Physical Sciences and Mathematics Commons^™

The Study Of Corrosion On Additive-Manufactured Metals., Braydan Daniels

Electronic Theses and Dissertations

The purpose of this study was to investigate and compare the corrosion mechanisms between wrought and additive-manufactured (3D-printed) copper and stainless steel. The experimental procedure consisted of measuring the open circuit potential, electrochemical impedance spectroscopy, linear sweep voltammetry, Tafel analysis, surface topology, and scanning electron microscopy for each metal within salt water, tap water, sulfuric acid, and synthetic body fluid (excluding copper in synthetic body fluid).

Overall, printed stainless steel was more corrosion-resistant than wrought stainless steel in tap water and synthetic body fluid based on OCP, LSV, and surface topology results. Additionally, printed copper was more corrosion-resistant than wrought …

Use Of Electrochemical Techniques And Statistical Analysis To Investigate The Pitting Probability Of Copper, Sina Matin

Electronic Thesis and Dissertation Repository

The development of a safe permanent disposal plan is essential for the long-term disposal of used fuel bundles. Nuclear Waste Management Organization (NWMO) has been investigating the deep geologic disposal of nuclear waste which offers the optimum passive safety system with a negligible probability of release of radionuclides into the environment.

The proposed used fuel containers (UFC) for the permanent disposal of high-level nuclear waste in Canada is comprised of a carbon steel vessel coated with a 3 mm corrosion-resistant copper layer deposited using a combination of electrodeposition and cold spray deposition. Although copper is often considered to be thermodynamically …

Development And Implementation Of A Pressure-Temperature Control System For The Physical Vapor Deposition Of Copper And Niobium From A Molybdenum Filament In The Development Of Superconducting 3d Printed Rf Cavity Particle Accelerators, Chandler J. Fleuette

Honors Theses and Capstones

This report covers the development of the pressure-temperature control system used in the production of small superconducting RF cavities for particle accelerators. To test the validity of the created program, a model for the process was created and tested. The model was used to fine tune the control system before integrating it into the lab. The end goal of the control system is to measure the pressure inside of a deposition vacuum chamber, convert that pressure to a temperature, and use that temperature in tandem with a PID controller to control the current passing though a molybdenum filament which is …

Copper And Gold In Vapors And Liquids As A Function Of Hcl At 700°C And 100 Mpa, Corrie A. Lucchesi

Graduate Research Theses & Dissertations

Porphyry ore deposits are major sources of copper (Cu) and gold (Au) and form when a magmatic volatile phase (MVP) exsolves from a porphyritic intermediate to felsic melt and transports metals to surrounding country rock where they precipitate in an ore zone. There is a consensus that the chloride concentration of the MVP has a direct relationship to the concentration of Cu and Au in the MVP, but the role of dissolved HCl on Cu and Au concentrations has not been addressed. It is hypothesized that increasing HCl concentrations in the MVP will result in higher concentrations of Cu and …

Geophysical Characteristics Of Nickel And Copper Deposits In Wadi Al Khadra Prospect, Southwestern Of Saudi Arabia, Abdulrahman Ahmed Aljabbab

Doctoral Dissertations

“Three geophysical datasets (self-potential, magnetics, and time - domain electromagnetics) were acquired at Wadi Al Khadra Ni-Cu prospect in southwest Saudi Arabia, and were processed and interpreted for the Saudi Geological Survey. The primary objectives were to map the distribution of metallic mineralization, map structures, verify the integration of the geophysical interpretations and its signatures in conjunction with boreholes information, distinguish the similarities and differences in the integrated interpretation of geophysical data, and design optimal processing and interpretation data parameters. The self-potential tool was used to map the variation in natural surface potential differences to map lateral variations in the …

Electrodeposited Epitaxial Cobalt Oxides And Copper Metal, Caleb M. Hull

Doctoral Dissertations

"Electrochemical deposition methods are presented for the deposition of Co(OH)₂ and Cu metal. Paper I shows the deposition of β-Co(OH)₂ on Ti through electrochemical reduction of [Co(en)₃]³⁺ to [Co(en)₃]²⁺ in 2M NaOH. The catalytic properties of the deposited Co(OH)₂ towards water oxidation is found comparable to Co₃O₄, with the surface of the Co(OH)₂ converting to CoOOH during the reaction. Paper II gives the conditions suitable for epitaxial growth of Co(OH)₂ on Au(100), Au(110), and Au(111) following the same reduction mechanism as described in Paper I. …

Homo- And Heterometallic Bis(Pentafluorobenzoyl)Methanide Complexes Of Copper(Ii) And Cobalt(Ii), Janell Crowder

Legacy Theses & Dissertations (2009 - 2024)

β-Diketones are well known to form metal complexes with practically every known metal and metalloid. Metal complexes of fluorinated β-diketones generally exhibit increased volatility and thermal stability compared to the non-fluorinated analogues, and thus are used extensively in various chemical vapor deposition (CVD) processes for the deposition of metal, simple or mixed metal oxides, and fluorine-doped metal oxide thin films. Furthermore, the electron-withdrawing nature of the fluorinated ligand enhances the Lewis acidity of a coordinatively unsaturated metal center which facilitates additional coordination reactions. The physical and structural properties of fluorinated β-diketonate complexes are discussed in Chapter 1 …

Doped Tio2 Nanowires For Applications In Dye Sensitized Solar Cells And Sacrifical Hydrogen Production, Qasem Alsharari

Electronic Thesis and Dissertation Repository

This thesis explores the synthesis of metal oxide 1-D nanowires using a sol-gel method in supercritical carbon dioxide (sc-CO₂), as an environmental friendly enabling solvent. Porous nanowires were synthesized and their performance was tested in dye sensitized solar cell and sacrifical hydrogen production. Titanium isopropoxide (TIP) was used as a precursor for titania synthesis while copper, bismuth and indium were examined as dopants, respectively. The sol-gel reactions were catalyzed by acetic acid in CO₂ at a temperature of 60 °C and pressure of 5000 psi. It was observed that acetic acid/monomer ratio > 4 produced nanowires while a …

Novel Approaches For Assessment Of Copper Toxicity: Fast Scan Cyclic Voltammetry And Optical Bioassays, Annette R. Tremonti

Wayne State University Dissertations

Anthropogenic activities negatively impact fresh water ecosystems through toxic contaminants that are released into the environment. Copper (Cu) is a water contaminant that is fundamentally persistent once introduced into the environment that has the potential for bioaccumulation. Although Cu toxicity has been studied for decades, there is still a continuing problem with new sources and pathways. New approaches are needed to understand distribution and transport of Cu and its potential for complex biological impacts beyond the simple assessment of lethality. Several novel approaches were used in this research project to advance our understanding of Cu toxicity, including fast scan cyclic …

Functional Characterization Of Green Sorption Media And Scaling Of Pilot Studies For Copper Removal In Stormwater Runoff, Cameron Houmann

Electronic Theses and Dissertations

Green adsorption media with the inclusion of renewable and recycled materials can be applied as a stormwater best management practice for copper removal. A green adsorption media mixture composed of recycled tire chunk, expanded clay aggregate, and coconut coir was physicochemically evaluated for its potential use in an upflow media filter. The results found that the use of the green adsorption media mixture in isolation or the coconut coir with an expanded clay filtration chamber could be an effective and reliable stormwater best management practice for copper removal. A suite of tests were conducted on the media mixture and the …

Synthesis Of Platinum And Platinum-Copper Branched Nanoparticles For Electrooxidation Of Methanol, Eric Courtland Taylor

Graduate Theses and Dissertations

Platinum and Pt alloys are among the most important heterogeneous catalysts for many organic reactions and electrochemical reactions associated with the fuel cell technologies. How to reduce Pt usage while maintaining the performance of the catalysts becomes a subject for intensive research in materials chemistry. For heterogeneous catalysis, the catalytic reactivity and selectivity are strongly correlated with different crystallographic facets exposed on the surface. The facets with high-index planes whose Miller indices with at one is larger than unity are generally more active than those with low-index planes (e.g., {100}, {111}, and {110}). Tuning the morphology of the nanoparticles to …

Multiscale Modeling Of Enzyme-Catalyzed Methanol Production By Particulate Methane Monooxygenase, Katherine K. Bearden

Doctoral Dissertations

In this work, the conversion of methane to methanol by the particulate Methane Monooxygenase (pMMO) enzyme is investigated using a multi-scale modeling approach. This enzyme participates in carbon cycling and aids in the removal of harmful atmospheric methane, converting it to methanol. The interaction between pMMO and a neighboring enzyme that is present in the same organism is studied, and the unknown pMMO active site is elucidated and tested for methane oxidation towards the production of methanol.

Fundamental knowledge of pMMO's mechanism is not fully understood. Understanding how this enzyme works in nature will provide information towards designing efficient synthetic …

Ruco To Extend The Scalability Of Ultra-Thin Direct Plate Liners, Daniel Verne Greenslit

Legacy Theses & Dissertations (2009 - 2024)

In traditional semiconductor technology a sputtered copper seed layer is used to improve the adhesion, microstucture, and electromigration characteristics of electrochemically deposited (ECD) copper. The seed layer is deposited on top of a Ta/TaN stack. The Ta layer acts as an adhesion and nucleation layer for the copper seed and the TaN serves as a diffusion barrier for the Cu. As the line widths continue to shrink, scaling each of these layers becomes more difficult. It would be advantageous for the interconnect to be composed of as much copper as possible, transitioning from the traditional liner seed stack to a …

The Influence Of Copper Substrate Orientation On Graphene Growth, Zachary Robert Robinson

Legacy Theses & Dissertations (2009 - 2024)

This dissertation is focused on determining the influence of the copper substrate on graphene grown by \ac{CVD}. Graphene, which can be grown in single atomic layers on copper substrates, has potential applications in future electronic devices. One of the key issues for the use of graphene grown by chemical vapor deposition for device applications is the influence of defects on the transport properties of the graphene. For instance, growth on metal foil substrates results in multi-domain graphene growth because the foil substrates themselves have a variety of different surface terminations. Therefore, they don't serve as a very good template for …

Nucleation, Wetting And Agglomeration Of Copper And Copper-Alloy Thin Films On Metal Liner Surfaces, Stephanie Florence Labarbera

Legacy Theses & Dissertations (2009 - 2024)

One of the key challenges in fabricating narrower and higher aspect ratio interconnects using damascene technology has been achieving an ultra-thin (~2 nm) and continuous Cu seed coverage on trench sidewalls. The thin seed is prone to agglomeration because of poor Cu wetting on the Ta liner. Using in-situ conductance measurements, the effect of lowering the substrate temperature during Cu seed deposition has been studied on tantalum (Ta) and ruthenium (Ru) liner surfaces. On a Ta surface, it was found that lowering the deposition temperature to -65°C increases the nucleation rate of the Cu thin film, and reduces the minimum …

Compensation And Characterization Of Gallium Arsenide, Randy A. Roush

Electrical & Computer Engineering Theses & Dissertations

The properties of transition metals in gallium arsenide have been previously investigated extensively with respect to activation energies, but little effort has been made to correlate processing parameters with electronic characteristics. Diffusion of copper in gallium arsenide is of technological importance due to the development of GaAs:Cu bistable photoconductive devices. Several techniques are demonstrated in this work to develop and characterize compensated gallium arsenide wafers. The material is created by the thermal diffusion of copper into silicon-doped GaAs. Transition metals generally form deep and shallow acceptors in GaAs, and therefore compensation is possible by material processing such that the shallow …

Oxidized Copper Mineralization Along The Continental Fault Near Butte, Montana, Theodore H. Eyde

Bachelors Theses and Reports, 1928 - 1970

Located in the fault zone of the Continental fault near the western edge of Boulder batholith of southwestern Montana the oxidized copper deposits are developed by three open pit mines, one of which is a presently in operation. Copper has been deposited by descending cold solutions which have leached copper from the surrounding quartz monzonite and deposited within the crushed fault zone. Local high grade 'bunches' of ore occur along narrow limonite veins, remnants of primary sulfide veins which have been enriched by the descending cold solutions.

Effect Of Recovery On The Recrystallized Grain-Size Of High Purity Aluminum, Rodney L. Helterline

Bachelors Theses and Reports, 1928 - 1970

When a cold-worked metal is annealed, it’s physical properties hange as a result of a new grain structure. The annealing treatment is divided into three stages according to the changes that occur in the distorted metal: (1) recovery, (2) recrystallization, and (3) grain growth.

The Application Of Electric Energy To The Metallurgy Plants In Montana, Edwin J. Duncan

Bachelors Theses and Reports, 1928 - 1970

Since the year 1800, metallurgy has been affiliated with electricity. In fact, the two industries have grown side by side, being naturally dependent upon each other and having a parallel growth.

The Construction And Operation Of A Universal Specimen Mount With Protective Lead Shield For The Purpose Of Determining Pole Figures Using The Schulz-Decker Transmission Technique, Richard L. Fausner

Bachelors Theses and Reports, 1928 - 1970

It was the purpose of this study to construct a universal mount, to construct a protective lead shield, to operate the instrument, and to provide a pole figure using the transmission method of Schulz and Decker. There are at present several lengthy x-ray methods of determining the grain orientation of metals. These methods are mainly photographic. In order to provide a rapid means of obtaining the necessary information concerning the grain orientation of a metal, a universal mount was constructed.

Host Rocks And Gangue Minerals Associated With Copper Deposits In Plutonic Igneous Rocks, Richard D. Montgomery

Bachelors Theses and Reports, 1928 - 1970

All of the information on the various districts has come directly from published reports. The investigation was suggested by Mr. Forbes Robertson. The geographical extent of the deposits was confined to the western United States. Many of these deposits are of the disseminated porphyry type. A few of the de­posits, such as at Butte, Montana, were of the fissure vein type.

The Effect Of Manganese On The Age Hardening Of Aluminum-Copper Alloys, Keith P. Burgess

Bachelors Theses and Reports, 1928 - 1970

It is known that age-hardening occurs in alloys of the solid solution type containing a hardening constituent, of a metal or metallic compound which is more soluble in the solvent phase at higher tempertures than at lower temperatures.

The Benefication Of A Low-Grade, Montana Scheelite Ore, Walter G. Parker

Bachelors Theses and Reports, 1928 - 1970

The increasing importance of tungsten as an industrial metal and the recent discoveries of extensive deposits of low-grade tungsten ores in Montana led to the investigation which is reported in this paper. The purpose of this investigation was to determine if a saleable concentrate could be obtained from one of these low-grade, Montana scheelite ores.

The Effect Of Ferric Iron Upon The Current Efficiency And The Deposition Of Copper In The Electrowinning Of Copper From Copper Sulphate Solutions, James L. Owings

Bachelors Theses and Reports, 1928 - 1970

In the hydrometallurgy of copper, probably the most widely used method for the precipitation of copper is by electrolysis using insoluble anodes. The process is similar in many respects to the electrolytic refining of copper; one of the main differences is the use of insoluble anodes in electrowinning as compared to the use of impure copper anodes in electrorefining. Impurities, however, are common to both processes. The nature of these impurities differ and the problem of purifying the electrolyte is also different.

Variation Of Induction And Hysteresis Curves For The Heusler Alloy, Cu2mna1, Ford W. Knight

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine the fundamental magnetic characteristics of induction and hysteresis, for the alloy Cu₂MnAl. This is a ternary, ferromagnetic Heusler alloy. The problem is not only to determine these characteristics for the alloy as-cast but to heat treat it and observe the manner in which different heat treat­ments affect these two fundamental magnetic characteristics.

An Investigation Of The Hardening Properties Of Some Alpha Copper Indium Alloys, Charles W. Mcpherson

Bachelors Theses and Reports, 1928 - 1970

Precipitation hardening alloys has assumed a major role in modern da^y development of alloys. In his search for stronger, harder materials, the metallurgist has often been limited by the cost of metals which posses the needed properties.

The Effect Of Iron Upon The Electrowinning Of Copper With An Amalgam Electrode, John A. Alexander

Bachelors Theses and Reports, 1928 - 1970

Current commercial use of the mercury cathode cell is limited to two types of electrolytic sodium cells-­the Castner cell and the Sorenson cell. Mercury as a cathode medium has also found application in polarographic analysis, a method of a simultaneous quantitative and qualitative analysis of several metal components of solution.

Polarographic Analysis Applied To Metallurgical Solutions And Products, Donald W. Johnson

Bachelors Theses and Reports, 1928 - 1970

The polarograph has been applied to a large number of chemical and metallurgical analyses, and is especially applicable to solution control analysis and to the deter­mination of minute quantities of ions in the presence of large amounts of other ions.

Vacuum Distillation Of Zinc And Cadmium From Zinc Leach Purification Cake, Stiles R. Slosson

Bachelors Theses and Reports, 1928 - 1970

The term "vacuum distillation" is used to des­cribe the process employed when certain elements are separated either from their mother compounds or from one another by distilling them under reduced atmos­pheric pressure.

Ferromagnetic Alloys In The System Cu-Mn-Zn, W. Michael Yim

Bachelors Theses and Reports, 1928 - 1970

The purpose of this investigation is to determine whether ferromagnetic alloys exist in the ternary sys­tem Cu-Mn-Zn analogous to the other Heusler alloys. The work in this thesis is a preliminary investi­gation on these alloys using a common metallographic re­search technique and augmented with X-ray methods.