Physical Sciences and Mathematics Commons^™

Mono-Sized Sphere Packing Algorithm Development Using Optimized Monte Carlo Technique, Karn Soontrapa, Yitung Chen

College of Engineering: Graduate Celebration Programs

In this research, fuel cell catalyst layer was developed using the optimized sphere packing algorithm. An optimization technique named adaptive random search technique (ARSET) was employed in this packing algorithm. The ARSET algorithm will generate the initial location of spheres and allow them to move in the random direction with the variable moving distance, randomly selected from the sampling range (a), based on the Lennard–Jones potential and Morse potential of the current and new configuration. The solid fraction values obtained from this developed algorithm are in the range of 0.610–0.624 while the actual processing time can significantly be reduced by …

Spectroscopic Investigation Of Palladium-Copper Bimetallic Systems For Pem Fuel Cell Catalysts, Timo Hofmann

UNLV Theses, Dissertations, Professional Papers, and Capstones

One of the main barriers to commercialization of polymer electrolyte membrane fuel cells systems is cost, which is largely due to the need of platinum (Pt)-containing catalysts. In this thesis we investigate bimetallic systems consisting of a base metal (copper) and a noble metal (palladium) that, as an alloy on the nanoscale, mimic the electronic properties that make Pt desirable as a catalyst.

We present a detailed investigation of the electronic structure of carbon-supported Pd/Cu nanoparticle catalysts, model bilayer thin film systems, alloys, and various metal reference samples. We have investigated the valence band structure of the catalysts using a …