Physical Sciences and Mathematics Commons^™

Environmental And Energy Saving Technologies Of Vinyl Chloride Production, Mykola Kurta

USF Tampa Graduate Theses and Dissertations

Recently, because of the increase of environmental concerns in process design, the need to enhance conversion to product and prevent generation of wasteful byproducts in the reactor network has become urgent. This prevents high cost treatment and separation costs downstream in the process. Therefore, in this thesis I focus on making production of vinyl chloride monomer (VCM) more efficient and on possible ways of industrial organochlorine waste (OCW) recycling. In particular, in the first experiment, we investigate how catalyst and its structure can affect product output.

Infrared spectroscopy and X-ray diffraction analysis were utilized to investigate the structure of the …

Location And Capacity Modeling Of Network Interchanges, Aldo D. Fabregas

USF Tampa Graduate Theses and Dissertations

Network design decisions, especially those pertaining to urban infrastructure, are made by a central authority or network leader, and taking into consideration the network users or followers. These network decision problems are formulated as non-linear bi-level programming problems. In this work, a continuous network design problem (CNDP) and discrete network design problem (DNDP) bi-level optimization programs are proposed and solved in the context of transportation planning. The solution strategy involved reformulation and linearization as a single-level program by introducing the optimality conditions of the lower level problem into the upper level problem. For the CNDP, an alternative linearization algorithm (modified …

Adiabatic Flame Temperature For Combustion Of Methane Ii, Rebeca Pupo

Undergraduate Journal of Mathematical Modeling: One + Two

We calculate the adiabatic flame temperature of a mixture of methane and oxygen in the presence of a diluent gas then determine the mole fractions of methane without respect to nitrogen and solve for the moles of oxygen present. Knowing the moles of methane and oxygen, allows us to calculate the moles of nitrogen present at four constant mole fractions of nitrogen, and the adiabatic flame temperature is determined from the energy released by the reaction. Lastly, we produce several graphs to compare the adiabatic flame temperatures at different mole fractions of nitrogen.

A Simplified Model Of The Internal Combustion Engine, Christofer Neff

Undergraduate Journal of Mathematical Modeling: One + Two

This project further investigates a model of a simplified internal combustion engine considered by Kranc in 1977. Using Euler’s method for ordinary differential equations, we modeled the interaction between the engine’s flywheel and thermodynamic power cycle. Approximating with sufficiently small time intervals (0.001 seconds over a period of 12 seconds) reproduced Kranc’s results with the engine having an average angular velocity of 72/sec.

Finding The Area Of A Major League Baseball Field, Jacob Courchaine

Undergraduate Journal of Mathematical Modeling: One + Two

Using a Major League Baseball (MLB) baseball field template for guidelines, we estimate the cost of building the largest possible field accepted under MLB standards. This includes finding the areas of both the clay and grassy regions and determining how many bags of clay and fertilizer are required to cover the field.

Optimized Correlation Of Geophysical And Geotechnical Methods In Sinkhole Investigations: Emphasizing On Spatial Variations In West-Central Florida, Henok Gidey Kiflu

USF Tampa Graduate Theses and Dissertations

Abstract

Sinkholes and sinkhole-related features in West-Central Florida (WCF) are commonly identified using geotechnical investigations such as standard penetration test (SPT) borings and geophysical methods such as ground penetrating radar (GPR) and electrical resistivity tomography (ERT). Geophysical investigation results can be used to locate drilling and field testing sites while geotechnical investigation can be used to ground truth geophysical results. Both methods can yield complementary information. Geotechnical investigations give important information about the type of soil, groundwater level and presence of low-density soils or voids at the test location, while geophysical investigations like GPR surveys have better spatial coverage and …

Robotic Swarming Without Inter-Agent Communication, Daniel Jonathan Standish

USF Tampa Graduate Theses and Dissertations

Many physical and algorithmic swarms utilize inter-agent communication to achieve advanced swarming behaviors. These swarms are inspired by biological swarms that can be seen throughout nature and include bee swarms, ant colonies, fish schools, and bird flocks. These biological swarms do not utilize inter-agent communication like their physical and algorithmic counterparts. Instead, organisms in nature rely on a local awareness of other swarm members that facilitates proper swarm motion and behavior. This research aims to pursue an effective swarm algorithm using only line-of-sight proximity information and no inter-agent communication. It is expected that the swarm performance will be lower than …

Non-Equilibrium Melting And Sublimation Of Graphene Simulated With Two Interatomic Potentials, Brad Steele

USF Tampa Graduate Theses and Dissertations

The mechanisms of the sublimation of graphene at zero pressure and the condensation of carbon vapor is investigated by molecular dynamics (MD) simulations. The interatomic interactions are described by the Reactive Empirical Bond Order potential (REBO). It is found that graphene sublimates at a temperature of 5,200 K. At the onset of sublimation, defects that contain several pentagons and heptagons are formed, that are shown to evolve from double vacancies and stone wales defects. These defects consisting of pentagons and heptagons act as nucleation sites for the gaseous phase. The influence of the interatomic interactions on the sublimation process are …

Flexible Urban Water Distribution Systems, Seneshaw Amare Tsegaye

USF Tampa Graduate Theses and Dissertations

With increasing global change pressures such as urbanization and climate change, cities of the future will experience difficulties in efficiently managing scarcer and less reliable water resources. However, projections of future global change pressures are plagued with uncertainties. This increases the difficulty in developing urban water systems that are adaptable to future uncertainty.

A major component of an urban water system is the distribution system, which constitutes approximately 80-85% of the total cost of the water supply system (Swamee and Sharma, 2008). Traditionally, water distribution systems (WDS) are designed using deterministic assumptions of main model input variables such as water …

Algorithms And Data Structures For Efficient Timing Analysis Of Asynchronous Real-Time Systems, Yingying Zhang

USF Tampa Graduate Theses and Dissertations

This thesis presents a framework to verify asynchronous real-time systems based on model checking. These systems are modeled by using a common modeling formalism named Labeled Petri-nets(LPNs).

In order to verify the real-time systems algorithmically, the zone-based timing analysis method is used for LPNs. It searches the state space with timing information (represented by zones). When there is a high degree of concurrency in the model, firing concurrent enabled transitions in different order may result in different zones, and these zones may be combined without affecting the verification result. Since the zone-based method could not deal with this problem efficiently, …

Determining The Benefit Of Human Input In Human-In-The-Loop Robotic Systems, Christine Elizabeth Bringes

USF Tampa Graduate Theses and Dissertations

This work analyzes human-in-the-loop robotic systems to determine where human input can be most beneficial to a collaborative task. This is accomplished by implementing a pick-and-place task using a human-in-the-loop robotic system and determining which segments of the task, when replaced by human guidance, provide the most improvement to overall task performance and require the least cognitive effort.

The first experiment entails implementing a pick and place task on a commercial robotic arm. Initially, we look at a pick-and-place task that is segmented into two main areas: coarse approach towards a goal object and fine pick motion. For the fine …

Model Pt- And Pd-Based Electrocatalysts For Low Temperature Fuel Cells Applications, Selasi Ofoe Blavo

USF Tampa Graduate Theses and Dissertations

In the search for alternative energy technologies, low temperature fuel cells continue to feature as technologies with the most promise for mass commercialization. Among the low temperature fuel cells, alkaline and proton exchange membrane fuel cells are the most popular. Alkaline fuel cells have typically been used for water generation as well as auxiliary power for space shuttles. Their bulkiness however makes them undesirable for other applications, especially in automobiles, where there is a great demand for alternative technologies to internal combustion engines. Proton exchange membrane fuel cells on the other hand possess numerous qualities including their compact size, high …

Human Intention Recognition Based Assisted Telerobotic Grasping Of Objects In An Unstructured Environment, Karan Hariharan Khokar

USF Tampa Graduate Theses and Dissertations

In this dissertation work, a methodology is proposed to enable a robot to identify an object to be grasped and its intended grasp configuration while a human is teleoperating a robot towards the desired object. Based on the detected object and grasp configuration, the human is assisted in the teleoperation task. The environment is unstructured and consists of a number of objects, each with various possible grasp configurations. The identification of the object and the grasp configuration is carried out in real time, by recognizing the intention of the human motion. Simultaneously, the human user is assisted to preshape over …

Investigation Of Mercury Use, Release, Deposition, And Exposures In The Tampa Bay Area, Ryan Algernon Michael

USF Tampa Graduate Theses and Dissertations

I investigate the links between mercury use, release, deposition, and population exposure in Tampa Bay, with the focus of identifying levers for reducing population mercury exposures. To achieve this, I investigated the trends in mercury use and release by products and processes in the Tampa Bay area using a Material Flow Analysis. Analysis of USEPA National Emissions Inventory data over time (1999 - 2008) identified relevant air source emission categories, and explored and compared state and regional trends in mercury emissions. To understand source contributions to wet deposited mercury in the Tampa Bay area, I analyzed trends in mercury deposition …

Control Of Smart Building Using Advanced Scada, Vivin Thomas Samuel

USF Tampa Graduate Theses and Dissertations

ABSTRACT

For complete control of the building, a proper SCADA implementation and the optimization strategy has to be build. For better communication and efficiency a proper channel between the Communication protocol and SCADA has to be designed.

This paper concentrate mainly between the communication protocol, and the SCADA implementation, for a better optimization and energy savings is derived to large scale industrial buildings. The communication channel used in order to completely control the building remotely from a distant place. For an efficient result we consider the temperature values and the power ratings of the equipment so that while controlling the …

Towards Interference-Immune And Channel-Aware Multicarrier Schemes: Filters, Lattices, And Interference Issues, Alphan Sahin

USF Tampa Graduate Theses and Dissertations

In this dissertation, multicarrier schemes are reviewed within the framework of Gabor Systems. Their fundamental elements; what to transmit, i.e., symbols, how to transmit, i.e., filters or pulse shape, and where/when to transmit, i.e., lattices are investigated extensively. The relations between different types of multicarrier schemes are discussed.

Within the framework of Gabor systems, a new windowing approach, edge windowing, is developed to address the out-of-band (OOB) radiation problem of orthogonal frequency division multiplexing (OFDM) based multicarrier schemes. To the best of our knowledge, for the first time, the diversity on the range of the users is exploited to suppress …

Fpca Based Human-Like Trajectory Generating, Wei Dai

USF Tampa Graduate Theses and Dissertations

This thesis presents a new human-like upper limb and hand motion generating method. The work is based on Functional Principal Component Analysis and Quadratic Programming. The human-like motion generating problem is formulated in a framework of minimizing the difference of the dynamic profile of the optimal trajectory and the known types of trajectory. Statistical analysis is applied to the pre-captured human motion records to work in a low dimensional space. A novel PCA FPCA hybrid motion recognition method is proposed. This method is implemented on human grasping data to demonstrate its advantage in human motion recognition. One human grasping hierarchy …

Efficient And Private Processing Of Analytical Queries In Scientific Datasets, Anand Kumar

USF Tampa Graduate Theses and Dissertations

Large amount of data is generated by applications used in basic-science research and development applications. The size of data introduces great challenges in storage, analysis and preserving privacy. This dissertation proposes novel techniques to efficiently analyze the data and reduce storage space requirements through a data compression technique while preserving privacy and providing data security.

We present an efficient technique to compute an analytical query called spatial distance histogram (SDH) using spatiotemporal properties of the data. Special spatiotemporal properties present in the data are exploited to process SDH efficiently on the fly. General purpose graphics processing units (GPGPU or just …

Development Of Nanostructured Graphene/Conducting Polymer Composite Materials For Supercapacitor Applications, Punya A. Basnayaka

USF Tampa Graduate Theses and Dissertations

The developments in mobile/portable electronics and alternative energy vehicles prompted engineers and researchers to develop electrochemical energy storage devices called supercapacitors, as the third generation type capacitors. Most of the research and development on supercapacitors focus on electrode materials, electrolytes and hybridization. Some attempts have been directed towards increasing the energy density by employing electroactive materials, such as metal oxides and conducting polymers (CPs). However, the high cost and toxicity of applicable metal oxides and poor long term stability of CPs paved the way to alternative electrode materials. The electroactive materials with carbon particles in composites have been used substantially …

Magnetization Dynamics And Related Phenomena In Nanostructures, Sayan Chandra

USF Tampa Graduate Theses and Dissertations

Collective magnetic behavior in nanostructures is a phenomenon commonly observed in various magnetic systems. It arises due to competing inter/intra–particle interactions and size distribution and can manifest in phenomena like magnetic freezing, magnetic aging, and exchange bias (EB) effect. In order to probe these rather complex phenomena, conventional DC and AC magnetic measurements have been performed along with radio–frequency transverse susceptibility (TS) measurements. We also demonstrate the magnetic entropy change as a parameter sensitive to subtle changes in the magnetization dynamics of nanostructures. The focus of this dissertation is to study the collective magnetic behavior in core-shell nanostructures of Fe/γ–Fe …

Application And Characterization Of Self-Assembled Monolayers In Hybrid Electronic Systems, Michael Enoch Celesin

USF Tampa Graduate Theses and Dissertations

In this study, we explore ultra-thin insulators of organic and inorganic composition and their potential role as high-speed rectifiers. Typical applications for these structures include IR sensing, chemical detection, high speed logic circuits, and MEMS enhancements. While there are many elements in the functional group required to create a rectifying antenna (rectenna), the primary thrust of this work is on the rectifier element itself.

To achieve these research goals, a very good understanding of quantum tunneling was required to model the underlying phenomenon of charge conduction. The development of a multi-variable optimization routine for tunneling prediction was required. MATLAB was …

Assessment Of A Modified Double Agar Layer Method To Detect Bacteriophage For Assessing The Potential Of Wastewater Reuse In Rural Bolivia, Sakira N. Hadley

USF Tampa Graduate Theses and Dissertations

Water scarcity is a global concern that impacts many developing countries, forcing people to depend on unclean water sources for domestic, agricultural, and industrial needs. Wastewater is an alternative water source that contains nutrients needed for crop growth. Wastewater reuse for agriculture can cause public health problems because of human exposure to pathogens. Pathogen monitoring is essential to evaluate the compliance of wastewater with established World Health Organization (WHO) and U.S. Environmental Protection Agency (EPA) wastewater reuse guidelines. Indicator organisms are commonly used to detect pathogens in water and wastewater because they are quick and easy to measure, non-pathogenic, and …

A Study On The Optimization Of Dye-Sensitized Solar Cells, Md Imran Khan

USF Tampa Graduate Theses and Dissertations

Considering biocompatibility, the Dye Sensitized Solar Cell (DSC) based on titanium dioxide should play a major role in the future of solar energy. In this ongoing study, different components and ambient process conditions for the fabrication of were investigated. Titanium dioxide substrate thickness and morphology was found to have a direct impact on the cell efficiency. Scanning Electron Microscopy (SEM) was used to investigate the TiO2 nanostructure. Different chemical treatments and electrolytes were also explored towards optimizing the cell performance. A group of porphyrin based organic dyes were synthesized and evaluated. Standard solar cell characterization techniques such as current-voltage and …

Effect Of Solids Retention Time On The Denitrification Potential Of Anaerobically Digested Swine Waste, Maureen Njoki Kinyua

USF Tampa Graduate Theses and Dissertations

Three continuously stirred tank reactors (CSTR) were operated in semi continuous mode treating swine waste using anaerobic digestion. The reactors were used to test the effect of solid retention time (SRT) on CH4 yield, total ammonia nitrogen (TAN) concentrations, % volatile solids (VS), chemical oxygen demand (COD) and volatile fatty acids (VFA) removal, readily biodegradable COD concentration and the denitrification potential for the effluent in a biological nutrient removal (BNR) system. During Phase I of the study, the three reactors were operated at the same 28 day SRT for 16 weeks. SRTs were then changed during the 12 week Phase …

Development Of Novel Nano-Composite Membranes As Introduction Systems For Mass Spectrometers: Contrasting Nano-Composite Membranes And Conventional Inlet Systems, Luis Miranda

USF Tampa Graduate Theses and Dissertations

This dissertation presents the development of novel nano-composite membranes as introduction systems for mass spectrometers. These nano-composite membranes incorporate anodic aluminum oxide (AAO) membranes as templates that can be used by themselves or modified by a variety of chemical deposition processes. Two types of nano-composite membranes are presented. The first nano-composite membrane has carbon deposited within the pores of an AAO membrane. The second nano-composite membrane is made by coating an AAO membrane with a thin polymer film. The following chapters describe the transmission properties these nano-composite membranes and compare them to conventional mass spectrometry introduction systems. The nano- composite …

Packet Coalescing And Server Substitution For Energy-Proportional Operation Of Network Links And Data Servers, Mehrgan Mostowfi

USF Tampa Graduate Theses and Dissertations

Electricity generation for Information and Communications Technology (ICT) contributes over 2% of the human-generated CO2 to the atmosphere. Energy costs are rapidly becoming the major operational expense for ICT and may soon dwarf capital expenses as software and hardware continue to drop in price. In this dissertation, three new approaches to achieving energy-proportional operation of network links and data servers are explored.

Ethernet is the dominant wireline communications technology for Internet connectivity. IEEE 802.3az Energy Efficient Ethernet (EEE) describes a Low Power Idle (LPI) mechanism for allowing Ethernet links to sleep. A method of coalescing packets to consolidate link idle …

Time Scale Of Groundwater Recharge: A Generalized Modeling Technique, Makhan Virdi

USF Tampa Graduate Theses and Dissertations

Estimating the quantity of water that reaches the water table following an infiltration event is vital for modeling and management of water resources. Estimating the time scale of groundwater recharge after a rainfall event is difficult because of the dependence on nonlinear soil characteristics and variability in antecedent conditions. Modeling the flow of water through the variably saturated zone is computationally intensive since it requires simulation of Richards' equation, a nonlinear partial differential equation without a closed-form analytical solution, with parametric relationships that are difficult to approximate. Hence, regional scale coupled (surface water - groundwater) hydrological models make simplistic assumptions …

Energy Efficient Context-Aware Framework In Mobile Sensing, Ozgur Yurur

USF Tampa Graduate Theses and Dissertations

The ever-increasing technological advances in embedded systems engineering, together with the proliferation of small-size sensor design and deployment, have enabled mobile devices (e.g., smartphones) to recognize daily occurring human based actions, activities and interactions. Therefore, inferring a vast variety of mobile device user based activities from a very diverse context obtained by a series of sensory observations has drawn much interest in the research area of ubiquitous sensing. The existence and awareness of the context provides the capability of being conscious of physical environments or situations around mobile device users, and this allows network services to respond proactively and intelligently …

Synthesis And Investigations Of Type I And Ii Clathrates Of Group 14, Michael Blosser

USF Tampa Graduate Theses and Dissertations

Clathrates are a class of new materials that have an open-framework structure that allows guest atoms or molecules to be enclosed inside of their polyhedral framework. Varying the number, weight, and size of the guest species in a particular framework allows one to alter the physical properties of the clathrate. This relationship enables one to further the fundamental understanding of the physics and chemistry of the clathrate structure and use this knowledge to "tune" certain properties. This "tunability" of inorganic clathrates is of great interest as it allows one to optimize their physical properties; making them promising candidates for a …

Prevention And Detection Of Intrusions In Wireless Sensor Networks, Ismail Butun

USF Tampa Graduate Theses and Dissertations

Wireless Sensor Networks (WSNs) continue to grow as one of the most exciting and challenging research areas of engineering. They are characterized by severely constrained computational and energy

resources and also restricted by the ad-hoc network operational

environment. They pose unique challenges, due to limited power

supplies, low transmission bandwidth, small memory sizes and limited energy. Therefore, security techniques used in traditional networks cannot be directly adopted. So, new ideas and approaches are needed, in order to increase the overall security of the network. Security applications in such resource constrained WSNs with minimum overhead provides significant challenges, and is the …