Physical Sciences and Mathematics Commons^™

Developing And Applying An Integrated Spatial Karst Evaluation And Management Priority Tool: Case Study In Tongass National Forest, Alaska, Usa, Christian Decelle

Masters Theses & Specialist Projects

Karst terrains are complex landscapes that are sensitive to human disturbance. Human activities have polluted and impacted many of these terrains around the world. To preserve these unique landscapes, many karst regions are protected and designated as national parks, geologic special areas, or UNESCO Biosphere Reserves. Despite the widespread general protection of karst landscapes globally, a review of each area’s management plan reveals there is no standardized method of cave and karst management or evaluation of karst impacts.

The non-standardization of karst management strategies may be due to the gap that exists between the needs of karst land managers and …

Development Of A Karst Tourism Management Index To Assess Tourism-Driven Degradation Of Protected Karst Sites, Keith R. Semler

Masters Theses & Specialist Projects

The intent of this research was to create and evaluate a karst tourism management index (KTMI). This index is intended to be a new management tool designed to quantify environmental disturbances caused specifically by tourism activities in karst regions, particularly show caves and springs. In an effort to assess the effectiveness of the index as a management tool in karst terrains, after development, the index was applied to six case study sites. A review of the management policies at each study site was conducted with the use of standard policy critique methods and semistructured interviews with managers at the study …

A Tourism Impact Index For Water-Based Natural Attractions Field-Tested In Subarctic And Maritime Climates, Jason Fox

Masters Theses & Specialist Projects

Tourism in cold and cool-climate regions is largely characterized by recreational and sightseeing activities at water-based natural attractions such as beaches, coastal cliffs, and waterfalls. While the economic benefits of the tourism industry can contribute to a sustainable future for these regions, the environmental implications of a hastilydeveloped industry cannot be ignored given that cold-climate and cool-climate landscapes are at risk of rapid environmental change from a warming climate and other environmental concerns. This study consisted of the development of the Tourism Impact Index for Water-Based Natural Sites, the first of its kind, and its application and refinement in the …

Dispersion Of Ammonia From Concentrated Animal Feeding Operations, Austin D. Wardall

Masters Theses & Specialist Projects

The purpose of this research is to investigate the dispersion of ammonia (NH3) from three Concentrated Animal Feeding Operations (CAFOs) in western Kentucky, as well as to investigate the Weather Research and Forecasting – Chemistry (WRF-Chem) model’s sensitivity response to initial NH3 concentrations under both wet conditions (significant precipitation) and dry conditions (no precipitation). As expected, pollutant concentrations generally were significantly higher near their points of origin and generally declined away from the sources. Contrary to expectations, ammonia tended to rise through the planetary boundary layer (PBL) regardless of atmospheric conditions. Results showed modeled NH3 pollution levels at the surface …

Advancing Methods To Measure The Atmospheric Co2 Sink From Carbonate Rock Weathering, Devon Salley Mr.

Masters Theses & Specialist Projects

With rising atmospheric CO2 concentrations, a detailed understanding of processes that impact atmospheric CO2 fluxes is required. While a sink of atmospheric carbon from the continents to the ocean from carbonate mineral weathering is, to some degree, offset by carbonate mineral precipitation in the oceans, efforts are underway to make direct measurements of these fluxes. Measurement of the continental sink has two parts: 1) measurement of the dissolved inorganic carbon (DIC) flux leaving a river basin, and 2) partitioning the inorganic carbon flux between the amount removed from the atmosphere and the portion from the bedrock. This study attempted to …

Zero-Waste Planning At Higher Education Institutions: A Case Study Of Western Kentucky University, Kianoosh Ebrahimi

Masters Theses & Specialist Projects

Over the past two decades, the number of universities that pursue zero-waste strategies has steadily increased. However, more study is required on several interrelated factors, policy barriers, and infrastructural fundamentals, which each influence the efficiency of waste management structures (WM) at universities. In this work, the role of the aforementioned factors in implementing an efficient sustainable WM program at higher education institutions was investigated, using Western Kentucky University (WKU) as a case study. The objectives of this study were to identify and assess what type of WM strategies should be priorities for a university that may lack stringent WM infrastructure. …

Evaluating The Effectiveness Of Regulatory Stormwater Monitoring Protocols On Groundwater Quality In Urbanized Karst Regions, Daniel C. Nedvidek

Masters Theses & Specialist Projects

Non-point pollution from stormwater runoff is one of the greatest threats to water quality in the United States today, particularly in urban karst settings. In these settings, the use of karst features and injection wells for stormwater management results in virtually untreated water being directed into the karst aquifer. Currently, no policies exist specifically to provide water quality protections to karst environments. This study utilized a combination of karst stormwater quality data, along with survey data collected from MS4 Phase II communities, and an analysis of current federal, local, and state water quality regulations, to assess the need for karst-specific …

Phosphorus Transport And Distribution In Kentucky Soils Prepared Using Various Biochar Types, Anvesh Reddy

Masters Theses & Specialist Projects

Conserving the environment is an issue that is gaining popularity day by day. Phosphorus transfer from agricultural soils is an important environmental issue that is being closely observed as the transport of phosphorous to water bodies is adversely affecting water quality due to accelerated eutrophication. It is important to establish phosphorous models that accurately account for soil test phosphorous. Standard models like SWAT (Soil and Water Assessment Tool) and EPIC (Environmental Policy Integrated Climate) were designed for serving this purpose. They are now used as the basis for developing new models that can more accurately account for the phosphorus transport, …

Making Music Sustainable: The Case Of Marketing Summer Jamband Festivals In The U.S., 2010, Melissa A. Cary

Masters Theses & Specialist Projects

Commercial music festivals in the United States have been growing in popularity since the 1960s. Today, many weekend-long music festivals are annual events spanning a variety of genres and often occur at the same locations each year. My research compares and contrasts how jamband music festivals are marketed as sustainable events and attempts to determine how the advertised sustainable practices are implemented and utilized at selected jamband music venues. The jamband genre of music emphasizes musical improvisation and borrows from other styles of music: rock, electronic, jazz, blues, folk, and bluegrass.

In addition, any impacts these festivals have upon the …

Removal Of Heavy Metals From Drinking Water By Adsorption Onto Limestone With A Focus On Copper And Aluminum Applications, Swarna Latha Somasani

Masters Theses & Specialist Projects

Elevated levels of arsenic and other heavy metals like copper, aluminum, zinc, and selenium in drinking water are found to have deleterious effects on human health. Hence, finding methods for reducing their levels is critical. Iron-coated limestone is used as an adsorption material for the removal of heavy metals from drinking water. Removal of heavy metals by native or uncoated limestone was also observed and used for comparison to and evaluation of the improvement in removal efficiency from the ironcoated material. The removal efficiency with limestone was studied for different concentrations of heavy metals. Kinetic studies were done to determine …

Multiple Storm Event Impacts On Epikarst Storage And Transport Of Organic Soil Amendments In South-Central Kentucky, Sean M. Vanderhoff

Masters Theses & Specialist Projects

The groundwater in agricultural karst areas is susceptible to contamination from organic soil amendments and pesticides. During major storm events during 2011, dye traces were initiated using sulphorhodamine-B, fluorescein and eosine in a groundwater recharge area where manure was applied to the ground. Fecal coliform samples were collected from significant storm events from January-September 2011. Water samples and geochemical data were collected every four hours before, during, and between the storm events from a waterfall in Crumps cave flowing from the known recharge area to track the transport and residence time of the epikarst water and organic soil amendments during …

Distribution Of Trace Elements In Cumberland River Basin Reservoir Sediments, Laura Mahoney Benneyworth

Masters Theses & Specialist Projects

The U.S. Army Corps of Engineers, Nashville District, maintains ten reservoirs in the Cumberland River Basin in Kentucky and Tennessee, and has been monitoring sediment chemistry in the reservoirs since 1994. The purpose of this study is to evaluate the sediment data collected from the reservoirs from 1994 to 2010 to determine if there are any spatial patterns of the trace elements: arsenic, beryllium, cadmium, chromium, copper, lead, mercury, nickel, and zinc. The results indicated that trace element levels were consistent with national baseline concentrations measured by the U.S. Geological Survey. Center Hill reservoir had the greatest number of trace …

Determining The Lon-Exchange Mechanism Of Strontium Into A Niobium Doped Titanosilicate, Samantha Jane Kramer

Masters Theses & Specialist Projects

A 25% niobium substituted sitinakite was exchanged with strontium as time resolved X-ray diffraction data was collected. The structural modeling of this data by Rietveld method1 has lead to the determination of the atomic positions of the ions and unit cell parameters as strontium occupancy increases.

The starting material of the exchange experiment is the protonated phase, H2Nb0.67Ti1.33SiO7·1.9 H2O, with space group P42/mcm2,3. Once strontium (Sr2+) enters the unit cell, extra-framework H2O molecules shift to provide the necessary hydration coordination. These new positions of H2O result in a lowering of symmetry to the P-42m space group, and it is thought …

National Park Service Cave And Karst Resources Management Case Study: Great Smoky Mountains National Park, Daniel C. Nolfi

Masters Theses & Specialist Projects

As discussed in the National Parks Service’s (NPS) Directors Orders/Natural Resources Management Reference Manual #77 and the 2006 NPS Management Policy Handbook, implementing a management plan specifically for cave and karst resources within a national park is paramount to afford these resources appropriate protection. With support from the Federal Cave Resources Protection Act and the National Park Service Organic Act of 1906, management actions protecting caves has begun to place significant importance outside the traditional cave environment onto a broader karst landscape. The need to understand and protect the karst environment and caves as a karst resource has taken a …

The Hydrology Of The Carroll Cave-Toronto Springs System: Identifying And Examining Source Mixing Through Dye Tracing, Geochemical Monitoring, Seepage Runs, And Statistical Methods, Benjamin Verlinden Miller

Masters Theses & Specialist Projects

In karst areas relationships between activities occurring on the surface and the overall health of the subsurface environment are often highly interconnected. However, the complex nature of karst flow systems can often make identification of these connections difficult. Carroll Cave, a large stream cave system located in the central Missouri Ozarks, is known for its biological and speleological significance. A dye tracing project to delineate a Carroll Cave recharge area through dye tracing has identified an area of 18.5 km2 which contributes water to the cave. The water from Thunder River within Carroll Cave was positively traced to eight springs …

Algal Biomass Accrual In Relation To Nutrient Availability Along A Longitudinal Gradient In The Upper Green River, Kentucky, Mary Douglas Penick

Masters Theses & Specialist Projects

Nutrient limitation in aquatic ecosystems results from a deficiency in nitrogen or phosphorus levels relative to cellular growth needs. Nutrient limitation of freshwater systems is a function of biotic and abiotic factors. Biotic factors include vascular and nonvascular plant community composition. Abiotic factors include underlying bedrock and land-use activities (e.g. agriculture, septic systems). Nutrient availability directly affects growth, productivity, and community structure of primary producers. The purpose of this study was two-fold: (1) to assess the relationship between ambient algal biomass. and in-stream nutrient levels along the longitudinal course of a river through a transition from weak to well-developed underlying …

Near-Surface Atmospheric Response To Simulated Changes In Land-Cover Vegetation Fraction, And Soil Moisture Over Western Kentucky, Ronnie Leeper

Masters Theses & Specialist Projects

A series of land-use-land-cover-change (LULCC) based sensitivity experiments, including changes in vegetation type, fractional vegetation (FV), and soil moisture (SM), over Western Kentucky were conducted to investigate atmospheric response to land-use. The choice of land-use for this study was chosen in the context of Western Kentucky’s historical LULCC. For this study, vegetation types considered were grassland, forest, and bare soil with further variations in FV for grassland and forest at 25, 50, 75, and 100 % and systematic increases and decreases in volumetric SM of 0.05, 0.10, and 0.15 m3 m-3. To the author’s knowledge, this is the first assessment …

The Study Of Variations In The Properties Of Biodiesel On Addition Of Antioxidants, Hiranmayee Kandala

Masters Theses & Specialist Projects

This research studies variations in biodiesel upon addition of different concentrations of antioxidant and petrodiesel additives. Oxidation onset temperature, oxidation induction time, oxidative stability, thermal stability, crystallization onset temperature and moisture retention properties of the biodiesel, with and without antioxidants have been studied. Antioxidants like BHT, BHA, PrG, Vit E and Vit C were added to the biodiesel during the study. These samples were analyzed using the PDSC, TGA, DSC and TGA-SA instrumentation.

The results of this research show an improvement in the OOT, OIT and Oxidative stability of biodiesel with the addition of antioxidants and by blending the biodiesel …

A Survey Of Drought Impacts And Mitigation Planning In Kentucky, Crystal Jane Bergman

Masters Theses & Specialist Projects

Drought is a well-known and costly climate-related natural hazard. Unlike other climate-related natural hazards, droughts are usually long in duration and may cover a large region, the physical boundaries of areas affected by drought are sometimes arbitrary, and the impacts are sometimes difficult to identify. Climate records since 1895 show that drought has occurred periodically in Kentucky. The drought of 2007 was the most recent drought to affect Kentucky and is the primary focus of this research. The purpose of this research is to identify impacts of drought and potential vulnerabilities to various drought impact sectors in Kentucky so that …

Sustainability With Globalization: An Unsustainable Proposition, Daniel B. Reader

Masters Theses & Specialist Projects

Globalization is recognized as a world-encompassing phenomenon, even as its benefits are debated. Sustainability, the capacity to maintain high standards of living through generations, is at stake. This paper examines the problems of sustainability with globalization from several perspectives. High statistical correlation between indices of globalization and environmental degradation (r2 = 0.977, p < .001) is found using multi-dimensional scaling software. The socially destabilizing, culture flattening effects of globalization are examined, and the terms ‘nationalism’ and ‘terrorism’ are defined. On the basis of its medial position among the indices of both globalization and environmental degradation, Chile is explored in a case study of the interaction. Conclusions regarding Chile’s vulnerabilities are reached, and the country’s environmental, social, and economic ‘weak spots’ are identified. The ethical positions of globalization and sustainability are considered, and the conclusion that there is very little that can be done to alter the nature of the interaction is drawn. It is suggested that globalization minimizes the prospects of success in efforts toward sustainability by maximizing vulnerabilities among sustainability’s components.

Factors Affecting Wood Fuel Consumption And Environmental Impacts In Warren County, Kentucky, Barry Vann

Masters Theses & Specialist Projects

The purpose of this research is to identify factors that contribute to wood fuel consumption as a space heating source and estimate a county-wide proportion for wood fuel consuming households. In addition, environmental problems associated with deforestation such as erosion and loss of wildlife habitat are delineated; moreover, air pollution resulting from wood fuel emissions are discussed.

An exhaustive literature review provided the basis for the study. Data on Warren County wood fuel consumption patterns were derived from a mail survey. Proportion estimates were tested by using a classical two-tail test of hypothesis. Subsequently, factors were identified and used in …

A “Drastic” Evaluation Of The Ground-Water Pollution Potential Of Karst Terrain: Lost River Ground-Water Basin, Warren County, Kentucky, David Baize

Masters Theses & Specialist Projects

Karst terrains, such as the Lost River Karst Ground-Water Basin, are extremely vulnerable to ground-water contamination. Seven physical factors: depth to water, recharge, aquifer media, soil media, topography, impact of the vadose zone, and hydraulic conductivity, are evaluated using the DRASTIC system to determine the ground-water pollution potential of the study area. A numerical value is calculated for each of the seven factors, and a map layer for each factor is produced. These layers are then “added” together to produce a DRASTIC ground-water pollution potential map. The effectiveness of each factor in evaluating the pollution potential of karst terrain is …