Physical Sciences and Mathematics Commons^™

Pirolityczne Metody Utylizacji Odpadów Niebezpiecznych - Przykładowe Rozwiązania I Emisja Zanieczyszczeń, Robert Oleniacz

Robert Oleniacz

The paper presents the pyrolysis and gasification processes of organic matter and the main directions of their use for the thermal disposal of hazardous waste. Used for this purpose the basic technical solutions are discussed with regard to existing and new technologies. Given the fact that the pyrolytic methods in Poland were primarily used for the incineration of medical waste, most attention was paid to a facility designated for such waste disposal. The problem of air pollutant emissions from this type of installation and some operating guidelines was also presented on the basis of the literature analyses and own research. …

New Developments In A Hazard Identification Algorithm For Hormone Receptor Ligands, Steven P. Bradbury, Ovanes Mekenyan, Nina Nikolova, Stoyan Karabunarliev, Gerald T. Ankley, Bjorn Hansen

Steven P. Bradbury

Recently we described the Common REactivity PAttern (COREPA) technique to screen data sets of diverse structures for their ability to serve as ligands for steroid hormone receptors [1]. The approach identi®es and quanti®es similar global and local stereoelectronic characteristics associated with active ligands through a comparison of energeticallyreasonable conformer distributions for selected descriptors. For each stereoelectronic descriptor selected, discrete conformer distributions from a training set of ligands are evaluated and parameter ranges common for conformers from all the chemicals in the training set are identi®ed. The use of discrete partitions of parameter ranges to de®ne common reactivity patterns can, however, …

Emisja Związków Fluoru Z Hutnictwa Żelaza, Marian Mazur, Marek Bogacki, Robert Oleniacz

Robert Oleniacz

The article presents the results of the last few years of comprehensive researches related to the emission of fluorine compounds from iron metallurgy in Poland. Determined of the levels of flue-gas concentrations and air emissions for fluorine in the form of gaseous and solid compounds, including water-soluble compounds (considered to be toxic). The study also made it possible to analyze of raw materials used in these processes taking into account fluorine content and its impact on the amount of fluorine compounds emitted to the air.

English title: Emissions of fluorine compounds with iron metallurgy.

Modelowanie Stężenia Ozonu W Niskiej Troposferze Na Przykładzie Nowego Sącza, Marek Bogacki, Marek Mazur, Robert Oleniacz

Robert Oleniacz

The paper presents the results of research related to the modeling of physicochemical phenomena occurring in the ground layer of the atmosphere in terms of ozone formation. For this purpose, the box model was used, in which the computational area is defined as a space designated by a steady surface and a variable height. Conducted in Nowy Sącz (Poland) experiment confirmed the possibility of using this type of model to diagnose and possibly forecasting ozone concentrations in any area of ​​calculation. The study also showed that the quality of the results depends mainly on accuracy in preparing of input data, …

Biotransformation Of 4-Methoxyphenol In Rainbow Trout (Oncorhynchus Mykiss) Hepatic Microsomes, Steven P. Bradbury, R. Kolanczyk, P. Schmieder, T. Spizzo

Steven P. Bradbury

Rainbow trout liver microsomes were used to study the O-demethylation and ring hydroxylation of 4-methoxyphenol (4-MP) (4-hydroxyanisole) at 11 and 25°C by directly measuring the production of the primary metabolite hydroquinone (HQ), 4-methoxycatechol (4-MCAT), and additional metabolites. An HPLC method with integrated ultraviolet (UV) and electrochemical detection (ECD) was developed for metabolite identification and quantification at low concentrations. Sample handling with appropriate buffers, solvents, low temperature and light prevented loss of extremely labile metabolites. Saturation kinetics for the production of HQ via O-demethylation of 4-MP (0.66–40 mM) was never achieved, with substrate solubility being the limiting factor. The linear rate …

Temporal Changes In Purity And Specific Activity Of Tritium-Labeled 2,3,7,8-Tetrachlorodibenzo-Ρ-Dioxin: Radiopurity Model For Toxicology, Steven P. Bradbury, Joseph D. Fernandez, Philip M. Cook, Brian C. Butterworth

Steven P. Bradbury

The specific activity (S) and radiopurity (R) of tritium labeled 2,3,7,8-tetrachlorodibenzo-p-dioxin, [3H]TCDD, were measured by gas chromatography/mass spectrometry (GC/ MS) while attempting to accurately characterize TCDD doses received by invertebrates, fish, and fish embryos during several toxicology studies conducted over a 3 year period. The [3H]TCDD sample was found to consist of six TCDD analogues involving hydrogen, deuterium, and tritium substitution at the 1,6-dibenzo-p-dioxin carbon positions and a complex mixture of impurities (with and without tritium labels). Planar aromatic impurities were identified as tolyl- TCDD adducts and appeared to result from the decay of 3H radiolabels to produce TCDD carbocations …

New Testing Apparatus For Assessing Interactive Effects Of Suspended Solids And Chemical Stressors On Plankton Invertebrates, Steven P. Bradbury, Carl Herbrandson, Deborah L. Swackhamer

Steven P. Bradbury

To better predict and interpret the responses of aquatic organisms to environmentally relevant chemical exposures, it is necessary to investigate the combined effects of physical (e.g., suspended solids) and chemical stressors. One of the limitations in investigating suspended solids–chemical interactions has been the lack of an appropriate testing system. The specific objective of the current study was to develop and assess a suspended solids testing apparatus (SSTA) for studies on the combined effects of suspended solids and chemicals on aquatic invertebrates. The SSTA was designed to permit the assessment of varying suspended solids concentrations on Daphnia magna at a constant …

A Synthesis Of Lead Isotopes In Two Millennia Of European Air, Charles Dunlap, Eiliv Steinnes, A. Russell Flegal

Charles Dunlap

Four airborne particulate records from ombrotrophic peat bogs in southern Norway, extending back 300 years, have been measured for chronology, lead concentration, and lead isotope composition. Since southern Norway receives an airborne lead signal that accumulates emissions from the European continent, the trend in the four bog records can be used to correlate previously reported measurements from France, Switzerland, England, and Greenland that cover different ranges of time. When these are compiled, the integrated European record that emerges spans the last 2300 years of human influence on lead in the air over Europe and suggests human control of lead in …