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Full-Text Articles in Physical Sciences and Mathematics
Development And Implementation Of A Pressure-Temperature Control System For The Physical Vapor Deposition Of Copper And Niobium From A Molybdenum Filament In The Development Of Superconducting 3d Printed Rf Cavity Particle Accelerators, Chandler J. Fleuette
Student Research Projects
This report covers the development of the pressure-temperature control system used in the production of small superconducting RF cavities for particle accelerators. To test the validity of the created program, a model for the process was created and tested. The model was used to fine tune the control system before integrating it into the lab. The end goal of the control system is to measure the pressure inside of a deposition vacuum chamber, convert that pressure to a temperature, and use that temperature in tandem with a PID controller to control the current passing though a molybdenum filament which is …
Continuous Catalytic Deoxygenation Of Waste Free Fatty Acid-Based Feeds To Fuel-Like Hydrocarbons Over A Supported Ni-Cu Catalyst, Ryan Loe, Yasmeen Lavoignat, Miranda Maier, Mohanad Abdallah, Tonya Morgan, Dali Qian, Robert Pace, Eduardo Santillan-Jimenez, Mark Crocker
Continuous Catalytic Deoxygenation Of Waste Free Fatty Acid-Based Feeds To Fuel-Like Hydrocarbons Over A Supported Ni-Cu Catalyst, Ryan Loe, Yasmeen Lavoignat, Miranda Maier, Mohanad Abdallah, Tonya Morgan, Dali Qian, Robert Pace, Eduardo Santillan-Jimenez, Mark Crocker
Center for Applied Energy Research Faculty and Staff Publications
While commercial hydrodeoxygenation (HDO) processes convert fats, oils, and grease (FOG) to fuel-like hydrocarbons, alternative processes based on decarboxylation/decarbonylation (deCOx) continue to attract interest. In this contribution, the activity of 20% Ni-5% Cu/Al2O3 in the deCOx of waste free fatty acid (FFA)-based feeds—including brown grease (BG) and an FFA feed obtained by steam stripping a biodiesel feedstock—was investigated, along with the structure-activity relationships responsible for Ni promotion by Cu and the structural evolution of catalysts during use and regeneration. In eight-hour experiments, near quantitative conversion of the aforementioned feeds to diesel-like hydrocarbons was achieved. …
Collaborative Research: A Nanostructure Sensor For Measuring Dissolved Iron And Copper Concentrations In Coastal And Offshore Seawater, Mark Wells, Carl Tripp
Collaborative Research: A Nanostructure Sensor For Measuring Dissolved Iron And Copper Concentrations In Coastal And Offshore Seawater, Mark Wells, Carl Tripp
University of Maine Office of Research Administration: Grant Reports
Iron and Copper serve as key co-constituents for numerous enzymes in a wide range of biological systems, and their elevated or impoverished levels in aqueous systems have dramatic consequences at organismal, ecosystem, and human health scales. Over the last decade these effects have increasingly been recognized to be important in ocean systems. Identifying sites and times where these metals cause negative environmental outcomes is greatly hampered by their comparatively sparse datasets. This problem is a direct consequence of the analytical challenge of obtaining accurate Fe and Cu determinations in saline waters at very low (trace) concentrations, and the limitations of …
Properties Of Cu(In,Ga,Al)Se² Thin Films Fabricated By Magnetron Sputtering, Talaat A. Hameed, Wei Cao, Bahiga A. Mansour, Inas K. Elzawaway, El-Metwally M. Abdelrazek, Hani E. Elsayed-Ali
Properties Of Cu(In,Ga,Al)Se² Thin Films Fabricated By Magnetron Sputtering, Talaat A. Hameed, Wei Cao, Bahiga A. Mansour, Inas K. Elzawaway, El-Metwally M. Abdelrazek, Hani E. Elsayed-Ali
Applied Research Center Publications
Cu (In,Ga,Al)Se2 (CIGAS) thin films were studied as an alternative absorber layer material to Cu(InxGa1-x)Se2. CIGAS thin films with varying Al content were prepared by magnetron sputtering on Si(100) and soda-lime glass substrates at 350 °C, followed by postdeposition annealing at 520 °C for 5 h in vacuum. The film composition was measured by an electron probe microanalyzer while the elemental depth profiles were determined by secondary ion mass spectrometry. X-ray diffraction studies indicated that CIGAS films are single phase with chalcopyrite structure and that the (112) peak clearly shifts to higher 2θ …
Synthesis Of Large And Few Atomic Layers Of Hexagonal Boron Nitride On Melted Copper, Majharu Haque Khan, Zhenguo Huang, Feng Xiao, Gilberto Casillas, Zhixin Chen, Paul Molino, Hua-Kun Liu
Synthesis Of Large And Few Atomic Layers Of Hexagonal Boron Nitride On Melted Copper, Majharu Haque Khan, Zhenguo Huang, Feng Xiao, Gilberto Casillas, Zhixin Chen, Paul Molino, Hua-Kun Liu
Australian Institute for Innovative Materials - Papers
Hexagonal boron nitride nanosheets (h-BNNS) have been proposed as an ideal substrate for graphene-based electronic devices, but the synthesis of large and homogeneous h-BNNS is still challenging. In this contribution, we report a facile synthesis of few-layer h-BNNS on melted copper via an atmospheric pressure chemical vapor deposition process. Comparative studies confirm the advantage of using melted copper over solid copper as a catalyst substrate. The former leads to the formation of single crystalline h-BNNS that is several microns in size and mostly in mono- and bi-layer forms, in contrast to the polycrystalline and mixed multiple layers (1-10) yielded by …
Aqueous Preparation Of Surfactant-Free Copper Selenide Nanowires, Xinqi Chen, Zhen Li, Jianping Yang, Qiao Sun, S X. Dou
Aqueous Preparation Of Surfactant-Free Copper Selenide Nanowires, Xinqi Chen, Zhen Li, Jianping Yang, Qiao Sun, S X. Dou
Australian Institute for Innovative Materials - Papers
Uniform surfactant-free copper selenide (Cu2- x Se) nanowires were prepared via an aqueous route. The effects of reaction parameters such as Cu/Se precursor ratio, Se/NaOH ratio, and reaction time on the formation of nanowires were comprehensively investigated. The results show that Cu2- x Se nanowires were formed through the assembling of CuSe nanoplates, accompanied by their self-redox reactions. The resultant Cu2- x Se nanowires were explored as a potential thermoelectric candidate in comparison with commercial copper selenide powder. Both synthetic and commercial samples have a similar performance and their figures of merit are 0.29 and 0.38 at …
Ambient Facile Synthesis Of Gram-Scale Copper Selenide Nanostructures From Commercial Copper And Selenium Powder, Xinqi Chen, Zhen Li, S X. Dou
Ambient Facile Synthesis Of Gram-Scale Copper Selenide Nanostructures From Commercial Copper And Selenium Powder, Xinqi Chen, Zhen Li, S X. Dou
Australian Institute for Innovative Materials - Papers
Grams of copper selenides (Cu2-xSe) were prepared from commercial copper and selenium powders in the presence of thiol ligands by a one-pot reaction at room temperature. The resultant copper selenides are a mixture of nanoparticles and their assembled nanosheets, and the thickness of nanosheets assembled is strongly dependent on the ratio of thiol ligand to selenium powder. The resultant Cu2-xSe (0 ≤ x ≤ 0.25) nanostructures were treated with hydrazine solution to remove the surface ligands and then explored as a potential thermoelectric candidate in comparison with commercial copper selenide powders. The research provides a novel …
A Novel Route To Copper(Ii) Detection Using 'Click' Chemistry-Induced Aggregation Of Gold Nanoparticles, Carol Hua, William H. Zhang, Swahnnya De Almeida, Simone Ciampi, Danmar Gloria, Guozhen Liu, Jason Brian Harper, J Justin Gooding
A Novel Route To Copper(Ii) Detection Using 'Click' Chemistry-Induced Aggregation Of Gold Nanoparticles, Carol Hua, William H. Zhang, Swahnnya De Almeida, Simone Ciampi, Danmar Gloria, Guozhen Liu, Jason Brian Harper, J Justin Gooding
Australian Institute for Innovative Materials - Papers
A simple colorimetric method for the detection of copper ions in water is described. This method is based on the 'click' copper(i)-catalyzed azide-alkyne cycloaddition reaction and its use in promoting the aggregation of azide-tagged gold nanoparticles by a dialkyne cross-linker is described. Nanoparticle cross-linking, evidenced as a colour change, is used for the detection of copper ions. The lowest detected concentration by the naked eye was 1.8 μM, with the response linear with log(concentration) between 1.8-200 μM. The selectivity relative to other potentially interfering ions was evaluated.
Electronic And Structural Properties Of Molybdenum Thin Films As Determined By Real Time Spectroscopic Ellipsometry, J. D. Walker, H. Khatri, V. Ranjan, Jian Li, R. W. Collins, S. Marsillac
Electronic And Structural Properties Of Molybdenum Thin Films As Determined By Real Time Spectroscopic Ellipsometry, J. D. Walker, H. Khatri, V. Ranjan, Jian Li, R. W. Collins, S. Marsillac
Electrical & Computer Engineering Faculty Publications
Walker, J.D., Khatri, H., Ranjan, V., Li, J., Collins, R.W., & Marsillac, S. (2009). Electronic and structural properties of molybdenum thin films as determined by real-time spectroscopic ellipsometry. Applied Physics Letters, 94(14). doi: 10.1063/1.3117222
High-Efficiency Solar Cells Based On Cu(Inal)Se[Sub 2] Thin Films, S. Marsillac, P. D. Paulson, M. W. Haimbodi, R. W. Birkmire, W. N. Shafarman
High-Efficiency Solar Cells Based On Cu(Inal)Se[Sub 2] Thin Films, S. Marsillac, P. D. Paulson, M. W. Haimbodi, R. W. Birkmire, W. N. Shafarman
Electrical & Computer Engineering Faculty Publications
A Cu(InAl)Se2solar cell with 16.9% efficiency is demonstrated using a Cu(InAl)Se2thin film deposited by four-source elemental evaporation and a device structure of glass/Mo/Cu(InAl)Se2/CdS/ZnO/indium tin oxide/(Ni/Algrid)/MgF2. A key to high efficiency is improved adhesion between the Cu(InAl)Se2 and the Mo back contact layer, provided by a 5-nm-thick Ga interlayer, which enabled the Cu(InAl)Se2 to be deposited at a 530 °C substrate temperature. Film and device properties are compared to Cu(InGa)Se2 with the same band gap of 1.16 eV. The solar cells have similar behavior, with performance limited by recombination through …
Influence Of Copper Doping On The Performance Of Optically Controlled Gaas Switches, St. T. Ko, V. K. Lakdawala, K. H. Schoenbach, M. S. Mazzola
Influence Of Copper Doping On The Performance Of Optically Controlled Gaas Switches, St. T. Ko, V. K. Lakdawala, K. H. Schoenbach, M. S. Mazzola
Electrical & Computer Engineering Faculty Publications
The influence of the copper concentration in silicon-doped gallium arsenide on the photoionization and photoquenching of charge carriers was studied both experimentally and theoretically. The studies indicate that the compensation ratio (NCu/NSi) is an important parameter for the GaAs:Si:Cu switch systems with regard to the turn-on and turn-off performance. The optimum copper concentration for the use of GaAs:Si:Cu as an optically controlled closing and opening switch is determined.
An Optically Controlled Closing And Opening Semiconductor Switch, K. H. Schoenbach, V. K. Lakdawala, R. Germer, S. T. Ko
An Optically Controlled Closing And Opening Semiconductor Switch, K. H. Schoenbach, V. K. Lakdawala, R. Germer, S. T. Ko
Electrical & Computer Engineering Faculty Publications
A concept for a bulk semiconductor switch is presented, where the conductivity is increased and reduced, respectively, through illumination with light of different wavelengths. The increase in conductivity is accomplished by electron ionization from deep centers and generation of bound holes. The reduction of conductivity is obtained by hole ionization from the excited centers and subsequent recombination of free electrons and holes. The transient behavior of electron and hole density in a high power semiconductor (GaAs:Cu) switch is computed by means of a rate equation model. Changes in conductivity by five orders of magnitude can be obtained.