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Articles 1 - 7 of 7
Full-Text Articles in Physical Sciences and Mathematics
Gaseous Flux And Distribution Of Polycyclic Aromatic Hydrocarbons Across The Air-Water Interface Of Southern Chesapeake Bay, Kurt E. Gustafson
Gaseous Flux And Distribution Of Polycyclic Aromatic Hydrocarbons Across The Air-Water Interface Of Southern Chesapeake Bay, Kurt E. Gustafson
Dissertations, Theses, and Masters Projects
Gaseous fluxes of polycyclic aromatic hydrocarbons (PAHs) across the air-water interface of Southern Chesapeake Bay were calculated for the period January 1994 through May 1995 using a modified two-film model. Additionally, the distributions of PAHs between the vapor and aerosol phase in the atmosphere, and between the freely dissolved and suspended particulate phase in the water column were investigated. Net instantaneous gaseous fluxes of PAHs were determined to vary in direction and magnitude both spatially and temporally across the air-water interface of Southern Chesapeake Bay at four sites ranging from remote to urban and highly industrialized. The magnitude of gas …
Low-Valent Metal Complexes As Reductive Coupling Agents For Smoke Suppression In Poly(Vinyl Chloride), Panagiotis Ioannou Kourtesis
Low-Valent Metal Complexes As Reductive Coupling Agents For Smoke Suppression In Poly(Vinyl Chloride), Panagiotis Ioannou Kourtesis
Dissertations, Theses, and Masters Projects
No abstract provided.
Water Quality Modeling As An Inverse Problem, Jian Shen
Water Quality Modeling As An Inverse Problem, Jian Shen
Dissertations, Theses, and Masters Projects
An inverse mathematical estuarine eutrophication model has been developed. The model provides a framework to estimate unknown parameters by assimilation of the concentration data of those state variables. The inverse model developed is a laterally integrated, two-dimensional, real-time model which consists of a hydrodynamic model, an eutrophication model and an adjoint model. The hydrodynamic model provides the dynamic fields for both the eutrophication model and the adjoint model. The eutrophication model simulates eight water quality state variables which are phytoplankton, organic nitrogen, ammonium nitrogen, nitrite-nitrate nitrogen, organic phosphorus, inorganic (ortho) phosphorus, carbonaceous biochemical oxygen demand and dissolved oxygen. The adjoint …
Synthesis And Characterization Of Boron-Containing Polymeric Materials For Neutron Shielding Applications, Michael B. Glasgow
Synthesis And Characterization Of Boron-Containing Polymeric Materials For Neutron Shielding Applications, Michael B. Glasgow
Dissertations, Theses, and Masters Projects
The development of boron-containing polymeric materials for neutron shielding applications was undertaken. Three types of materials were characterized for physical and thermal properties: boron powder-filled epoxy composites, carborane polyamides having boron chemically bonded into the polymer, and boron-loaded polyimide thin films. Addition of amorphous submicron boron powder did not affect significantly the thermal performance of the epoxy. The 17% boron loading produced a 26% increase in compressive failure strength and a 68% increase in the compressive modulus. 0.125 inch thick specimens containing 17% boron absorbed 92% of incident neutrons from a 5-Curie Pu/Be source compared with {dollar}<{dollar}1% for the neat epoxy. Dispersion of the boron in the epoxy was improved with the addition of larger size crystalline boron powders. Carborane polyamides containing up to 35% boron were thermally stable up to 400{dollar}\sp\circ{dollar}C in air. The polymers had hydrogen/boron ratios from 2.0 to 3.8 and were soluble in several organic solvents. Polymer solutions were processed into clear, colored thin films. Boron-filled polyamic acid solutions of a PMDA-ODA polyimide containing up to 10% boron were processed into thin films. Neutron absorption of the opaque films measured in a 5-Curie Pu/Be neutron source was linear with boron concentration and film thickness. The fraction of neutrons absorbed varied linearly with boron concentration and film thickness. The applicability of boron-containing materials to the aerospace, nuclear power and accelerator industries was investigated.
Characterizing The Degradation Of Nylon-11 And Pvdf In A Flexible Oil Pipe And Cure Monitoring Of Chemflake Vinylester, John Chen Yang
Characterizing The Degradation Of Nylon-11 And Pvdf In A Flexible Oil Pipe And Cure Monitoring Of Chemflake Vinylester, John Chen Yang
Dissertations, Theses, and Masters Projects
No abstract provided.
The Projector Basis Method For Electronic Band Structure Calculations, Christopher Haas
The Projector Basis Method For Electronic Band Structure Calculations, Christopher Haas
Dissertations, Theses, and Masters Projects
Over the last several decades, two methods have emerged as the standard tools for the calculation of electronic band structures. These methods, the Car-Parinello plane wave method and the linear augmented plane wave method (LAPW), each have strengths and weaknesses in different regimes of physical problems. The Car-Parinello algorithm is ideal for calculations with soft pseudopotentials and large numbers of atoms. The LAPW method, on the other hand, easily handles all-electron and hard-core pseudopotential calculations with a small number of atoms. The projector basis method, presented here, is a hybrid mixed basis method which allows the calculation of moderately large …
Surface Reflection Hyperthermal Neutral Stream Source, Christopher A. Nichols
Surface Reflection Hyperthermal Neutral Stream Source, Christopher A. Nichols
Dissertations, Theses, and Masters Projects
A novel source of hyperthermal (1-30 eV) reactive neutrals based on the surface-reflection-neutralization technique is described. This source is potentially capable of minimizing the charge-induced damage associated with plasma based semiconductor processing steps. The goal of this thesis is to investigate the issues involved in scale-up of this technology for processing of 8{dollar}\sp{lcub}\prime\prime{rcub}{dollar} diameter wafers used today in the semiconductor industry. This includes modeling the plasma ion source and trajectory simulations of the reflected neutral flux. A prototype source was constructed for experimental verification of the plasma model.;An inductively coupled plasma (ICP) source is used to provide a source of …