Physical Sciences and Mathematics Commons^™

Examining The Corn Seedling Emergence–Temperature Relationship For Recent Hybrids: Insights From Experimental Studies, Sahila Beegum, Charles Hunt Walne, Krishna N. Reddy, Vangimalla Reddy, Kambham Raja Reddy

Nebraska Water Center: Faculty Publications

Corn seedling emergence is a critical factor affecting crop yields. Accurately predicting emergence is crucial for precise crop growth and development simulation in process-based crop models. While various experimental studies have investigated the relationship between corn seedling emergence and temperature, there remains a scarcity of studies focused on newer corn hybrids. In the present study, statistical models (linear and quadratic functional relationships) are developed based on the seedling emergence of ten current corn hybrids, considering soil and air temperatures as influencing factors. The data used for model development are obtained from controlled soil plant atmospheric research chamber experiments focused on …

Analysis Of Wastewater Samples To Explore Community Substance Use In The United States: Pilot Correlative And Machine Learning Study, Marie A. Severson, Sathaporn Onanong, Alexandra Dolezal, Shannon L. Bartelt-Hunt, Daniel D. Snow, Lisa M. Mcfadden

Nebraska Water Center: Faculty Publications

Background: Substance use disorder and associated deaths have increased in the United States, but methods for detecting and monitoring substance use using rapid and unbiased techniques are lacking. Wastewater-based surveillance is a cost-effective method for monitoring community drug use. However, the examination of the results often focuses on descriptive analysis.

Objective: The objective of this study was to explore community substance use in the United States by analyzing wastewater samples. Geographic differences and commonalities of substance use were explored.

Methods: Wastewater was sampled across the United States (n=12). Selected drugs with misuse potential, prescriptions, and over-the-counter drugs …

Characterization Of Environmental Levels Of Pesticide Residues In Household Air And Dust Samples Near A Bioenergy Plant Using Treated Seed As Feedstock, Jabeen Taiba, Eleanor G. Rogan, Daniel D. Snow, Chandran Achutan, Muhammad Zahid

Nebraska Water Center: Faculty Publications

Exposure to neonicotinoid insecticides is associated with adverse human health outcomes. There is environmental contamination in Saunders County, Nebraska, due to the accumulation of fungicides and insecticides from a now-closed ethanol plant using seed corn as stock. A pilot study quantified environmental contamination in nearby houses from residual pesticides by measuring dust and air (indoor/outdoor) concentrations of neonicotinoids and fungicides at the study site (households within two miles of the plant) and control towns (20–30 miles away). Air (SASS^® 2300 Wetted-Wall Air Sampler) and surface dust (GHOST wipes with 4 × 4-inch template) samples were collected from eleven study …

Leaching Performance Of Nanotechnology-Induced High-Arsenic-Bearing Tooeleite-Like Mineral Nanowaste, Arindam Malakar, Sanjit Das, Samirul Islam, Rajneesh Singh, Sugata Ray

Nebraska Water Center: Faculty Publications

For arsenic decontamination from groundwater, arsenic crystallization is becoming adopted due to its sustainability and economic benefits. However, arsenic crystallization technology is a two-step process, which makes it complex and generates hazardous waste. Successful efforts toward making it a single-step process are presented here. The addition of nanorods and ball-milled zinc sulfide nanoparticles to arsenic-contaminated water result in highly monodispersed and higharsenic- containing mineralized nanowaste with a crystalline structure similar to the mineral Tooeleite ((Fe³⁺₆(As³⁺O₃)₄SO₄(OH)₄•4H₂O)). This study reports the results of a short-term stability test …

Reaction Steps In Heterogeneous Photocatalytic Oxidation Of Toluene In Gas Phase—A Review, Yerzhigit Tulebekov, Zhandos Orazov, Bagdat Satybaldiyev, Daniel D. Snow, Raphaël Schneider, Bolat Uralbekov

Nebraska Water Center: Faculty Publications

A review of the current literature shows there is no clear consensus regarding the reaction mechanisms of air-borne aromatic compounds such as toluene by photocatalytic oxidation. Potential oxidation reactions over TiO₂ or TiO₂-based catalysts under ultraviolet and visible (UV/VIS) illumination are most commonly considered for removal of these pollutants. Along the pathways from a model pollutant, toluene, to final mineralization products (CO₂ and H₂O), the formation of several intermediates via specific reactions include parallel oxidation reactions and formation of less-reactive intermediates on the TiO₂ surface. The latter may occupy active adsorption sites and …

Adsorptive–Photocatalytic Performance For Antibiotic And Personal Care Product Using Cu0.5Mn0.5Fe2O4, Chanat Chokejaroenrat, Chainarong Sakulthaew, Athaphon Angkaew, Apiladda Pattanateeradetch, Wuttinun Raksajit, Kanokwan Teingtham, Piyaporn Phansak, Pawee Klongvessa, Daniel D. Snow, Clifford E. Harris, Steven Comfort

Nebraska Water Center: Faculty Publications

The amount of antibiotics and personal care products entering local sewage systems and ultimately natural waters is increasing and raising concerns about long-term human health effects. We developed an adsorptive photocatalyst, Cu_0.5Mn_0.5Fe₂O₄ nanoparticles, utilizing co-precipitation and calcination with melamine, and quantified its efficacy in removing paraben and oxytetracycline (OTC). During melamine calcination, Cu_0.5Mn_0.5Fe₂O₄ recrystallized, improving material crystallinity and purity for the adsorptive–photocatalytic reaction. Kinetic experiments showed that all four parabens and OTC were removed within 120 and 45 min. We found that contaminant adsorption and reaction …

Incorporation Of Carbon Dioxide Production And Transport Module Into A Soil-Plant-Atmosphere Continuum Model, Sahila Beegum, Wenguang Sun, Dennis Timlin, Zhuangji Wang, David Fleisher, Vangimalla R. Reddy, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

Carbon dioxide release from agricultural soils is influenced by multiple factors, including soil (soil properties, soil-microbial respiration, water content, temperature, soil diffusivity), plant (carbon assimilation, rhizosphere respiration), atmosphere (climate, atmospheric carbon dioxide), etc. Accurate estimation of the carbon dioxide (CO₂) fluxes in the soil and soil respiration (CO₂ flux between soil and atmosphere) requires a process-based modeling approach that accounts for the influence of all these factors. In this study, a module for CO₂ production via root and microbial respiration and diffusion-based carbon dioxide transport is developed and integrated with MAIZSIM (a process-based maize crop growth …

Improving The Cotton Simulation Model, Gossym, For Soil, Photosynthesis, And Transpiration Processes, Sahila Beegum, Dennis Timlin, Kambham Raja Reddy, Vangimalla Reddy, Wenguang Sun, Zhuangji Wang, David Fleisher, Chittaranjan Ray

Nebraska Water Center: Faculty Publications

GOSSYM, a mechanistic, process-level cotton crop simulation model, has a two-dimensional (2D) gridded soil model called Rhizos that simulates the below-ground processes daily. Water movement is based on gradients of water content and not hydraulic heads. In GOSSYM, photosynthesis is calculated using a daily empirical light response function that requires calibration for response to elevated carbon dioxide ( CO₂). This report discusses improvements made to the GOSSYM model for soil, photosynthesis, and transpiration processes. GOSSYM’s predictions of below-ground processes using Rhizos are improved by replacing it with 2DSOIL, a mechanistic 2D finite element soil process model. The photosynthesis …

Occurrence Of Radionuclides And Hazardous Elements In The Transboundary River Basin Kyrgyzstan–Kazakhstan, Mariya A. Severinenko, Vladimir P. Solodukhin, Bekmamat M. Djenbaev, The National Academy Of Science Of The Kyrgyz Republic G. Lennik, Baktiyar T. Zholboldiev, Daniel D. Snow

Nebraska Water Center: Faculty Publications

Important for irrigation, the transboundary river basin between Kyrgyzstan and Kazakhstan is vulnerable to geochemical and anthropogenic sources of pollution. The use of water use indices, together with measurements of the elemental and radionuclide composition of the water and bottom sediments, provides a means for evaluating the continued use of the water from this region. Recent monitoring shows the highest concentrations of hazardous contaminants include lead and thorium contained in the bottom and banks of the Kichi-Kemin River. These contaminants are likely remnants of an accidental spill at the Aktyuz tailing dump in 1964. The specific activity of the Th-232 …

Projected Long-Term Climate Trends Reveal The Critical Role Of Vapor Pressure Deficit For Soybean Yields In The Us Midwest, Wenguang Sun, David Fleisher, Dennis Timlin, Chittaranjan Ray, Zhuangji Wang, Sahila Beegum, Vangimalla Reddy

Nebraska Water Center: Faculty Publications

Extreme climate events including heat waves and droughts are projected to become more frequent under future climate change conditions. However, the mechanisms between soybean yields and climate factors, specifically involving variable rainfall and high heat episodes, are still unclear, particularly with respect to spatial trends in the United States (US) Midwest. A recently modified version of the model GLYCIM was used to evaluate rainfed soybean production across 12 states at a 10 km spatial resolution for three time periods (2011–2020, 2051–2060, 2091–2099) under Representative Concentration Pathway (RCP) scenarios 4.5 and 8.5. Results showed that except for the northernmost Midwest counties, …

Importance Of Snowmelt On Soil Nitrate Leaching To Groundwater – A Model Study, Sahila Beegum, Arindam Malakar, Chittaranjan Ray, Daniel D. Snow

Nebraska Water Center: Faculty Publications

The movement of nitrate to surface water bodies during snow accumulation and melting has been extensively studied, but there are only limited studies on the influence of snow processes on nitrate leaching to groundwater. The present study investigated the impact of snow processes on nitrate leaching to groundwater based on a simulation modeling approach using HYDRUS-1D. HYDRUS-1D model has a temperature threshold-based snow model in addition to water, solute, and heat simulation components. The snow component in HYDRUS-1D was previously not applied to snow simulation studies since the method does not consider a detailed physical and process-based representation of snow …

Time Domain Reflectometry Waveform Interpretation With Convolutional Neural Networks, Zhuangji Wang, Shan Hua, Dennis Timlin, Yuki Kojima, Songtao Lu, Wenguang Sun, David Fleisher, Robert Horton, Vangimalla R. Reddy, Katherine Tully

Nebraska Water Center: Faculty Publications

Interpreting time domain reflectometry (TDR) waveforms obtained in soils with non-uniform water content is an open question. We design a new TDR waveform interpretation model based on convolutional neural networks (CNNs) that can reveal the spatial variations of soil relative permittivity and water content along a TDR sensor. The proposed model, namely TDR-CNN, is constructed with three modules. First, the geometrical features of the TDR waveforms are extracted with a simplified version of VGG16 network. Second, the reflection positions in a TDR waveform are traced using a 1D version of the region proposal network. Finally, the soil relative permittivity values …