Physical Sciences and Mathematics Commons^™

An Application Programming Interface For Parliamentary Procedure, Grant David Bourque

Honors Theses

No abstract provided.

A Graph Based Departmental Spoken Dialogue System, Julia Isaac

Honors Theses

Spoken dialogue systems are automatic, computer based systems that are a great way for people to receive important information. In this project, I created a spoken dialogue system that people can use to learn about the Computer Science Department at Union College. The system was built by populating an open source dialogue system using a graph based dialogue manager. I improved upon a previous working dialogue system by making the conversations sound more natural, improving the flexibility of the system and making the system more robust. To help with this process a corpus was created using about 200 different dialogues …

Atomic Force Microscopy Of Poly(Ethylane-Oxide) Crystalization, Xavier Capaldi

Honors Theses

Polymer crystallization is a complex process which is influenced by a variety of factors. Atomic force microscopy is used to explore the material properties of polymer crystals. Poly(ethylene-oxide) is used in a variety of molecular weights as the sample. In addition, a variety of sample preparation methods and microscopy modes were tested. A relatively new imaging technique was identified for the characterization of polymer crystals: amplitude modulation-frequency modulation viscoelastic mapping. This mode was used to measure material properties such as stiffness and dissipation.

Gasoline Confined In Nano-Porous Media, Matthew Giso

Honors Theses

The heat of combustion was determined for gasoline confined in nano-porous media of differing pore size by bomb calorimetry. The heat of combustion of the confined fuels was comparable to that of bulk within the experimental uncertainty. This suggests that all of the confined fuel burns without any flame quenching and no chemical interactions at the interface between pore walls and fuel mitigate combustion.

Heat Of Fusion Of Primary Alcohol Confined In Nanopores, Harrisonn Griffin

Honors Theses

Melting behavior of physically confined 1-decanol in nano porous silica was probed using a Differential Scanning Calorimeter (DSC). In agreement with the Gibbs-Thomson prediction, we observe that the melting temperature of the confined 1-decanol scales inversely with the physical size of the pores. Contrary to the assumption used in developing the Gibbs-Thomson equation, however, the apparent heat of fusion decreases as the pore size decreases. Previously, several models have been proposed where interfacial layers of molecules do not participate in the phase transition and thereby would not contribute to the heat of fusion. While these could reconcile the seeming contradiction, …

Automated Data Acquisition Of Deet Time-Dependent Concentration Profiles, Ryan D. Coleman

Honors Theses

Spatial insect repellents must maintain a sufficient concentration in the vapor phase to successfully deter pests. However, little is known regarding correlation of concentration to efficacy nor does there exist a standard testing protocol to measure efficacy in air. Among existing spatial repellents, DEET is the most common active ingredient. This research focuses on application of sensor-based technologies to monitor the concentration levels of DEET under static conditions.

Metal oxide semiconductor sensors feature conductivity variance in response to absorption and desorption of volatile organic compounds. Advantages of these sensors include cost, versatility, and sensitivity. Metal oxide semiconductor sensors were chosen …

Synthesis Of Acceptors For Use In Donor-Acceptor Copolymers And Characterization Of These Polymers, William D. Walker

Honors Theses

In this thesis, a selenium-derivatized acceptor was synthesized to examine the heavy atom effects of selenium on the position of the frontier molecular orbitals (HOMO/LUMO band gap) as opposed to sulfur in a donor-acceptor copolymer for use in light harvesting and detection applications. Over the course of this research, standard operating protocols for ultraviolet-visible (UV-Vis-NIR) and Fourier transform infrared (FT-IR) spectroscopies, as well as cyclic voltammetry (CV) characterization techniques were established. Once synthesized, the polymers were characterized through use of the established characterization protocols. The selenium-derivatized polymer exhibited a bathochromic shift compared to the sulfur analogue, with a solid-state absorption …

Density Functional Theory Calculations On The Doping Sequence Of Mnxfen(1-X)Ge, Jordan C. Ball

Honors Theses

No abstract provided.