into these confined water bodies, such as crude petroleum and refined petroleum products, leading to difficulties for resident biota and potential hazards for human health. The sluggish turnover of these water bodies (or low-energy zones within them) may retard the natural attenuation of the spilled contaminants. …

Homicide In The Brazilian Favela: Does Opportunity Make The Killer?, Elenice De Souza De Souza Oliveira, Joel Miller

Department of Justice Studies Faculty Scholarship and Creative Works

High rates of homicide in Brazil are heavily concentrated in poor urban shanty towns or ‘favelas’. This paper looks beyond conventional social and economic explanations of homicides, and examines the relationship between situational factors and homicide incidents within a case-study favela in the city of Belo Horizonte. Initial exploratory research identified potential mechanisms linking local situational characteristics with homicide. A matched case–control study then tested hypotheses based on these mechanisms. When the characteristics of 100 addresses of homicide incidents were compared with those of 100 nearby non-homicide addresses, they showed statistical associations with drug areas, bars, alleys, windows onto the …

Effects Of Weathering On Aromatic Compounds In Beach Tars From The Deepwater Horizon Disaster, Gulf Of Mexico Coast, Usa, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Operators aboard the Deepwater Horizon drilling platform lost control of the Macondo No. 1 well about 90 km southwest of the Louisiana coast on April 20, 2010, leading to a catastrophic release of ca. 550 Gg of crude oil over the next 86 days [1]. Oil from the spill soon found its way to nearby coastal areas, leaving tarry deposits on beaches and marshes. Oil was reported on the beach at Gulf Shores, Alabama (180 km northeast of the well) on June 5 and the relatively fresh sample discussed herein (GSA) was collected that same day. Oil reached the beach …

Organic Geochemical Investigation Of A Highly Contaminated Urban Waterway: The Gowanus Canal, Brooklyn, New York, Usa, Michael A. Kruge, Kevin K. Olsen, Eric A. Stern

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The Gowanus Canal is an industrial waterway constructed in the mid-19^th century by widening and deepening a natural tidal channel. It is ca. 3 km in length and empties into Gowanus Bay, an arm of New York Harbor. Its banks, reinforced by bulkheads and piers, became the site of intensive industrial activity, including oil refining, coal gasification, soap making and tanning. Even though much of the industrial activity along the canal has ceased, its sediments remain highly enriched in organic and inorganic contaminants, with combined sewer outfalls continuing to transport pollutants into the canal. The canal area remains densely …

Significance Of Polycyclic Aromatic Hydrocarbons (Pahs) And Petroleum Biomarker Compounds In Contaminated Passaic River Sediments, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The lower Passaic River (northeastern New Jersey) flows through one of the most densely populated regions of the United States. The area’s long history of industrial activity is reflected in the complex and variable hydrocarbon composition of the river sediments. Sediments from river bottom grab samples at Newark and a 30 cm deep core at Kearny were subjected to thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS). This technique offers a practical alternative for rapid, inexpensive analysis, simply employing milligram quantities of dry, disaggregated sediment, avoiding the use of hazardous organic solvents. For each sample, a total of 181 hydrocarbons and organosulfur compounds …

Application Of Pyrolysis-Gc/Ms For Rapid Assessment Of Organic Contamination In Sediments From Barcelona Harbor, Michael A. Kruge, Albert Permanyer

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Pyrolysis-GC/MS is advantageous as a tool for rapid sediment contamination assessment because of the small sample size required, minimal sample preparation, and its ability to detect a wide variety of organic pollutants as well as naturally-occurring biological materials. Py-GC/MS was applied, together with determination of organic carbon, and major and minor element concentrations, to evaluate potentially contaminated sediments in the port of Barcelona (Spain) and the adjacent Llobregat River delta. Detected contaminant markers, most evident in the Old Port (Port Vell) area, included hopanes and alkylated PAHs (petroleum), sterenes (sewage), C₁₆-C₁₉ phenylalkanes (detergents) and parent …

An Environmental Geochemical Study Of Connecticut Marsh Sediments, Nicole A. Heller, Michael A. Kruge, Johan C. Varekamp, Tabitha Zierzow

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Core material from Spartina-dominated Housatonic and Connecticut River estuarine sites (ranging from low to high marsh) were investigated in order to test the hypothesis that organic and inorganic pollutants preferentially accumulate in the low marsh environment. Radiometric data indicate that the low marsh setting experienced sedimentation rates an order of magnitude greater than that of the mid to high marsh. The low marsh sediments from the Housatonic tend to have significantly higher concentrations of trace metals (e.g., Cu and Zn, likely contributed by brass mills formerly active upstream). Petrographic examination of the samples under reflected white and blue light …

Biogeochemistry And Contaminant Geochemistry Of Marine And Estuarine Sediments, New Haven, Connecticut (Usa), Michael A. Kruge, Gaboury Benoit

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The urbanized shore areas of Long Island Sound in the vicinity of New Haven, Connecticut (USA) have a long history of exposure to point and non-point sources of pollution, New Haven having been one of the birthplaces of the industrial revolution. As an unintended consequence of such activities, the region's sedimentary systems have incorporated a complex mixture of organic and inorganic contaminants. With its long and varied pollution history and the multiplicity of sedimentary environments (fluvial, estuarine, intertidal, marsh, etc.) present in a compact geographical area, the region is ideal natural laboratory for field testing new contamination assessment techniques. The …

Molecular Organic Geochemistry Of New York Bight Sediments. Sources Of Biogenic Organic Matter And Polycyclic Aromatic Hydrocarbons, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

As part of a multidisciplinary evaluation of the environmental impact of waste disposal in the New York Bight, a preliminary effort was undertaken to assess the molecular geochemistry of its sedimentary organic matter (OM). For this initial phase of the study, samples were taken from two New York Bight cores collected outside the area of known dumping [in Sandy Hook Bay, NJ], to establish the environmental context for future work on sediments from within dumpsite zones. The method employed was flash pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS), which is an organic microanalysis technique suitable for solid samples, in this case dried, raw …

Flash Pyrolysis Of Anthropogenic And Natural Organic Matter In Polluted Sediments, Sami T. Abdel Bagi, Michael A. Kruge, Gary L. Salmon

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

INTRODUCTION - Combustion products along with spilled petroleum and industrial chemicals contribute to environmental degradation by contaminating soils and sediments. Such anthropogenic organic matter (OM), if preserved in sediments, can serve an archival function, documenting the local, history of industrial pollution. Christensen and Zhang (1993) determined the sources of polycyclic aromatic hydrocarbons (P AH) to Lake Michigan from sedimentary records, finding that coal combustion was a major source for PAHs in these sediments. Bodzek and Luks-Betlej (1993) reported that atmospheric deposition is the main source of PAH in soils of the heavily industrialized Upper Silesia region of Poland. Smith and …